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Transcription:

Material Safety Data Sheet NFPA HMIS Personal Protective Equipment Health Hazard Fire Hazard See Section 5. Section. Chemical Product and Company Identification Page Number: Common Name/ Trade Name Manufacturer Commercial Name(s) Synonym Chemical Name Chemical Family Chemical Formula Supplier Silicone Fluid 5 SPECTRUM LABORATORY PRODUCTS INC. 4422 S. SAN PEDRO STREET GARDENA, CA 9248 Dow Corning 2 fluid, 5 cst Silicone Oil; Silicone Fluid 5 cst; DC Silicone fluid 2, 5 cst; Polydimethylsiloxane, Trimethylsiloxy-Terminated; Polydimethylsiloxane SPECTRUM LABORATORY PRODUCTS INC. 4422 S. SAN PEDRO STREET GARDENA, CA 9248 Catalog Number(s). CAS# RTECS TSCA CI# SI2 CALL (3) 56-8 6348-62-9 JT64845 TSCA 8(b) inventory: Listed as Dimethyl Silicones and S i l o x a n e s ( C A S n o. 6348-62-9) IN CASE OF EMERGENCY CHEMTREC (24hr) 8-424-93 Section 2.Composition and Information on Ingredients Name CAS # Exposure Limits TWA (mg/m 3 ) STEL (mg/m 3 ) CEIL (mg/m 3 ) % by Weight ) Polydimethylsiloxane 6348-62-9 or 96-65-9 >6 Toxicological Data on Ingredients Section 3. Hazards Identification Potential Acute Health Effects Potential Chronic Health Effects Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion. Non-hazardous in case of inhalation. CARCINOGENIC EFFECTS: MUTAGENIC EFFECTS: TERATOGENIC EFFECTS: DEVELOPMENTAL TOXICITY: Repeated or prolonged exposure is not known to aggravate medical condition.

Silicone Fluid 5 Page Number: 2 Section 4. First Aid Measures Eye Contact Skin Contact Serious Skin Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 5 minutes. Get medical attention if irritation occurs. Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Inhalation Serious Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention if symptoms appear. Ingestion Serious Ingestion Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear. Section 5. Fire and Explosion Data Flammability of the Product Auto-Ignition Temperature Flash Points Flammable Limits Products of Combustion Fire Hazards in Presence of Various Substances May be combustible at high temperature. CLOSED CUP: >. C (24 F). Slightly flammable to flammable in presence of open flames and sparks, of heat. Explosion Hazards in Presence of Various Substances Risks of explosion of the product in presence of mechanical impact: Risks of explosion of the product in presence of static discharge: Fire Fighting Media and Instructions Fire Hazards Explosion Hazards SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet. Section 6. Accidental Release Measures Small Spill Large Spill Absorb with an inert material and put the spilled material in an appropriate waste disposal. Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Section 7. Handling and Storage Precautions Storage Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not breathe gas/fumes/ vapor/spray. If ingested, seek medical advice immediately and show the container or the label. Keep away from incompatibles such as oxidizing agents. Keep container tightly closed. Keep container in a cool, well-ventilated area.

Silicone Fluid 5 Page Number: 3 Section 8. Exposure Controls/Personal Protection Engineering Controls Personal Protection Personal Protection in Case of a Large Spill Exposure Limits Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location. Safety glasses. Lab coat. Gloves. No respiratory protection should be needed. Please note that the personal protective equipment that is recommended is for room temperature handling without aerosol/spray application. Use at elevated temperature or aerosol/spray applications may require added precautions. For further information regarding aerosol inhalation toxicity, please refer to the guidance document regarding the use of silicone-based materials in aerosol applications that has been developed by the silicone industry (www.sehsc.com). Coments: When heated to temperatures above 5 deg. C in the presence of air, this product can form formaldehyde vapors. Formaldehyde is a potenetial cancer hazard, a known skin and respiratory sensitizer, and an irritant to the eyes, nose, throat, skin, and digestive system. Safe handling conditions may be maintained by keeping vapor concentrations within the OSHA Permissible Limit for formaldehyde. Respiratory protection is not necessary for normal handling. Good room ventilation or use of local exhaust (fume hood) is sufficient. Use a vapor respirator under conditions where exposure to the substance is apparent (e.g. generation of high concentrations of mist or vapor, inadequate ventilation, development of respiratory tract irritation), and engineering controls are not feasible. Be sure to use an approved/certified respirator or equivalent. Splash goggles. Full suit. Boots. Gloves. No respiratory protection should be needed.please note that the personal protective equipment that recommended above is for room temperature handling without aerosol/spray application. Use at elevated temperature or aerosol/spray applications may require added precautions. For further information regarding aerosol inhalation toxicity, please refer to the guidance document regarding the use of silicone-based materials in aerosol applications that has been developed by the silicone industry (www.sehsc.com). Coments: When heated to temperatures above 5 deg. C in the presence of air, this product can form formaldehyde vapors. Formaldehyde is a potenetial cancer hazard, a known skin and respiratory sensitizer, and an irritant to the eyes, nose, throat, skin, and digestive system. Safe handling conditions may be maintained by keeping vapor concentrations within the OSHA Permissible Limit for formaldehyde. Section 9. Physical and Chemical Properties Physical state and appearance Liquid. Odor Odorless. Molecular Weight ph (% soln/water) Taste Color Colorless. Colorless to light yellow. Boiling Point >65 C (49 F) Melting Point Critical Temperature Specific Gravity.97@ 25 deg. C. (Water = ) Vapor Pressure <. kpa (@ 2 C) Vapor Density Volatility Odor Threshold Water/Oil Dist. Coeff. Ionicity (in Water) Dispersion Properties Solubility Insoluble in cold water, hot water.

Silicone Fluid 5 Page Number: 4 Section. Stability and Data Stability Instability Temperature Conditions of Instability Incompatibility with various substances Corrosivity The product is stable. Excess heat, incompatible materials Reactive with oxidizing agents. Corrosivity Polymerization Will not occur. Section. Toxicological Information Routes of Entry Toxicity to Animals Chronic Effects on Humans Other Toxic Effects on Humans Toxicity to Animals Chronic Effects on Humans other Toxic Effects on Humans Contact with skin. Eye contact. Acute oral toxicity (LD5): >7 mg/kg [Rat]. Acute dermal toxicity (LD5): >2 mg/kg [Rabbit]. Slightly hazardous in case of skin contact (irritant), of ingestion. Non-hazardous in case of inhalation. Other Lethal Dose/Conc: LC [Rabbit] - Route: Inhalation; Dose: >978 mg/kg/7.5h LD [Guinea Pig]: Route: Ingestion; Dose: > mg/kg Acute Potential Health Effects: Skin: May cause skin irritation. However, no significant irritation is expected from a single short-term exposure. Eyes: Direct contact may cause irritation with temporary redness and discomfort. Inhalation: No significant effects expected from a single short-term exposure. Ingestion: Low ingestion hazard in normal use. Section 2. Ecological Information Ecotoxicity BOD5 and COD Products of Biodegradation Toxicity of the Products of Biodegradation the Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.

Silicone Fluid 5 Page Number: 5 Section 3. Disposal Considerations Waste Disposal Waste must be disposed of in accordance with federal, state and local environmental control regulations. Section 4. Transport Information DOT Classification Identification Not a DOT controlled material (United States). Special Provisions for Transport DOT Section 5. Other Regulatory Information and Pictograms Federal and State Regulations California Proposition 65 Warnings Other Regulations TSCA 8(b) inventory: Listed as Dimethyl Silicones and Siloxanes (CAS no. 6348-62-9) TSCA 8(a) PAIR: Listed as Dimethyl Silicones and Siloxanes (CAS no. 6348-62-9) TSCA 8(d) H and S data reporting: Listed as Dimethyl Silicones and Siloxanes (CAS no. 6348-62-9): Effective Date: /2/93; Sunset Date: 6/3/98 California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: No products were found. California prop. 65: This product contains the following ingredients for which the State of California has found to cause birth defects which would require a warning under the statute: No products were found. EINECS: This product is not on the European Inventory of Existing Commercial Chemical Substances. Canada: Listed on Canadian Domestic Substance List (DSL). China: Listed on National Inventory. Japan: Listed on National Inventory (ENCS). Korea: Listed on National Inventory (KECI). Philippines: Listed on National Inventory (PICCS). Australia: Listed on AICS Other Classifications WHMIS (Canada) Not controlled under WHMIS (Canada). DSCL (EEC) This product is not classified according to the EU regulations. HMIS (U.S.A.) Health Hazard Fire Hazard Personal Protection g National Fire Protection Association (U.S.A.) Health Flammability Specific hazard WHMIS (Canada) DSCL (Europe)

Silicone Fluid 5 Page Number: 6 TDG (Canada) ADR (Europe) Protective Equipment Gloves. Lab coat. Safety glasses. Section 6. Other Information MSDS Code References Other Special Considerations S3332 Major Uses: In fire resistant transformers; in cosmetics, toiletries, food and related products, coatings, paints, inks, rubber and plastics, polishes, fibers, threads, and household, automotive products, defoaming agent. Validated by Sonia Owen on 7/5/22. Verified by Sonia Owen. Printed 7/5/22. CALL (3) 56-8 Notice to Reader All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products, Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.