Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 20-4453-5 Version Number: 5.01 Issue Date: 02/23/15 Supercedes Date: 02/23/15 SECTION 1: Identification 1.1. Product identifier 3M Deodorizer - Fresh Scent - Ready-to-Use (Product No. 13, 3M Chemical Management Systems) Product Identification Numbers LN-DCCX-127B-1, 61-0000-6307-5 1.2. Recommended use and restrictions on use Recommended use Deodorizer, Long-lasting deodorizer leaves a fresh, clean scent. 1.3. Supplier s details MANUFACTURER: 3M DIVISION: Commercial Solutions Division ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification 2.1. Hazard Skin Sensitizer: Category 1. 2.2. Label elements Signal word Warning Symbols Exclamation mark Pictograms Page 1 of 9
Hazard Statements May cause an allergic skin reaction. Precautionary Statements Prevention: Avoid breathing mist/spray. Wear protective gloves. Contaminated work clothing must not be allowed out of the workplace. Response: IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified None. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt WATER 7732-18-5 > 95 Trade Secret * POLYALKOXY ALCOHOLS 69013-18-9 0.5-1.5 Trade Secret * SORBITAN POLYETHOXY MONOLAURATE 9005-64-5 0.1-1 Trade Secret * (POLYSORBATE 20) terpenes AND terpenoids, SWEET ORANGE- 68647-72-3 0.01-1 Trade Secret * OIL FRAGRANCE (NJTSN 04499600-6517) Trade Secret* 0.01-1 2-PHENOXYETHANOL 122-99-6 0.01-1 Trade Secret * TERPINOLENE 586-62-9 0.001-0.05 Trade Secret * NJTS or NJTSRN: New Jersey Trade Secret Registry Number. *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. Page 2 of 9
If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Material will not burn. Non-combustible. Use a fire fighting agent suitable for surrounding fire. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Carbon monoxide Carbon dioxide Oxides of Nitrogen Condition During Combustion During Combustion During Combustion 5.3. Special protective actions for fire-fighters No unusual fire or explosion hazards are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with water. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling For industrial or professional use only. NOTE: The above precautionary information presumes that this ready-to-use product has been diluted and dispensed from a chemical dispensing system. Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. 7.2. Conditions for safe storage including any incompatibilities No special storage requirements. Page 3 of 9
SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments 2-PHENOXYETHANOL 122-99-6 CMRG TWA:25 ppm Skin Notation ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control mist/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety Glasses with side shields Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Nitrile Rubber If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron Nitrile Respiratory protection None required. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Liquid Odor, Color, Grade: Clear; blue color; fresh, clean fragrance. Odor threshold No Data Available ph 6.5-7.5 Boiling Point 212 ºF Flash Point No flash point Evaporation rate 1 [Ref Std: WATER=1] Page 4 of 9
Flammability (solid, gas) Not Applicable Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable Density 1 g/ml [Ref Std: WATER=1] Specific Gravity 1 [Ref Std: WATER=1] Solubility in Water Complete Solubility- non-water No Data Available Decomposition temperature No Data Available Viscosity < 100 centipoise Hazardous Air Pollutants Not Applicable Volatile Organic Compounds 0 % weight [Test Method: calculated per CARB title 2] Percent volatile > 95 % VOC Less H2O & Exempt Solvents 0 g/l [Test Method: calculated per CARB title 2] SECTION 10: Stability and reactivity 10.1. Reactivity This material is considered to be non reactive under normal use conditions. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid None known. 10.5. Incompatible materials None known. 10.6. Hazardous decomposition products Substance None known. Condition Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material in Section 2 if specific ingredient s are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: No known health effects. Skin Contact: Page 5 of 9
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Contact with the eyes during product use is not expected to result in significant irritation. Ingestion: No known health effects. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the. Acute Toxicity Name Route Species Value Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg SORBITAN POLYETHOXY MONOLAURATE Ingestion Rat LD50 40,600 mg/kg (POLYSORBATE 20) terpenes AND terpenoids, SWEET Inhalation- Vapor (4 hours) Mouse LC50 > 3.14 mg/l FRAGRANCE (NJTSN 04499600-6517) Dermal Rabbit LD50 > 5,000 mg/kg terpenes AND terpenoids, SWEET Dermal Rabbit LD50 > 5,000 mg/kg FRAGRANCE (NJTSN 04499600-6517) Ingestion Rat LD50 14,800 mg/kg terpenes AND terpenoids, SWEET Ingestion Rat LD50 4,400 mg/kg 2-PHENOXYETHANOL Dermal Rabbit LD50 > 2,000 mg/kg 2-PHENOXYETHANOL Ingestion Rat LD50 1,260 mg/kg TERPINOLENE Inhalation- Vapor (4 hours) Mouse LC50 > 3.14 mg/l TERPINOLENE Dermal Rabbit LD50 > 5,000 mg/kg TERPINOLENE Ingestion Rat LD50 4,400 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value terpenes AND terpenoids, SWEET Rabbit Mild irritant TERPINOLENE Rabbit Mild irritant Serious Eye Damage/Irritation Name Species Value terpenes AND terpenoids, SWEET Rabbit Mild irritant TERPINOLENE Rabbit Mild irritant Skin Sensitization Name Species Value terpenes AND terpenoids, SWEET Mouse Sensitizing TERPINOLENE Mouse Sensitizing Respiratory Sensitization For the component/components, either no data are currently available or the. Germ Cell Mutagenicity Name Route Value terpenes AND terpenoids, SWEET In Vitro Not mutagenic terpenes AND terpenoids, SWEET In vivo Not mutagenic TERPINOLENE In Vitro Not mutagenic TERPINOLENE In vivo Not mutagenic Carcinogenicity Name Route Species Value terpenes AND terpenoids, SWEET Ingestion Rat Some positive data exist, but the data are not Page 6 of 9
sufficient for TERPINOLENE Ingestion Rat Some positive data exist, but the data are not sufficient for Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration terpenes AND terpenoids, SWEET Ingestion Not toxic to male reproduction Rat NOAEL 150 terpenes AND terpenoids, SWEET terpenes AND terpenoids, SWEET Ingestion Ingestion Some positive female reproductive data exist, but the Some positive developmental data exist, but the Rat NOAEL 750 Multiple animal species NOAEL 591 TERPINOLENE Ingestion Not toxic to male reproduction Rat NOAEL 150 TERPINOLENE Ingestion Some positive female reproductive data Rat NOAEL 750 exist, but the TERPINOLENE Ingestion Some positive developmental data exist, but the Multiple animal species NOAEL 591 premating & during gestation during organogenesi s premating & during gestation during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration terpenes AND terpenoids, SWEET Ingestion nervous system Some positive data exist, but the TERPINOLENE Ingestion nervous system Some positive data exist, but the NOAEL Not available NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration terpenes AND terpenoids, SWEET terpenes AND terpenoids, SWEET terpenes AND terpenoids, SWEET Ingestion kidney and/or bladder Some positive data exist, but the Ingestion liver Some positive data exist, but the Ingestion heart endocrine system bone, teeth, nails, and/or hair hematopoietic system immune system muscles nervous system respiratory system TERPINOLENE Ingestion kidney and/or bladder Rat LOAEL 75 Mouse NOAEL 1,000 All data are negative Rat NOAEL 600 Some positive data exist, but the TERPINOLENE Ingestion liver Some positive data exist, but the TERPINOLENE Ingestion heart endocrine system bone, teeth, nails, and/or hair hematopoietic system immune system muscles nervous system Rat LOAEL 75 Mouse NOAEL 1,000 All data are negative Rat NOAEL 600 Page 7 of 9
respiratory system Aspiration Hazard Name terpenes AND terpenoids, SWEET TERPINOLENE Value Aspiration hazard Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information A 3M Product Environmental Data Sheet (PED) is available. Chemical fate information A 3M Product Environmental Data Sheet (PED) is available. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of waste product in a permitted industrial waste facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. EPA Hazardous Waste Number (RCRA): Not regulated SECTION 14: Transport Information For Transport Information, please visit http://3m.com/transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - No Delayed Hazard - No 15.2. State Regulations 15.3. Chemical Inventories The components of this product are in compliance with the new substance notification requirements of CEPA. The components of this material are in compliance with the China "Measures on Environmental Management of New Chemical Substance". Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Philippines RA 6969 requirements. Certain restrictions may apply. Contact the selling division for additional information. The components of this product are in compliance with the chemical notification requirements of TSCA. Page 8 of 9
15.4. International Regulations This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 0 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: 2 Flammability: 0 Physical Hazard: 0 Personal Protection: X - See PPE section. Hazardous Material Identification System (HMIS III) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS III ratings are to be used with a fully implemented HMIS III program. HMIS is a registered mark of the American Coatings Association (ACA). Document Group: 20-4453-5 Version Number: 5.01 Issue Date: 02/23/15 Supercedes Date: 02/23/15 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3m.com Page 9 of 9