MATERIAL SAFETY DATA SHEET This Material Safety Data Sheet complies with the Canadian Controlled Product Regulations (WHMIS) and the United States Occupational Safety and Health Administration (OSHA) Hazard Communication Standard, 29 CFR 1910.1200. 1. Product and Supplier Identification Product: Dentec Safety Shield Ultra Sport Lotion 30 SPF Formula 325-133 Product Use: Sunscreen 2. Composition Component % (w/w) This product contains no ingredients which require disclosure under the requirements of the Canadian Hazardous Products Act (HPA). Not classified as a hazardous material under OSHA, 29CFR 1910, Subpart Z: * ACGIH: American Conference of Governmental Industrial Hygienists. Exposure Limits(ACGIH)* 100 Not applicable LD 50 LC 50 Not applicable Exposure limits may vary from time to time and from one jurisdiction to another. Check with local regulatory agency for the exposure limits in your area. Routes of Entry: 3. Hazards Identification Skin Contact: Minor Eye Contact: Moderate Ingestion: Moderate Inhalation: Minor Acute Health Effects: Direct contact may cause minor irritation of the skin and eyes. In persons predisposed to skin problems, minor rash may occur. Eye irritation is expected to be minor, causing minor pain and redness. Ingestion may cause abdominal discomfort. Inhalation of vapors, if heated, may cause upper respiratory tract irritation. Chronic Health Effects: When used as prescribed by the manufacturer, there is no chronic effect. Only purposeful inhalation of vapors by heating the sunscreen in confined areas over an extended period of time may cause harmful toxic effects to the blood. - 1 - January 28, 2011
4. First Aid Measures Eye Contact: Flush contaminated eye(s) with lukewarm, gently running water for 15 minutes, holding eyelids open. Seek medical attention if irritation persists. Skin Contact: If application of sunscreen causes a rash or skin reaction, wash immediately with soap and water. If irritation persists, seek immediate medical attention. Remove any contaminated clothing and launder clothing before reuse. Inhalation: This is an unlikely route of entry, but if victim has been exposed to vapors as a result of heating the product, remove immediately to fresh air. If breathing has stopped, a trained person should perform artificial respiration. Get medical attention immediately. Ingestion: Do not induce vomiting. If conscious, dilute contents of stomach with 1 2 glasses of milk or water. If vomiting occurs naturally, have victim lean forward to avoid aspiration. Seek medical attention. 5. Fire Fighting Measures Flash point: Autoignition temperature: Lower Explosive Limit: Upper Explosion Limit: Sensitivity to Impact: Sensitivity to Static Discharge: Not flammable Not sensitive. Not sensitive. Hazardous Combustion Products: None known Extinguishing Media: Use a means of extinguishing surrounding fire. Fire Fighting Instructions: There are no specific recommendations for this product. 6. Accidental Release Measures Personal Protection: No specific recommendation. Environmental Precautions: Not expected to have any environmental impact. May be worn on skin into natural waterways. Cleanup Procedures: Wipe up excess spilled material using cloth or towel. After absorbing excess, clean area with water and mild detergent. 7. Handling and Storage Handling Procedures: Keep container tightly closed when not in use. Store in cool, dry place and in an upright position to prevent leakage. Keep away from heated elements, or open flames. Launder clothing before reuse. Keep out of the reach of children. - 2 - January 28, 2011
Storage: This product contains ingredients that may deteriorate if exposed to heat and ultraviolet sun s rays. This product is expected to have a shelf life of three years if stored in a cool dark place when not being used. 8. Exposure Controls, Personal Protection Engineering Controls: No specific recommendation. Respiratory Protection: No specific recommendation. Skin Protection:. Eye and Face Protection: Protect eyes when applying sunscreen. Other: None 9. Physical and Chemical Properties Appearance: White/ cream colored viscous lotion Odor: Fragrant Odor Threshold: Not established ph: 4.5 5.5 Vapor Pressure: Not established Solubility: Dispersible Vapor Density: Not established Freezing Point Not established Boiling Point: Not established Critical Temperature:. Relative Density: 0.98 1.03 (water = 1) Partition Coefficient: Not established Evaporation Rate: Not established Viscosity: 70M to 130M cps @ 23 C, RVF#6 4 rpm 10. Stability and Reactivity Chemical Stability and Reactivity: Product is stable. Conditions to Avoid: None Incompatibility: None known. Hazardous Decomposition Products: No hazardous decomposition products known. Hazardous Polymerization: Hazardous polymerization will not occur. 11. Toxicological Information Acute Exposure: Theoretical LD 50 (rat/oral) for product exceeds 10000 mg/kg. Chronic Exposure: See Section 3. Exposure Limits: See Section 2. Irritancy: See Section 3. Sensitization: See Section 3. - 3 - January 28, 2011
Carcinogenicity: Teratogenicity: Reproductive toxicity: Mutagenicity: Synergistic products: No ingredients have been listed by IARC None known Environmental toxicity: No data available. 12. Ecological Information Biodegradability: When released into the environment, this product is expected to biodegrade. 13. Disposal Considerations Canadian Environmental Protection Act: All ingredients are listed on the DSL. Dispose according to all local, provincial and federal requirements. 14. Transport Information Canadian Transportation of Dangerous Goods Regulations: Not regulated US Department of Transportation: Not regulated International Air Transport Association (IATA): Not regulated International Maritime Organization (IMO): Not regulated Canadian Federal Regulations: 15. Regulatory Information Canadian Environmental Protection Act: All ingredients are on the Domestic Substances List. WHMIS Classification: Not a controlled substance. UNITED STATES FEDERAL REGULATIONS: TOXIC SUBSTANCES CONTROL ACT (TSCA): All components are listed in the inventory OSHA, 29CFR 1910, Subpart Z: Does not meet criteria for a hazardous substance CERCLA, 40 CFR 302: No components listed SARA 302, 40 CFR 355: No components listed SARA 313, 40 CFR 372: No components listed SARA 311/312, 40 CFR 370: Does not meet criteria - 4 - January 28, 2011
Preparation Date: January 28, 2011 16. Other Information Prepared by: Dentec Safety Specialists Inc 100 Harry Walker Parkway North Newmarket, Ontario This Material Safety Data Sheet was prepared using information provided by CCINFO. The information in the Material Safety Data Sheet is offered for your consideration and guidance when exposed to this product. Norwood Packaging Ltd. expressly disclaims all expressed or implied warranties and assumes no responsibilities for the accuracy or completeness of the data contained herein. The data in this MSDS does not apply to use with any other product or in any other process. This Material Safety Data Sheet may not be changed, or altered in any way without the expressed knowledge and permission of Dentec Safety Specialists Inc. - 5 - January 28, 2011