Page: 1 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER Chemical Product and Company Identification Product Name Company Name Address Telephone/Fax Number Email Recommended Use Other Names Other Tel: (03)9416 6700 Fax: (03)9416 816 Web: www.peerlessjal.com.au email: sales@peerlessjal.com.au Frag Tabs Lavender Peerless Jal Pty Ltd (ABN 3 006 489 34) 10-12 Raglan Street Preston Victoria 3072 Australia Tel: (03) 9416 6700 Fax: (03) 9416 816 sales@peerlessjal.com Place unwrapped tablets in desired location. Name 2. HAZARDS IDENTIFICATION Hazard Classification Risk Phrase(s) Safety Phrase(s) Product Code Deodorant Double Strength Deodorant Tablets Lavender Tablets NOTICE: While the information contained herein is correct to the best our knowledge, PEERLESS JAL Pty Ltd herein disclaims any warranties as to the accuracy the same. Recommendations or suggestions are made without guarantee or representation as a result, since conditions use are beyond our control. All materials are sold subject to PEERLESS JAL Pty Ltd standard terms and conditions sale and on the condition that buyer shall make his/her own tests to determine the suitability such product for buyers purposes. No statement contained herein shall be construed as a recommendation to infringe any patent. Approved Criteria Classification (Calculated) Harmful and Irritating, Risk Phrases R: 22-36/38 Safety Phrases S: 2-22-24/2-46 SUSDP Classification S (PDB-paradichlorobenzene) ADG Classification Not a dangerous good. UN Number Not a dangerous good EMERGENCY OVERVIEW Colour White Physical Description Solid tablets Odour Lavender Major Health Hazards Harmful if swallowed and irritating to skin and eyes. R22 Harmful if swallowed. R36/38 Irritating to eyes and skin. S2 Keep out reach children. S22 Do not breathe dust. S24/2 Avoid contact with skin and eyes. S46 If swallowed, seek medical advice immediately and show this container or label. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Characterization Ingredients Solid Name CAS Proportion Hazard Symbol Risk Phrase
Page: 2 4. FIRST AID MEASURES First Aid Measures Inhalation Ingestion Skin Eye First Aid Facilities Advice to Doctor Paradichlorobenzene 106-46-7 99.9 % Perfume (Proprietary) 0-1 % Dye (Proprietary) 0-1 % For advice, contact a Poisons Centre (Phone 13 1126) or a doctor. Leave contaminated area. Give water to drink. Wash skin with water. Wash with water.. FIRE FIGHTING MEASURES Suitable Extinguishing Media Specific Methods Specific Hazards Other No special facilities required. Treat symptomatically. Use water spray or fog, foam, dry agent or carbon dioxide. Move container from fire area if it can be done without risk. Do not scatter spilled material with high-pressure water streams. Dike for later disposal. Use extinguishing agents appropriate for surrounding fire. Avoid inhalation material or combustion by-products. Stay upwind and keep out low areas. Auto ignition temperature > 60 C. Avoid flames, hot surfaces and electric arcs. ADG Classification: Not a dangerous good. 6. ACCIDENTAL RELEASE MEASURES Clean-up Methods - Small Spillages Clean-up Methods - Large Spillages 7. HANDLING AND STORAGE Precautions for Safe Handling Conditions for Safe Storage Sweep up and collect for reuse or reprocessing. Sweep up and collect for reuse or reprocessing. Dispose according to local authority. This material is a Schedule Poison. Handle in accordance with State or Territory Poisons Regulations. Avoid contact with eyes and skin. Do not breathe dust. This material is a Schedule Poison. Store in accordance with State or Territory Poisons Regulations. Store in a cool dry place. Store away from sources heat or ignition. Keep containers closed. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION National Exposure Standards The National Occupational Health and Safety Commission (Worksafe Australia) has set no exposure standards for this material. This does not imply that this material is safe or non-hazardous. There may be insufficient information available to allow the National Commission to assign an exposure standard, even on a tentative basis. Where exposure standards are available for the ingredients this material, they are listed below. Ingredient Exposure Limits Ingredient TWA STEL Notices ppm mg/m³ ppm mg/m³ p-dichlorobenzene 7 41 110 661 - Application in the Workplace TWA - the Time-Weighted Average airborne concentration over an eight-hour working day, for a five-day week over an entire working life. According to current knowledge this concentration should neither impair the health, nor cause undue discomfort to, nearly all workers. STEL is the Short Term Exposure Limit and is a 1-minute TWA exposure, which should not be exceeded at any time during a working day. Exposures at the STEL should not be longer than 1 minutes and should not be repeated more than four times per day. There should be at least 60 minutes between successive
Page: 3 Engineering Controls Respiratory Protection Eye Protection Hand Protection Body Protection Hygiene Measures exposures at the STEL. Guide Only Exposure Standards are guides to be used in the control occupational health hazards. They are not fine dividing lines between safe and dangerous concentrations chemicals nor are they measures relative toxicity. All atmospheric contamination should be kept to as low a level as is practicable. Ventilation Ensure adequate ventilation to maintain concentrations below exposure standards. Consider using local exhaust ventilation Not usually required. If inhalation risk exists, wear respirator that complies with AS/NZS 171 and AS/NZS 1716. Choose a canister suitable for use with organic vapours. Not usually required. Protective Material Types: Gloves that are suitable include those made latex, PVC and rubber. Skin Protection: Not usually required. Always wash hands before eating, drinking, smoking or using the toilet.... 9. PHYSICAL AND CHEMICAL PROPERTIES Form Odour Boiling Point Solubility in Water Specific Gravity ph Value Vapour Density (Air=1) Colour Flash Point Explosion Limit - Upper Explosion Limit - Lower Solid Lavender 174 C. Not soluble. 1.248@ C. white 67 C. 10. STABILITY AND REACTIVITY Stability and Reactivity Conditions to Avoid Incompatible Materials Hazardous Decomposition Products Hazardous Polymerization Stable at normal temperatures and pressures. Avoid heating above flash point 67 C. Avoid flames, hot surfaces and electric arcs. No special precautions. May produce hydrogen chloride and phosgene on ignition and decomposition. Will not occur. 11. TOXICOLOGICAL INFORMATION Toxicology Health Hazard Toxicity Data LD0 (rat): 2-3gm/Kg; LD0 (Dermal): >6gm/Kg. Local Effects Slightly irritating to eyes and skin and if inhaled. Harmful if swallowed. References MSDS Recochem Inc. Issued May 1999. No adverse health effects expected if the product is handled in accordance with this Material Safety Data Sheet and the product label. Symptoms that may
Page: 4 Inhalation Ingestion Skin Eye Carcinogenicity 12. ECOLOGICAL INFORMATION Ecological 13. DISPOSAL CONSIDERATIONS Disposal Considerations 14. TRANSPORT INFORMATION Transport 1. REGULATORY INFORMATION Regulatory Poisons Schedule Hazard Category 16. OTHER INFORMATION Technical Contact Numbers Other arise if the product is mishandled are: For WSA Format, please refer to Health Effects Section for acute effects. May be slightly irritating. May cause nausea and diarrhoea. May be slightly irritating. May cause redness and dryness. May be slightly irritating. Not classified. NTP IARC Product solidifies at 3 C. No further information. Dispose in accordance with all applicable regulations. Not classified as a dangerous good according to the Australian Dangerous Goods (ADG) Code. AICS All ingredients are listed in AICS. S Harmful,Irritant Technical Department 10-12 Raglan Street Preston VIC 3072 Tel: (03)9416 6700 Fax: (03)9416 816 PRODUCT SIZES AND CODES: 11FRTA 4 Kg 11FRTA10 10 Kg 11FRTA1 1 Kg JAL COLOUR CODING: Green - Neutral Revised Sections MSDS All sections. Update to 16-section format. Acronyms SUSDP Standard for the Uniform Scheduling Drugs and Poisons MSDS
Page: Material Safety Data Sheet ADG CODE Australian Code for the Transport Dangerous Goods by Road and Rail NOS Not Otherwise Specified CAS Number Chemical Abstracts Service Registry Number UN Number United Nations Number R-Phrases Risk Phrases HAZCHEM Code An emergency action code numbers and letters that gives information to emergency services National Occupational Health and Safety Commission NTP National Toxicology Program (USA) IARC International Agency for Research on Cancer AICS Australian Inventory Chemical Substances...End Of MSDS... Copyright Chemical Safety International Pty Ltd Copyright in the source code the HTML, PDF, XML, XFO and any other electronic files rendered by an Infosafe system for Infosafe MSDS displayed is the intellectual property Chemical Safety International Pty Ltd. Copyright in the layout, presentation and appearance each Infosafe MSDS displayed is the intellectual property Chemical Safety International Pty Ltd. The compilation MSDS's displayed is the intellectual property Chemical Safety International Pty Ltd. Copying any MSDS displayed is permitted for personal use only and otherwise is not permitted. In particular the MSDS's displayed cannot be copied for the purpose sale or licence or for inclusion as part a collection MSDS without the express written consent Chemical Safety International Pty Ltd.