Criterias for 10001 17.October 2012 Ecological criteria for the procurement of cleaning agents
Ecological criteria for the procurement of cleaning agents (10001/17.10.2012) 1. Introduction Important objectives regarding implementation of environmental protection in the facilities of the Vienna City Administration include reduction of resource consumption (e.g. energy), prevention of substances harmful to the environment, prevention and reduction of waste, the ecologically appropriate treatment of unavoidable waste, as well as reduction of noise and hazardous substances. The application of the following criteria especially contributes to the reduction in use of substances that are harmful to the environment and human health in cleaning. Information for users The following minimum requirements shall not apply to disinfectants, disinfectant cleaners nor to special cleaning products. Dishwasher detergent and rinse aid shall be procured from the same producer so that substances and dosage are adjusted correctly. The use of rinse aid shall always be scrutinised. If bleaching is necessary with dishwasher detergents, no bleaching agents containing chlorine shall be used. Factory coated linoleum and rubber floors (e.g. polyurethane and acrylate coatings) usually do not need any initial care and therefore any basic cleaning either. However, if initial care is absolutely necessary, the respective care products for non-factory coated linoleum and rubber floors can be used. The basic cleaning agent should be adjusted to the initial care product in order to ensure ideal cleaning results. In this case it is recommended to use the products by the same producer. It shall be defined whether basic and initial cleaning agents need to be suitable for scrubbing machines. It shall be defined for how long the protective layer of the initial care product needs to last. If durability of the protective layer of the care products against disinfectants and alcohol is required, it shall additionally be stated. The type of product shall be defined (powder or liquid). The required pack size shall be defined (in litres). When comparing different quotations, the prices of the utility solutions shall be used. For floor cleaning agents (basic, initial, floor care) the capacity (per 100 m 2 ) shall be taken into account. 2
The only microorganisms allowed in sanitary cleaning agents are those intentionally added by the producer. They need to be indicated on the label and shall only contain microorganisms of risk group 1 (according to the definition of biological agents at work as stated in the Workers Protection Act - ASchG 1 and in the ordinance on biological agents at work - VbA 2 ). Proof shall be provided by the tenderer. Expert reports shall exclude sensitizing effects. 1 Federal Law on Health and Safety at Work (Workers Protection Act) (Bundesgesetz über Sicherheit und Gesundheitsschutz bei der Arbeit (ArbeitnehmerInnenschutzgesetz - ASchG) in the applicable version 2 Ordinance of the Federal Minister of Labour, Health and Social Affairs on the protection of workers against the risks related to exposure to biological agents at work (Verordnung der Bundesministerin für Arbeit, Gesundheit und Soziales über den Schutz der Arbeitnehmer/innen gegen Gefährdung durch biologische Arbeitsstoffe (Verordnung biologische Arbeitsstoffe - VbA) in the applicable version. 3
2. Product groups This criteria list contains minimum requirements for: Laundry detergents Heavy-duty detergent Colour detergent Cleaning and care agents Universal cleaning agent (all-purpose cleaner) Intensive cleaner Dishwasher detergent and rinse aid - Powder dishwasher detergent for household dishwashers - Liquid dishwasher detergent for commercial dishwashers - Wash-up liquid for manual cleaning - Rinse aid Abrasive cleaner (liquid) Floor wiping care Sanitary cleaner Glass cleaner Alcohol-based cleaner Cleaner for scrubbing machines Basic cleaners (floor) and initial treatment agents Basic cleaner - Basic cleaner for removing the initial treatment agent of polyolefin-, natural stone, artificial stone and PVC floors - Basic cleaner for removing the initial treatment agent of non-factory coated linoleum and rubber floors - Initial treatment agent for the initial treatment of polyolefin, natural stone, artificial stone and PVC floors and non-factory coated linoleum and rubber floors 4
3. Minimum requirements of products 3.1. Laundry detergents 3.1.1. Heavy-duty detergents Heavy-duty detergents shall be used for washing laundry with a washing machine excluding wool and silk. It shall be suitable for temperatures between 30 to 90 C and chlorine-free. 3.1.2. Colour detergents Colour detergents shall be used for washing colour laundry with temperatures between 30 to 60 C (without bleach). 3.2. Cleaning and care agents 3.2.1. Universal cleaning agents (all-purpose cleaners) This product shall be used for wiping all kinds of objects and water-resistant surfaces that have a normal degree of soiling. It shall thoroughly remove all kinds of dirt as well as light amounts of limescale. The cleaned surface shall dry without leaving any streaks or residues. Its ph value shall only range between 6 and 10. 3.2.2. Intensive cleaners This product shall be used for rinsing all kinds of objects and water-resistant surfaces of a heavy degree of soiling. It shall thoroughly remove all kinds of heavy dirt as well as light amounts of limescale. The cleaned surface shall dry without leaving any streaks or residues. Its ph value shall only range between 8 and 10.5. 3.2.3. Dishwasher detergents and rinse aids 3.2.3.1. Powder dishwasher detergents for household dishwashers The product shall be suitable for washing dishes with a household dishwasher (not for manual washing of dishes), it shall be hard water resistant, low in dust, easy to dose and produce little foam. It shall clean the dishes effectively, dissolve grease and conserve the dishes. 5
3.2.3.2. Liquid detergents for commercial dishwashers The product shall be suitable for hygienic machine dishwashing in commercial dishwashers (not for manual dish washing). This low-foam detergent shall emulsify fatty residues and encrustations. 3.2.3.3. Liquid detergents for manual dishwashing The product shall be suitable for manual dishwashing and mild on skin. It shall emulsify fatty residues and encrustations. 3.2.3.4. Rinse aids The product shall be slightly acidic, have a self-drying effect and be suitable for machine dishwashing. The product shall guarantee a residue-free drying of the dishes and shall not produce foam. 3.2.4. Abrasive cleaners (liquid) Abrasive cleaners are to be used for removing soiling on all water-resistant surfaces and objects. Its ph value shall only range between 8 and 10. 3.2.5. Floor wiping care products Floor wiping care products shall be used for cleaning and caring for all water-resistant hard floors (e.g. linoleum, rubber, synthetic material, natural stone and artificial stone, sealed wooden flooring). The product shall have a cleaning, caring and surface-friendly effect; it shall be easy and fast to use. Furthermore, residues shall be easy to remove and polish. It shall have anti-slip properties. 3.2.6. Sanitary cleaners Sanitary cleaners shall be used for the cleaning of acid-resistant surfaces such as chromium fittings, wash basins, toilet bowls, acid-resistant enamel, acidic-resistant wall and floor coverings, anodised window frames, glass, synthetic material or stainless steel. The product shall remove limescale, encrusted dirt, lime soap, skin fat, light oil and fatty residues in toilets, bath tubs, etc. in one go and dry spotlessly. Its ph value shall only range between 2 and 6. 6
3.2.7. Glass cleaners The cleaner shall be ready to use, suitable for glass and all smooth surfaces and shall clean in a streak-free manner. 3.2.8. Alcohol-based cleaners (gloss cleaner) The cleaner shall be suitable for all washable, hard and glossy surfaces and shall clean in a streakfree and quick-drying manner. 3.2.9. Cleaners for scrubbing machines The product shall be used for water-resistant floorings with heavy soiling, as well as in scrubbing machines. It shall be a low-foam cleaner, the surface shall dry quickly and remain streak-free. Its ph value shall only range between 8 and 11. 3.3. Basic cleaners (floor) and initial treatment agents 3.3.1. Basic cleaners (floor) 3.3.1.1. Basic cleaners for the removal of initial treatment of polyolefin, natural stone, artificial stone and PVC floors The product shall remove initial treatment agents (e.g. wax and polymer coatings), as well as heavy soiling (e.g. oil and fatty encrustation). Its ph value shall only range between 10 and 13.5. 3.3.1.2. Basic cleaners for the removal of initial treatment of non-factory coated linoleum and rubber floors The product shall remove initial treatment agents (e.g. wax and polymer coatings), as well as heavy soiling (e.g. oil and fatty encrustation). Its ph value shall only range between 10 and 11. 3.3.2. Basic cleaner for initial treatment of polyolefin, natural stone, artificial stone and PVC floors and non-factory coated linoleum and rubber floors The product shall create a durable surface with good abrasion resistance and a specified date of minimum durability. The protective layer shall be stain repellent, resistant to wiping, remove traces, dry quickly and be slip resistant. Electrical conductivity and slip resistance (R rating) of the floor shall not be negatively altered by applying the initial treatment agent. 7
4. Content limits of the products The following pages list the minimum requirements for the exclusion of substances in laundry detergents, cleaning agents and care products, as well as basic cleaners (floor) and initial treatment agents. For reasons particularly concerning the protection of workers, the content limits of the respective substances refer to undiluted products (solutions and concentrates). The content limits specified in the minimum requirements shall not be exceeded. Requirements for concentrates Water content in liquid product shall not exceed 7. The solution produced with the concentrate shall make it possible to stay below the given limits for solutions when adhering to the specified dose of the producer. Concentrate containers shall be labelled in such a way that it is clear that the concentration may only be used with an appropriate dosing system. The system shall prevent the user s direct contact with the concentrate. It shall be a closed and/or automatic dosing system. The users shall not come into contact with the concentrate during dosing. The applied dosage (for normal soiling) shall not exceed 0.5 % by weight. The dosing system shall have a tolerance of max. ± 10 %. Additionally, the words concentrate or concentrated shall be stated and clearly legible on the label. It can be part of the product name or printed as additional clarification on the label. The label shall show the dosage recommendation in a sufficiently large size. 8
4.1. Content limits for laundry detergents Alkalis Solutions Concentrates KOH (potassium hydroxide) < 5 % by weight no restrictions NaOH (sodium hydroxide) Sodium Metasilicate Ammonia and Ammonia Donor Bleach Solutions Concentrates Hydrogen Peroxide, Sodium Percarbonate < 1 no restrictions Chlorine-based bleach, Perborates Builders Solutions Concentrates Iminodisuccinate, Methyl Glycine Diacetate (MGDA), Sodium Gluconate, Poly Aspartic Acid and salts thereof, Tetra Sodium Glutamate Diacetate (GLDA), Zeolites, Citrates Sodium Disilicate, layered Sodium Silicates < 3 < 3 < 3 < 3 Polycarboxylates and other polymeres < 5 % by weight < 5 % by weight Phosphonates < 1 % by weight < 5 % by weight Ethylene Diamintetraacetate (EDTA), Phosphates, Nitrilotriacetate (NTA) Organic solvents The respective CAS numbers shall be stated in brackets for clear identification. Solutions Concentrates Sum total of organic solvents < 3 no restrictions 9
Group 1: Butoxypropanol (CAS 5131-66-8), Butyrolactone (CAS 96-48-0), 1-tert-Butoxy-2- propanol (CAS 57018-52-7), Diethylene Glycol Dibutyl Ether (CAS 112-73-2), Dipropylene Glycole (CAS 110-98-5), Dipropylene Glycol Dimethyl Ether (CAS 111109-77-4), Dipropylene Glycole Monobutylether (CAS 24083-03-2: 1-(2- Butoxypropoxy)propan-2-ol and CAS 29911-28-2: 1- (2-Butoxy-1-methylethoxy)propan-2-ol), Ethanol (CAS 64-17-5), 1-Propanol (CAS 71-23-8), 2-Propanol (CAS 67-63-0), Propylene Glycol (CAS 57-55-6), Triethylene Glycol (CAS 112-27-6) Sum total of solvents of group 2 Group 2: 1-Butanol (CAS 71-36-3), 2-Butanol (CAS 78-92-2), Diethylene Glycol (CAS 111-46-6), Diethylene Glycol Monoethyl Ether (CAS 111-90-0), Diethylene Glycol Monobutyl Ether (CAS 112-34-5), Dipropylene Glycol Monomethyl Ether (CAS 34590-94-8), Ethylene Glycol (CAS 107-21-1), 1-Methoxy-2- propanol (CAS 107-98-2) < 3 no restrictions < 1 < 1 < 5 % by weight < 5 % by weight Ethanolamine (141-43-5), Triethanolamine (102-71-6) < 1 % by weight < 5 % by weight Group 3: Acetone (CAS 67-64-1), white spirit free from aromatic hydrocarbons, Butyl glycol (CAS 111-76-2), aromatic hydrocarbons (CAS 90989-39-2), Benzyl Alcohol (CAS 100-51-6), Diethylene Glycol Dimethyl Ether (CAS 111-96-6), Ethyl Glycol (CAS 110-80-5), Ethyl Glycol Acetate (CAS 111-15-92), halogenated organic compounds, light low boiling point aliphatic naphtha (CAS 64742-89-8), Methanol (CAS 67-56-1), Methyl Glycol (CAS 109-86-4), Methyl Glycol Acetate (CAS 110-49-6), Methyl Diglycol (CAS 111-77-3), N-Methyl-2-pyrrolidon (CAS 872-50-4), Propylene Glycol-2-Methyl Ether (CAS 1589-47-5), Turpentine oil (CAS 8006-64-2), white spirit 10
Diethanolamine (CAS 111-42-2) Neutral salts Solutions Concentrates Potassium Chloride, Calcium Chloride, Magnesium Silicate, Magnesium Sulphate, Sodium Chloride, Sodium Sulphate < 1 < 1 Acids Solutions Concentrates Adipic Acid, Malic Acid, Glutaric Acid, Lactic Acid, Sodium Bisulphate, Tartaric Acid, Citric Acid Acetic Acid Sulfamic Acid, Salicylic Acid Glycolic Acid, Glyoxylic Acid, Oxalic Acid, Phosphoric Acid < 3 no restrictions < 2 no restrictions < 1 no restrictions < 5 % by weight no restrictions Formic Acid, Hydrochloric Acid, Sulphuric Acid < 1 % by weight no restrictions Boric Acid, Nitric Acid Surfactants Solutions Concentrates Quaternary Ammonium Surfactants Alkylphenol and Arylphenol Ethoxylate (APEO) Surfactants, which are classified as R50/53 and R51/53, or as H410 and H411 Surfactants, which need special authorisation according to Article 4 of Regulation (EC) 648/2004 on detergents Preservatives Solutions Concentrates 11
Sorbic Acid and its salts, Benzoic Acid and its salts, < 1 % by weight < 1 % by weight 2-Phenoxyethanol (Ethylene Glycol Monophenyl Ether) Isothiazolinones (not halogenated) < 0.1 % by weight < 0.1 % by weight Other preservatives permitted according to the EC directive on biocides < 0.1 % by weight < 0.1 % by weight Formaldehyde and its donors, quaternary Ammonium Compounds, halogenated organic compounds (exemption: Chlorisothiazolinone, i.e. also Kathon CG, permitted up to 15 ppm), Biguanides Additives Solutions Concentrates Tetraacetylethylenediamine (TAED) Carboxymethyl cellulose (CMC) < 3 < 3 < 1 < 1 Enzymes (Amylases, Lipases, Cellulases) < 5 % by weight < 5 % by weight Sum total of all enzymes < 1 < 1 Polyvinylpyrrolidone (PVP) < 1 % by weight < 1 % by weight Aromatic substances (except Paradichlorobenzene, nitro musk compounds and polycyclic musk compounds) < 1 % by weight < 1 % by weight Colourants (except azo dyes listed in annex XVII of REACH Restricted Substances List) < 0.1 % by weight < 0.1 % by weight Paradichlorobenzene, Nitro Musk compounds and polycyclic musk compounds Azo dyes listed in annex XVII of REACH Restricted Substances List Disinfectants 12
Halogenated hydrocarbons Microorganisms (probiotic) Fatty amines 4.2. Content limits for cleaning and care agents Alkalis Solutions Concentrates Sodium Metasilikat in dishwasher detergents < 3 no restrictions Sodium Metasilikat in all other products < 5 % by weight no restrictions KOH (potassium hydroxide), NaOH (sodium hydroxide) < 5 % by weight no restrictions Ammonia and Ammonia Donor Bleach Solutions Concentrates Hydrogen Peroxide, Sodium Percarbonate < 1 no restrictions Chlorine-based bleach, Perborates Builders Solutions Concentrates Sodium Disilicate, layered Sodium Silicates Iminodisuccinate, Methyl Glycine Diacetate (MGDA), Sodium Gluconate, Poly Aspartic Acid and salts thereof, Tetra Sodium Glutamate Diacetate (GLDA), Zeolites, Citrates < 3 < 3 < 3 < 3 Phosphonates in dishwasher detergents < 1 < 1 Phosphonates in all other products < 5 % by weight < 5 % by weight Polycarboxylates and other polymeres < 5 % by weight < 5 % by weight 13
Phosphates in dishwasher detergents < 1 < 1 Phosphate in all other products Ethylene Diamintetraacetate (EDTA), Phosphates, Nitrilotriacetate (NTA) Organic solvents The respective CAS numbers shall be stated in brackets for clear identification. Solutions Concentrates Sum total of organic solvents Group 1: Butoxypropanol (CAS 5131-66-8), Butyrolactone (CAS 96-48-0), 1-tert-Butoxy-2- propanol (CAS 57018-52-7), Diethylene Glycol Dibutyl Ether (CAS 112-73-2), Dipropylene Glycole (CAS 110-98-5), Dipropylene Glycol Dimethyl Ether (CAS 111109-77-4), Dipropylene Glycole Monobutylether (CAS 24083-03-2: 1-(2- Butoxypropoxy)propan-2-ol and CAS 29911-28-2: 1- (2-Butoxy-1-methylethoxy)propan-2-ol), Ethanol (CAS 64-17-5), 1-Propanol (CAS 71-23-8), 2-Propanol (CAS 67-63-0), Propylene Glycol (CAS 57-55-6), Triethylene Glycol (CAS 112-27-6) Sum total of solvents of group 2 Group 2: 1-Butanol (CAS 71-36-3), 2-Butanol (CAS 78-92-2), Diethylene Glycol (CAS 111-46-6), Diethylene Glycol Monoethyl Ether (CAS 111-90-0), Diethylene Glycol Monobutyl Ether (CAS 112-34-5), Dipropylene Glycol Monomethyl Ether (CAS 34590-94-8), Ethylene Glycol (CAS 107-21-1), 1-Methoxy-2- propanol (CAS 107-98-2) Mono- (CAS 141-43-5), Triethanolamin (CAS 102-71- 6) < 3 no restrictions < 3 no restrictions < 1 < 1 < 5 % by weight < 5 % by weight < 1 % by weight < 5 % by weight 14
Group 3: Acetone (CAS 67-64-1), white spirit free from aromatic hydrocarbons, Butyl glycol (CAS 111-76-2), aromatic hydrocarbons (CAS 90989-39-2), Benzyl Alcohol (CAS 100-51-6), Diethylene Glycol Dimethyl Ether (CAS 111-96-6), Ethyl Glycol (CAS 110-80-5), Ethyl Glycol Acetate (CAS 111-15-92), halogenated organic compounds, light low boiling point aliphatic naphtha (CAS 64742-89-8), Methanol (CAS 67-56-1), Methyl Glycol (CAS 109-86-4), Methyl Glycol Acetate (CAS 110-49-6), Methyl Diglycol (CAS 111-77-3), N-Methyl-2-pyrrolidon (CAS 872-50-4), Propylene Glycol-2-Methyl Ether (CAS 1589-47-5), Turpentine oil (CAS 8006-64-2), white spirit Diethanolamine (CAS 111-42-2) Neutral salts Solutions Concentrates Potassium Chloride, Calcium Chloride, Magnesium Silicate, Magnesium Sulphate, Sodium Chloride, Sodium Sulphate < 1 < 1 Acids Solutions Concentrates Adipic Acid, Malic Acid, Glutaric Acid, Lactic Acid, Sodium Bisulphate, Tartaric Acid, Citric Acid Acetic Acid Sulfamic Acid, Salicylic Acid Glycolic Acid, Glyoxylic Acid, Oxalic Acid, Phosphoric Acid < 3 no restrictions < 2 no restrictions < 2 no restrictions < 5 % by weight no restrictions Formic Acid, Hydrochloric Acid, Sulphuric Acid < 1 % by weight no restrictions Boric Acid, Nitric Acid 15
Surfactants Solutions Concentrates Quaternary Ammonium Surfactants Alkylphenol and Arylphenol Ethoxylate (APEO) Surfactants, which are classified as R50/53 and R51/53, or as H410 and H411 Surfactants, which need special authorisation according to Article 4 of Regulation (EC) 648/2004 on detergents Softeners Solutions Concentrates Phthalates (e.g. Di(ethylhexyl) phthalate (DEHP)) Other softeners such as citric acid ester and lactic acid ethyl ester < 5 % by weight < 5 % by weight Preservatives Solutions Concentrates Sorbic Acid and its salts, Benzoic Acid and its salts, < 1 % by weight < 1 % by weight 2-Phenoxyethanol (Ethylene Glycol Monophenyl Ether) Isothiazolinones (not halogenated) < 0,1 % by weight < 0,1 % by weight Other preservatives permitted according tot he EC directive on biocides < 0,1 % by weight < 0,1 % by weight Formaldehyde and its donors, quaternary Ammonium Compounds, halogenated organic compounds (exemption: Chlorisothiazolinone, i.e. also Kathon CG, permitted up to 15 ppm), Biguanides Additives Solutions Concentrates Carboxymethyl cellulose (CMC) < 1 < 1 16
Enzymes (Amylases, Lipases, Cellulases) < 5 % by weight < 5 % by weight Sum total of all enzymes Aromatic substances (except Paradichlorobenzene, nitro musk compounds and polycyclic musk compounds) < 1 < 1 < 1 % by weight < 1 % by weight Polyvinylpyrrolidone (PVP) < 1 % by weight < 1 % by weight Colourants (except azo dyes listed in annex XVII of REACH Restricted Substances List) < 0,1 % by weight < 0,1 % by weight Azo dyes listed in annex XVII of REACH Restricted Substances List) Disinfectants Paradichlorobenzene, nitro musk compounds and polycyclic musk compounds Halogenated hydrocarbons Microorganisms in sanitary cleaners (probiotic), hazardous category 1, non-sensitizing no restrictions no restrictions Microorganisms (probiotic), hazardous category > 1 and intentionally added microorganisms in other product groups than sanitary cleaners Fatty amines 4.3. Content limits for basic cleaners (floor) and initial treatment agents Alkalis Sodium Metasilicate KOH (Potassium Hydroxide) Solutions < 1 < 5 % by weight NaOH (Sodium Hydroxide) 17
Ammonia and Ammonia donors Bleach Hydrogen Peroxide, Sodium Percarbonate Chlorine-based bleach, Perborates Solutions < 1 Builders Iminodisuccinate, Methyl Glycine Diacetate (MGDA), Sodium Gluconate, Poly Aspartic Acid and salts thereof, Tetra Sodium Glutamate Diacetate (GLDA), Zeolites, Citrates Sodium Disilicate, layered Sodium Silicates Polycarboxylates and other polymeres Phosphonates Ethylendiamintetraacetat (EDTA), Phosphate, Nitrilotriacetat (NTA) Solutions < 3 < 3 < 5 % by weight < 1 % by weight Organic solvents Solutions The respective CAS numbers shall be stated in brackets for clear identification. Sum total of organic solvents < 3 18
Group 1: Butoxypropanol (CAS 5131-66-8), Butyrolactone (CAS 96-48-0), 1-tert-Butoxy-2- propanol (CAS 57018-52-7), Diethylene Glycol Dibutyl Ether (CAS 112-73-2), Dipropylene Glycole (CAS 110-98-5), Dipropylene Glycol Dimethyl Ether (CAS 111109-77-4), Dipropylene Glycole Monobutylether (CAS 24083-03-2: 1-(2- Butoxypropoxy)propan-2-ol and CAS 29911-28-2: 1- (2-Butoxy-1-methylethoxy)propan-2-ol), Ethanol (CAS 64-17-5), 1-Propanol (CAS 71-23-8), 2-Propanol (CAS 67-63-0), Propylene Glycol (CAS 57-55-6), Triethylene Glycol (CAS 112-27-6) Sum total of solvents of group 2 Group 2: 1-Butanol (CAS 71-36-3), 2-Butanol (CAS 78-92-2), Diethylene Glycol (CAS 111-46-6), Diethylene Glycol Monoethyl Ether (CAS 111-90-0), Diethylene Glycol Monobutyl Ether (CAS 112-34-5), Dipropylene Glycol Monomethyl Ether (CAS 34590-94-8), Ethylene Glycol (CAS 107-21-1), 1-Methoxy-2- propanol (CAS 107-98-2) < 3 < 2 < 1 Ethanolamine (141-43-5), Triethanolamine (102-71-6) < 1 Group 3: Acetone (CAS 67-64-1), white spirit free from aromatic hydrocarbons, Butyl glycol (CAS 111-76-2), aromatic hydrocarbons (CAS 90989-39-2), Benzyl Alcohol (CAS 100-51-6), Diethylene Glycol Dimethyl Ether (CAS 111-96-6), Ethyl Glycol (CAS 110-80-5), Ethyl Glycol Acetate (CAS 111-15-92), halogenated organic compounds, light low boiling point aliphatic naphtha (CAS 64742-89-8), Methanol (CAS 67-56-1), Methyl Glycol (CAS 109-86-4), Methyl Glycol Acetate (CAS 110-49-6), Methyl Diglycol (CAS 111-77-3), N-Methyl-2-pyrrolidon (CAS 872-50-4), Propylene Glycol-2-Methyl Ether (CAS 1589-47-5), Turpentine oil (CAS 8006-64-2), white spirit 19
Diethanolamine (CAS 111-42-2) Neutral salts Potassium Chloride, Calcium Chloride, Magnesium Silicate, Magnesium Sulphate, Sodium Chloride, Sodium Sulphate Solutions < 1 Acids Adipic Acid, Malic Acid, Glutaric Acid, Lactic Acid, Sodium Bisulphate, Tartaric Acid, Citric Acid Acetic Acid Sulfamic Acid, Salicylic Acid Glycolic Acid, Glyoxylic Acid, Oxalic Acid, Phosphoric Acid Formic Acid, Hydrochloric Acid, Sulphuric Acid Boric Acid, Nitric Acid Solutions < 3 < 2 < 2 < 5 % by weight < 1 % by weight Surfactants Quaternary Ammonium Surfactants Alkylphenol and Arylphenol Ethoxylate (APEO) Surfactants, which are classified as R50/53 and R51/53, or as H410 and H411 Surfactants, which need special authorisation according to Article 4 of Regulation (EC) 648/2004 on detergents Solutions Softeners Phthalates (e.g. Di(ethylhexyl) phthalate (DEHP)) Solutions < 5 % by weight 20
Other softeners such as citric acid ester and lactic acid ethyl ester Preservatives Sorbic Acid and its salts, Benzoic Acid and its salts, Solutions < 1 % by weight 2-Phenoxyethanol (Ethylene Glycol Monophenyl Ether) Isothiazolinones (not halogenated) Other preservatives permitted according tot he EC directive on biocides < 0.1 % by weight < 0.1 % by weight Additives Carboxymethylcellulose (CMC) Enzymes (Amylases, Lipases, Cellulases) Sum total of all enzymes Aromatic substances (except Paradichlorobenzene, nitro musk compounds and polycyclic musk compounds) Colourants (except azo dyes listed in annex XVII of REACH Restricted Substances List) Paradichlorobenzene, nitro musk compounds and polycyclic musk compounds Azo dyes listed in annex XVII of REACH Restricted Substances List Disinfectant Halogenated hydrocarbons Fatty amines Solutions < 1 < 5 % by weight < 1 < 1 % by weight < 0.1 % by weight 21
5. Evidence The tenderers shall provide the following proof additionally to the tendered products: 5.1. Laundry detergents Producer Description or name of the product Dosage for normal soiling levels in ml and mg/litre of water Description of dosing aid Safety data sheet, technical data sheet (product data sheet) with information on substances, instructions for use 5.2. Cleaning and care agents 5.2.1. Liquid universal cleaning agents Producer Description or name of the product ph value of utility solution for normal soiling levels Dosage of utility solution for normal soiling levels in ml/litre of water Description of dosing aid Safety data sheet, technical data sheet (product data sheet) with information on substances, instructions for use 5.2.2. Liquid intensive cleaners Producer Description or name of the product ph value of utility solution for normal soiling levels Dosage of utility solution for normal soiling levels in ml/litre of water Description of dosing aid Safety data sheet, technical data sheet (product data sheet) with information on substances, instructions for use 5.2.3. Dishwasher detergents and rinse aid Producer Description or name of the product Dosage in ml or g/litre of water Description of dosing aid 22
Safety data sheet, technical data sheet (product data sheet) with information on substances, instructions for use 5.2.4. Abrasive cleaner (liquid) Producer Description or name of the product ph value of utility solution for normal soiling levels Dosage of utility solution for normal soiling levels in ml/litre of water Description of dosing aid Safety data sheet, technical data sheet (product data sheet) with information on substances, instructions for use 5.2.5. Floor wiping care Producer Description or name of the product ph value of utility solution for normal soiling levels Dosage of utility solution for normal soiling levels in ml/litre of water Description of dosing aid Required litres of utility solution for normal soiling levels per 100 m 2 of floor space Safety data sheet, technical data sheet (product data sheet) with information on substances, instructions for use 5.2.6. Liquid sanitary cleaner Producer Description or name of the product ph value of utility solution for normal soiling levels Dosage of utility solution for normal soiling levels in ml/litre of water Description of dosing aid Safety data sheet, technical data sheet (product data sheet) with information on substances, instructions for use 5.2.7. Glass cleaner Producer Description or name of the product ph value of utility solution for normal soiling levels Dosage of utility solution for normal soiling levels in ml/litre of water Description of dosing aid 23
Safety data sheet, technical data sheet (product data sheet) with information on substances, instructions for use 5.2.8. Alcohol-based cleaner Producer Description or name of the product ph value of utility solution for normal soiling levels Dosage of utility solution for normal soiling levels in ml/litre of water Description of dosing aid Safety data sheet, technical data sheet (product data sheet) with information on substances, instructions for use 5.2.9. Cleaner for scrubbing machines Producer Description or name of the product ph value of utility solution for normal soiling levels Dosage of utility solution for normal soiling levels in ml/litre of water Description of dosing aid Safety data sheet, technical data sheet (product data sheet) with information on substances, instructions for use 5.3. Basic cleaners (floor) and initial treatment agents 5.3.1. Basic cleaner Producer Description or name of the product ph value of utility solution for removing the initial treatment agent Dosage of utility solution for removing the initial treatment agent in ml/litre of water Description of dosing aid Required litres of utility solution for removing the initial treatment agent per 100 m 2 of floor space Safety data sheet, technical data sheet (product data sheet) with information on substances, instructions for use 5.3.2. Initial treatment agent for initial treatment of polyolefin, natural stone, artificial stone, PVC and non-factory coated linoleum and rubber floors Producer 24
Description or name of the product Required litres of initial treatment agent for 100 m 2 of floor space ph value of the utility solution Description of dosing aid Safety data sheet, technical data sheet (product data sheet) with information on substances, instructions for use Data sheets Prevailing data sheets for minimum requirements shall be provided. Minimum requirements not specified in the data sheets are to be produced in the appropriate form upon special request of the ordering party. 6. Packaging Halogenated polymers are in principle undesirable in packaging. Tenderers shall state, whether and in which collection and recycling system according to section 11 of the 1996 Regulation on Packaging, Federal Law Gazette (BGBl.) II No 648/1996 in the applicable version they are participating in. If they are not participating in a collection and recycling system they shall state which measures they take to recollect the packaging put into circulation. 25
ANNEX 1 ABBREVIATION AND DEFINITIONS BGBl CAS Bundesgesetzblatt, Federal Law Gazette Chemical Abstract Service: Registry number for chemical substances 26