Date: 9/5/2008 MSDS ID: 20509 Rev: 1.0.4 Replace: 9/6/2005 Material Safety Data Sheet Material Name: Fire Reitant Mineral Wool Inulation Section 1 Chemical Product and Company Identification Product Name(): MinWool-1200 Board, Flex, Blanket, Pipe, Pipe and Tank MinWool Sound Attenuation Fire Batt, Safing, Curtainwall Manufacturer Information Indutrial Inulation Group MinWool 908 John Buey Drive Phenix City, AL 36869 Web ite: www.iig-llc.com Phone number for Health and Safety Information: 970.858.6211 (M-F, 7:00 a.m. to 4:00 p.m. Mountain Time) Section 2 Compoition and Information on Ingredient OSHA ACGIH NIOSH CAS # Component Percent PEL TLV REL 65997-17-3 Synthetic Vitreou Fiber 95+ 15(T) 5(R) mg/m 3 1f/cc NE 25104-55-6 Cured Urea Formaldehyde/Phenol Binder 0-5 NE NE NE ACGIH TLV are 2006 value. OSHA PEL are thoe in effect on the date of preparation of thi MSDS. The lited PEL, TVL and REL are time weighted average expoure limit. Component Related Regulatory Information Thi product may be regulated, have expoure limit or other information identified a the following: Nuiance Particulate not otherwie regulated, Rock Wool Fiber Section 3 Hazard Identification Emergency Overview: Appearance and Odor: Commercial Board, Batt, and Pipe inulation i olid, green/yellow. Thi product i an article and under normal condition of ue, thi product i not expected to create any unuual emergency hazard. However, cutting, awing, or abrading may increae the rik of peronnel expoure. Inhalation of exceive amount of dut created when fabricating, cutting, or other mechanical alteration of the product may caue temporary upper repiratory irritation and/or congetion remove affected individual to freh air. Skin irritation may be treated by gently wahing affected area with oap and warm water. Eye irritation may be treated by fluhing eye with large amount of water. If irritation perit, contact a phyician. Prolonged contact with dut from thi product may caue Dermatiti. Acrid moke may be generated in a fire, ue normal fire fighting procedure to prevent inhalation of moke and gae. HMIS Rating: Health: 1, Fire: 0, Reactivity 0, Other: 0 NFPA Rating: Health: 1, Flammability: 0, Reactivity: 0 WHMIS Cla: IIG MinWool-1200 product are not controlled product IIG 20509 1 of 6
Potential Health Effect Summary Breathing dut from thi product may caue a cratchy throat, congetion, and light coughing. Getting dut or fiber on the kin, or in the eye may caue itching, rah, or redne. Breathing large amount of dut or fiber from thi product may lead to chronic health effect a dicued in Section 11 of thi material afety data heet. Inhalation: If inhaled, remove the affected peron to freh air. If irritation perit, eek medical attention. Skin Contact: Dut and fiber from thi product may caue temporary mechanical irritation to the kin. Eye Contact: Dut and fiber from thi product may caue temporary mechanical irritation to the eye. Ingetion: Thi product i not intended to be ingeted or eaten under normal condition of ue. If ingeted, it may caue temporary irritation to the gatrointetinal (GI) tract, epecially the tomach. Target Organ Upper repiratory paage, kin, and eye. Primary Route of Entry (Expoure) Inhalation (breathing dut), kin, and eye contact. Medical Condition Aggravated by Expoure: Chronic repiratory or kin condition may temporarily woren from expoure to thi product. Section 4 Firt Aid Meaure Firt Aid: Inhalation Remove to freh air. Drink water to clear throat, and blow noe to remove dut. If irritation perit, get medical attention. Firt Aid: Skin Wah gently with oap and warm water to remove dut. Ue a wah cloth to help remove fiber. To avoid further irritation, do not rub or cratch affected area. Rubbing or cratching may force fiber into the kin. If irritation perit get medical attention. Never ue compreed air to remove fiber from the kin. Wah hand before eating or uing the retroom. Firt Aid: Ingetion Product i not intended to be ingeted or eaten. If thi product i ingeted, irritation of the gatrointetinal (GI) tract may occur, and hould be treated ymptomatically. Watch the peron for everal day to make ure that partial or complete intetinal obtruction doe not occur. Do not induce vomiting unle directed to do o by medical peronnel. Rine mouth with water to remove fiber, and drink plenty of water to help reduce the irritation. No chronic effect are expected following ingetion. Firt Aid: Eye Do not rub or cratch your eye. Fiber may caue the eye to be cratched. Fluh eye with large amount of water for at leat 15 minute. If irritation perit, contact a medical profeional. Firt Aid: Note to Phyician Thi product i a mechanical irritant, and i not expected to produce any chronic health effect from acute expoure. Treatment hould be directed toward removing the ource of irritation with ymptomatic treatment a neceary. Section 5 Fire Fighting Meaure Flah Point: Not applicable Method Ued: Not applicable Upper Flammable Limit (UFL):Not applicable Lower Flammable Limit (LFL): Not applicable Auto Ignition: Not determined Flammability Claification: Non combutible Rate of Burning: Not applicable General Fire Hazard There i no potential for fire or exploion. Extinguihing Media Ue any extinguihing media appropriate for the urrounding fire IIG 20509 2 of 6
Fire Fighting Equipment/Intruction No pecial procedure are expected to be neceary for thi product. Normal fire fighting procedure hould be followed to avoid inhalation of moke and gae produced by other material. Hazardou Combution Product: Primary combution product are carbon monoxide, carbon dioxide, ammonia, and water. Other undetermined compound could be releaed in mall quantitie. Section 6 Accidental Releae Meaure Containment Procedure Pick up large piece. Vacuum dut. If weeping i neceary, ue a dut uppreant uch a water. Do not dry weep dut accumulation or ue compreed air for clean-up. Thee procedure will help to minimize potential expoure. Thi material will ink and dipere along the bottom of waterway and pond. It can not eaily be removed after it i waterborne; however, the material i non-hazardou in water. Clean-Up Procedure Wate are not hazardou a defined by the RCRA (40 CFR 261). Comply with tate and local regulation for dipoal of thee product. If you are unure of the regulation, contact your local Public Health Department, or the local office of the EPA. Section 7 Handling and Storage Handling Procedure Ue protective equipment a decribed in Section 8 of thi material afety data heet when handling uncontained material. Keep product in it packaging, a long a practicable to minimize potential dut generation. Keep work area clean. Avoid unneceary handling of crap material by placing them in wate dipoal container and equipment, kept a to cloe working area a poible, to prevent releae of fiber and dut. Good houekeeping practice hould be ued to prevent generation and accumulation of dut. After handling product, wah face and hand before eating, drinking, or moking. Storage Procedure Warehoue torage hould be in accordance with package direction, if any. Material hould be kept dry, and protected from the element. Section 8 Expoure Control and Peronal Protection General Product Information Follow all applicable expoure limit and ue OSHA-recommended equipment and work practice. A complete copy of thee practice can be obtained from IIG MinWool LLC (ee Section 1 of thi Material Safety Data Sheet), and i alo available on the OSHA webite (http://www.oha.gov/sltc/yntheticmineralfiber). Peronal Protective Equipment Peronal Protective Equipment: Eye/Face Safety glae with ide hield are recommended to keep dut out of the eye. Peronal Protective Equipment: Skin Leather or cotton glove hould be worn to prevent kin contact and irritation. Barrier cream may alo be ued to reduce kin contact and irritation caued by mineral wool fiber. Normal work clothing (long leeved hirt and long pant) i recommended. Skin irritation i known to occur chiefly at the preure point uch a around the neck, writ, wait and between the finger. Peronal Protective Equipment: Repiratory A repirator hould be ued if ventilation i unavailable, or i inadequate for keeping dut and fiber level below the applicable expoure limit. In thoe cae, ue a NIOSH-certified dipoable or reuable particulate repirator with an efficiency rating of N95 or higher (under 42 CFR 84) when working with thi product. For expoure up to five time the etablihed expoure limit ue a quarter-mak repirator, rated N95 or higher; and for expoure up to ten time the etablihed expoure limit ue a half-mak repirator (e.g., MSA' DM- 11, Racal' Delta N95, 3M' 8210), rated N95 or higher. For expoure up to 50 time the etablihed expoure limit ue a full-face repirator, rated N99 or higher. Operation uch a awing, blowing, tear out, and praying may generate airborne fiber concentration requiring a higher level of repiratory protection. Ventilation In fixed manufacturing etting, local exhaut ventilation hould be provided at area of cutting to remove IIG 20509 3 of 6
airborne dut and fiber. General dilution ventilation hould be provided a neceary to keep airborne dut and fiber below the applicable expoure limit and guideline. The need for ventilation ytem hould be evaluated by a profeional indutrial hygienit, while the deign of pecific ventilation ytem hould be conducted by a profeional engineer. Peronal Protective Equipment: General Looe-fitting, long-leeved clothing hould be worn to protect the kin from irritation. Expoed kin area hould be wahed with oap and warm water after handling. Section 9 Phyical & Chemical Propertie Appearance: Fibrou emi-circle, blanket, or board inulation. Odor: Organic ph: Not applicable Phyical State: Solid Vapor Denity: Not applicable Vapor Preure: Not applicable Melting Point: Not determined Boiling Point: Not applicable Specific Gravity: Not determined Solubility (H2O): Nil Freezing Point: Not applicable Vicoity: Not applicable Evaporation Rate: Not applicable VOC: 0 Percent Volatile: 0 Section 10 Chemical Stability & Reactivity Information Chemical Stability Thi i a table material. Thi product i not reactive. Hazardou Decompoition None. Hazardou Polymerization Will not occur. Incompatible Material: Thi product react with hydrofluoric acid. Hazardou Decompoition Product: Primary combution product are carbon monoxide, carbon dioxide, ammonia, and water. Other undetermined compound could be releaed in mall quantitie. Section 11 Toxicological Information Acute Toxicity Dut may caue mechanical irritation to eye and kin. Ingetion may caue tranient irritation of throat, tomach and gatrointetinal tract. Inhalation may caue coughing, noe and throat irritation, and neezing. Higher expoure may caue difficulty breathing, congetion, and chet tightne. B: Component Analyi - LD50/LC50 No LD50/LC50' are available for thi product. Carcinogenicity OSHA, NTP, IARC, and ACGIH have not claified thi product in it entirety a a carcinogen. B: Component Analyi - LD50/LC50 Cured Urea/formaldehyde/phenol binder (25104-55-6) Oral LD50 Rat : 7 gm/kg Oral LD50 Moue : 7 gm/kg Carcinogenicity: In October 2001 the IARC concluded it re-evaluation of the carcinogenic rik of mineral wool fiber. The reult wa a reclaification of the fiber from Group 2B (poibly carcinogenic to human) to Group 3 (not claifiable a to the carcinogenicity to human). Epidemiological tudie publihed during the 15 year prior to the 2001 IARC review provide no evidence of increaed rik of cancer from occupational expoure during manufacture or ue of mineral wool fiber. B: Component Carcinogenicity ACGIH, IARC, OSHA, and NTP carcinogen lit have been checked for thoe component with CAS regitry number. Synthetic Vitreou Fiber (65997-17-3) ACGIH: A3 - animal carcinogen (related to rock wool fiber) with unknown relevance to human IIG 20509 4 of 6
IARC: Monograph 43, 1988 (related to Gla filament) (Group 3 (not claifiable)) Section 12 Ecological Information Ecotoxicity No data available for thi product. B: Component Analyi - Ecotoxicity - Aquatic Toxicity No ecotoxicity data are available for thi product' component. Section 13 Dipoal Conideration US EPA Wate Number & Decription Thi product, a upplied, i not regulated a a hazardou wate by the U.S. EPA under RCRA regulation. Comply with tate and local regulation for dipoal. If you are unure of the regulation, contact your local Public Health Department, or the local office of the EPA. B: Component Wate Number No EPA Wate Number are applicable for thi product' component. Dipoal Intruction Dipoe of wate material according to Local, State, Federal, and Provincial Environmental Regulation. Section 14 Tranport Information US DOT Information Shipping Name: Thi product i not claified a hazardou material for tranport. Section 15 Regulatory Information US Federal Regulation No information on thi product a a whole. Formaldehyde content i below the SARA 313 0.1% de minimi concentration. B: Component Analyi Thi material contain one or more of the following chemical required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4). Synthetic Vitreou Fiber(65997-17-3) CERCLA: Include mineral fiber emiion from facilitie manufacturing or proceing gla rock or lag fiber (or other mineral derived fiber) of average diameter 1 micrometer or le; Statutory RQ = 1 pound (.454 kg); no final RQ i being aigned to the generic or broad cla (related to Fine mineral fiber) State Regulation The following tatement() are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Propoition 65): WARNING! Thi product contain a chemical known to the tate of California to caue cancer. Other Regulatory Information No information available for the product. B: TSCA Statu All ingredient of thi product are included in the US EPA Chemical Subtance Inventory or are not required to be lited. C: CERCLA Include mineral fiber emiion from facilitie manufacturing or proceing gla rock or lag fiber (or other mineral derived fiber) of average diameter 1 micrometer or le; Statutory RQ = 1 pound (.454 kg); no final RQ i being aigned to the generic or broad cla (related to Fine mineral fiber). D: Clean Air Act Mineral wool fiber appear on the Clean Air Act-1990 Hazardou Air Pollutant Lit. IIG 20509 5 of 6
International Regulation Canada Workplace Hazardou Material Information Sytem (WHMIS) WHMIS Claification: D2B Irritant Product claified a a manufactured article a defined in Hazardou Product Act (HPA), Section 11(1). Section 12(I) exempt it from the WHMIS upplier label and MSDS requirement of the Act. B: Component Analyi - WHMIS IDL No component are lited in the WHMIS IDL. Section 16 Other Information Information about Health and Safety Reearch on Rock- and Slag-wool can be obtained from the North American Inulation Manufacturer Aociation (NAIMA), 44 Canal Center Plaza, Suite 310, Alexandria, VA 22314, or on the web at http://www.naima.org Thi product ha been claified according to the hazard criteria of the CPR and the MSDS contain all the information required by the CPR. Key/Legend: EPA = Environmental Protection Agency; TSCA = Toxic Subtance Control Act; ACGIH = American Conference of Governmental Indutrial Hygienit; IARC = International Agency for Reearch on Cancer; NIOSH = National Intitute for Occupational Safety and Health; NTP = National Toxicology Program; OSHA = Occupational Safety and Health Adminitration; NFPA = National Fire Protection Aociation; HMIS = Hazardou Material Identification Sytem; RCRA = Reource Conervation and Recovery Act; CERCLA = Comprehenive Environmental Repone, Compenation and Liability Act; SARA = Superfund Amendment and Reauthorization Act; DSL = Canadian Dometic Subtance Lit; EINECS = European Inventory of New and Exiting Chemical Subtance; WHMIS = Workplace Hazardou Material Information Sytem; CAA = Clean Air Act; CHPA=Canadian Hazardou Product Act; IDL=Canadian Hazardou Dicloure Lit Reviion Summary: Thi i a revied MSDS which replace Reviion 1.0.3 with a new date. Get thi and other MSDS form electronically via Internet: http://www.iig-llc.com or by calling 800-866-3234. A of the date of preparation of thi document, the foregoing information i believed to be accurate and i provided in good faith to comply with applicable federal and tate law(). However, no warranty or repreentation with repect to uch information i intended or given. Prepared by IIG Technical Service. IMPORTANT SAFETY NOTICE: The information in thi MSDS relate only to the pecific material decribed herein and doe not relate to ue incomponent combination with any other material CAS # or ubtance or ints any proce. DS EINECS Becaue of the ue of thi information and the condition of ue of thi product are not within the control CA of L Indutrial Inulation Group, it i the uer obligation Calcium to determine ilicate the condition1344-95-2 of afe ue of thi product. Ye Uer Ye of thi Ye product hould tudy thi MSDS and become Continuou aware of filament the product gla hazard 65997-17-3 and afety informationye beforeye uing thi Ye product. Uer hould alo notify their employee, fiber agent, and contractor regarding information contained in thi MSDS and any product hazard and afety information Sodium Silicate in order to provide1344-09-8 for afe ue of thi product. Ye Ye Ye Iron Baed Color 51274-00-1 Ye Ye Ye Celluloe Fiber 9004-34-6 Ye Ye Ye IIG 20509 6 of 6