( 0 Issue date: 6/0/205 (6/0/205 Section. Identification of the substance or the mixture and of the supplier. Product Identifier Product identifier: Other identifiers: (Contains:CINNAMAL, DELTA-DAMASCONE, EUGENOL, LIMONENE None.2 Relevant identified uses of the substance of mixture and uses advised against Product uses:.3 Details of the supplier of the safety data sheet Company name: Company address: Happy Olive Limited 20 The Grove Fartown Huddersfield HD2 BL UK Contact: E-Mail address: Company phone:.4 Emergency telephone number (Office hours: Monday to Thursday 09.00 to 7.30 Friday 09.00 to 5.00 sarah.janes3@ntlworld.com +44 (0 484 3004 Emergency phone: Outside Office Hours: +44 7952 03628 2. Classification of the substance or mixture Section 2. Hazards identification Classification under Regulation (EC No 272/2008 Class and category of danger: Flammable Liquid, Hazard Category 3 Skin Corrosion / Irritation Category 2 Eye Damage / Irritation Category 2 Sensitization - Skin Category Aspiration Hazard Category Hazardous to the Aquatic Environment - Acute Hazard Category Hazardous to the Aquatic Environment - Long-term Hazard Category H226, Flammable liquid and vapour. H304, May be fatal if swallowed and enters airways. H35, Causes skin irritation. H37, May cause an allergic skin reaction. H39, Causes serious eye irritation. H40, Very toxic to aquatic life with long lasting effects.
2 ( 0 Issue date: 6/0/205 (6/0/205 39072 Class and category of danger: Hazard symbols: Risk phrases: Classification under Directive 999/45/EC Xn, Harmful. N, Dangerous for the environment. R0, Flammable. R38, Irritating to the skin. R43, May cause sensitisation by skin contact. R65, Harmful: May cause lung damage if swallowed R50/53, Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 2.2 Label elements Signal word: Hazard statements: Supplemental Information: Precautionary statements: Danger H226, Flammable liquid and vapour. H304, May be fatal if swallowed and enters airways. H35, Causes skin irritation. H37, May cause an allergic skin reaction. H39, Causes serious eye irritation. H40, Very toxic to aquatic life with long lasting effects. None P20, Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P233, Keep container tightly closed. P240, Ground/bond container and receiving equipment. P24, Use explosion-proof electrical, ventilating and lighting equipment. P242, Use only non-sparking tools. P243, Take precautionary measures against static discharge. P26, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P30/30, IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P303/36/353, IF ON SKIN (or hair: Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P305/35/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P33, Do not induce vomiting. P333/33, If skin irritation or rash occurs: Get medical advice/attention.
3 ( 0 Issue date: 6/0/205 (6/0/205 P337/33, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P370/378, In case of fire: Use carbon dioxide, dry chemical, foam for extinction. P39, Collect spillage. P403/235, Store in a well-ventilated place. Keep cool. P405, Store locked up. P50, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: Other hazards: None Section 3. Composition / information on ingredients 3.2 Mixtures Contains: Name CAS EC REACH Registration No. % Classification for (DSD 67/548/EEC Classification for (CLP 272/2008
4 ( 0 Issue date: 6/0/205 (6/0/205 LIMONENE CINNAMAL EUGENOL 5989-27-5 227-83-5 50-00% 04-55-2 203-23-9 0-<5% Xn-N ; R0-R38-R43-R65- R50/53 Xn ; R2-R38-R43 FL 3-SCI 2-SS B-AH -EH A-EH C;H226-H304- H35-H37-H40,- ATD 4-SCI 2-EDI 2-SS A; H32-H35-H37-H39,- 97-53-0 202-589- 0-<5% Xi ; R36-R43 EDI 2-SS B;H37-H39,- DECANAL 2-3-2 203-957-4 5-<0% N ; R5/53 EDI 2-EH C3;H39-H42,- 2-t- BUTYLCYCLOHEXYL ACETATE MYRCENE VANILLIN 2-33-5 204-465-2 -<3% Xi ; R36 EDI 2;H39,- TRIDEC-2- ENENITRILE DELTA-DAMASCONE TRIMETHYLCYCLOP ENTENYL DIMETHYLISOPENTE NOL GAMMA UNDECALACTONE FARNESENE BISABOLENE ALPHA-PINENES TERPINOLENE 88-4-5 20-828-7 -<3% N ; R5/53 EH C2;H4,- 23-35-3 204-622-5 -<3% Xn ; R0-R38-R65 FL 3-SCI 2-EDI 2-AH ; H226-H304-H35-H39,- 22629-49-8 245-42-6 0.-<% N ; R50/53 EH A-EH C;H40,- 57378-68-4 260-709-8 0.-<% ATO 4-SCI 2-SS A-EH A-EH C;H302-H35- H37-H40,- 07898-54- 4 4-580-3 0.-<% Xn-N ; R22-R38-R43- R50/53 Xi-N ; R38-R50/53 SCI 2-EH A-EH C;H35- H40,- 04-67-6 203-225-4 0.-<% N ; R5/53 EH C3;H42,- 8794-84-8 242-582-0 <0.% Xn ; R65 AH ;H304,- 495-62-5 207-805-8 <0.% 80-56-8 20-29-9 <0.% 586-62-9 209-578-0 <0.% Substances with Community workplace exposure limits, not listed above: Xn ; R38-R43-R65 Xn ; R0-R38-R43-R65 Xn-N ; R43-R65-R50/53 SCI 2-SS B-AH ;H304- H35-H37,- FL 3-SCI 2-SS B-AH ; H226-H304-H35-H37,- FL 3-SS B-AH -EH A- EH C;H226-H304-H37- H40,- Name BHT (BUTYLATED HYDROXYTOLUENE CAS EC % 28-37-0 204-88-4 0.00% DIETHYL PHTHALATE 84-66-2 20-550-6 0.43% Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.%: Not Applicable 4. Description of first aid measures Section 4. First-aid measures IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair: Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 4.2 Most important symptoms and effects, both acute and delayed May be fatal if swallowed and enters airways. Causes skin irritation.
5 ( 0 Issue date: 6/0/205 (6/0/205 May cause an allergic skin reaction. Causes serious eye irritation. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4. for further information. 5. Extinguishing media SECTION 5: Firefighting measures Suitable media: Carbon dioxide, Dry chemical, Foam. 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. Section 6. Accidental release measures 6. Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil. 6.3 Methods and material for containment and cleaning up: Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. 6.4 Reference to other sections: Also refer to sections 8 and 3. 7. Precautions for safe handling: Section 7. Handling and storage Keep away from heat, sparks, open flames and hot surfaces. - No smoking. 7.2 Conditions for safe storage, including any incompatibilities: Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge.
6 ( 0 Issue date: 6/0/205 (6/0/205 7.3 Specific end use(s: Use in accordance with good manufacturing and industrial hygiene practices. 8. Control parameters Workplace exposure limits: Section 8. Exposure controls/personal protection Ingredient CAS EC Description ppm mg/m³ Reference BHT (BUTYLATED HYDROXYTOLUENE 28-37-0 204-88- 4 Long-term exposure limit (8-hour TWA reference period Short-term exposure limit (5- minute reference period - 0 - - UK EH40 Oct 2007 UK EH40 Oct 2007 DIETHYL PHTHALATE 84-66-2 20-550- 6 Long-term exposure limit (8-hour TWA reference period Short-term exposure limit (5- minute reference period - 5-0 UK EH40 Oct 2007 UK EH40 Oct 2007 8.2 Exposure Controls Eye / Skin Protection Wear protective gloves/eye protection/face protection Respiratory Protection Ensure adequate and ongoing ventilation is maintained in order to prevent build up of excessive vapour and to ensure occupational exposure limits are adhered to. If appropriate, and depending on your patterns and volumes of use, the following engineering controls may be required as additional protective measures: a Isolate mixing rooms and other areas where this material is used or openly handled. Maintain these areas under negative air pressure relative to the rest of the plant. b Employ the use of Personal protective equipment - an approved, properly fitted respirator with organic vapour cartridges or canisters and particulate filters. c Use local exhaust ventilation around open tanks and other open sources of potential exposures in order to avoid excessive inhalation, including places where this material is openly weighed or measured. In addition, use general dilution ventilation of the work area to eliminate or reduce possible worker exposures. d Use closed systems for transferring and processing this material. Also refer to Sections 2 and 7. 9. Information on basic physical and chemical properties Appearance: Odour: ph: Initial boiling point / range: Flash point: 50 C Vapour pressure: Section 9. Physical and chemical properties Clear pale yellow to yellow liquid Not determined Not determined Not determined Not determined
7 ( 0 Issue date: 6/0/205 (6/0/205 Relative density: 0.8920-0.9000 Solubility(ies: Not determined 9.2 Other information: None available Section 0. Stability and reactivity 0. Reactivity: Presents no significant reactivity hazard, by itself or in contact with water. 0.2 Chemical stability: Good stability under normal storage conditions. 0.3 Possibility of hazardous reactions: Not expected under normal conditions of use. 0.4 Conditions to avoid: Avoid extreme heat. 0.5 Incompatible materials: Avoid contact with strong acids, alkalis or oxidising agents. 0.6 Hazardous decomposition products: Not expected.. Information on toxicological effects Section. Toxicological information This mixture has not been tested as a whole for health effects. The health effects have been calculated using the methods outlined in Regulation (EC No 272/2008 (CLP. May be fatal if swallowed and enters airways. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Assumed Toxicity Value (LD50 or ATE for Acute Oral Toxicity: >5000 Assumed Toxicity Value (LD50 or ATE for Acute Dermal Toxicity: >5000 Assumed Toxicity Value (LC50 or ATE for Acute Inhalation Toxicity: Inhalation Route: Information about hazardous ingredients in the mixture Not Available Not Available Ingredient CAS EC LD50/ATE Oral LD50/ATE Dermal LC50/ATE Inhalation LC50 Route CINNAMAL 04-55-2 203-23-9 2500 00 Not available Not available
8 ( 0 Issue date: 6/0/205 (6/0/205 Refer to Sections 2 and 3 for additional information. Section 2. Ecological information 2. Toxicity: Very toxic to aquatic life with long lasting effects. 2.2 Persistence and degradability: Not available 2.3 Bioaccumulative potential: Not available 2.4 Mobility in soil: Not available 2.5 Results of PBT and vpvb assessment: This substance does not meet the PBT/vPvB criteria of REACH, annex XIII. 2.6 Other adverse effects: Not available 3. Waste treatment methods: Section 3. Disposal considerations Dispose of in accordance with local regulations. Avoid disposing into drainage systems and into the environment. Empty containers should be taken to an approved waste handling site for recycling or disposal. Section 4. Transport information 4. UN number: UN69 4.2 UN Proper Shipping Name: EXTRACTS, AROMATIC, LIQUID 4.3 Transport hazard class(es: 3 Sub Risk: - 4.4. Packing Group: III 4.5 Environmental hazards: This is an environmentally hazardous substance. 4.6 Special precautions for user: None additional 4.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable Section 5. Regulatory information 5. Safety, health and environmental regulations/legislation specific for the substance or mixture None additional 5.2 Chemical Safety Assessment A Chemical Safety Assessment has not been carried out for this product. Section 6. Other information
9 ( 0 Issue date: 6/0/205 (6/0/205 Concentration % Limits: Total Fractional Values: Key to revisions: EH A=37.4% EH C=37.4% EH C2=3.70% EH C3=0.37003739% EH C4=33.59% SCI 2=3.27% EDI 2=36.50% EDI 2A=36.50% SS =. 00000000% AH =5.27% EH A=2.69 EH C=2.69 EH C2=27.00 EH C3=270.24 EH C4=2.98 SCI 2=7.54 EDI 2=2.74 EDI 2A=2.74 SS =00.00 AH =6.55 Not applicable Key to abbreviations: Abbreviation Meaning AH Aspiration Hazard Category ATD 4 Acute Toxicity - Dermal Category 4 ATO 4 Acute Toxicity - Oral Category 4 EDI 2 Eye Damage / Irritation Category 2 EH A Hazardous to the Aquatic Environment - Acute Hazard Category EH C Hazardous to the Aquatic Environment - Long-term Hazard Category EH C2 Hazardous to the Aquatic Environment - Long-term Hazard Category 2 EH C3 Hazardous to the Aquatic Environment - Long-term Hazard Category 3 FL 3 Flammable Liquid, Hazard Category 3 H226 Flammable liquid and vapour. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H32 Harmful in contact with skin. H35 Causes skin irritation. H37 May cause an allergic skin reaction. H39 Causes serious eye irritation. H40 Very toxic to aquatic life with long lasting effects. H4 Toxic to aquatic life with long lasting effects. H42 Harmful to aquatic life with long lasting effects. P20 Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P24 Use explosion-proof electrical, ventilating and lighting equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P26 Avoid breathing vapour or dust. P264 Wash hands and other contacted skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/eye protection/face protection. P30/30 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
0 ( 0 Issue date: 6/0/205 (6/0/205 P30/32 IF SWALLOWED: call a POISON CENTER or doctor/physician if you feel unwell. P302/352 IF ON SKIN: Wash with plenty of soap and water. P303/36/353 P305/35/338 P32 P330 P33 IF ON SKIN (or hair: Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTRE or doctor/physician if you feel unwell. Rinse mouth. Do not induce vomiting. P332/33 If skin irritation occurs: Get medical advice/attention. P333/33 If skin irritation or rash occurs: Get medical advice/attention. P337/33 If eye irritation persists: Get medical advice/attention. P362 P363 Take off contaminated clothing and wash before reuse. Wash contaminated clothing before reuse. P370/378 In case of fire: Use carbon dioxide, dry chemical, foam for extinction. P39 Collect spillage. P403/235 Store in a well-ventilated place. Keep cool. P405 P50 Store locked up. SCI 2 Skin Corrosion / Irritation Category 2 SS A SS B Dispose of contents/container to approved disposal site, in accordance with local regulations. Sensitization - Skin Category A Sensitization - Skin Category B The information in this safety data sheet is to the best of our knowledge true and accurate but all data, instructions, recommendations and/or suggestions are made without guarantee.