TEGO AddBnd Fr Maximum Adhesin
TEGO AddBnd
Imprving Adhesin The prducts f the TEGO AddBnd series are specialty plyester resins fr use as adhesin-enhancing cmpnents in slventbrne, waterbrne, r radiatin-curing catings and printing inks. Due t their brad cmpatibility with a large number f binders they are very suitable fr physically r xidatively drying, thermsetting, r radiatin-curing frmulatins. They imprve adhesin t a number f substrates, including critical substrates like metals, minerals, and varius types f plastics, and are therefre ften used in under cats. They als imprve intercat adhesin, s that they are highly recmmended even in multi-cat frmulatins. The adhesive pwer f the TEGO AddBnd prducts, cmbined with their excellent resistance t hydrlysis and their water-repellent prperties, significantly imprve crrsin prtectin in catings. In effect catings, TEGO AddBnd imprves the chesin within the film layer. Mrever, these prducts als help t imprve glss and flexibility. Prduct range/supply frm Packaging Slvent cntaining grades: Screw cap drum, net cntent 25 kg Steel drum, net cntent 200 kg TEGO AddBnd : PE-bag, antistatic, net cntent 25 kg TEGO AddBnd DS 1300: PE-canister, net cntent 25 kg, Srew cap drum, net cntent 200 kg Strage stability When prtected against light and humidity and at strage temperatures f less than 25 C, TEGO AddBnd prducts have a strage stability f 6 mnths. Avid string TEGO AddBnd 1270 at temperatures belw 10 C and TEGO AddBnd DS 1300 at temperatures belw 5 C. TEGO AddBnd HS TEGO AddBnd TEGO AddBnd LTW 75% by wt. in n-butyl acetate Irregular, drp-shaped pellets 60% by wt. in xylene Safety Any safety infrmatin needed may be btained frm ur MSDS. TEGO AddBnd LTW-B 60% by wt. in n-butyl acetate TEGO AddBnd 2220 ND 60% by wt. in Slvent Naphtha 150 TEGO AddBnd 2325 TEGO AddBnd 1270 TEGO AddBnd DS 1300 60% by wt. in n-butyl acetate 70% by wt. in sec.-butanl 45% by wt. in dem. water, neutralizer: Dimethylaminethanl Cntact with fds This Prduct can be used in cmpliance with the fllwing sectin(s) and may be subject t any applicable limitatins: Fd Cntact Ntificatin (FCN) 918. 1) As a mnmer, alne, r in cmbinatin with the plyhydric alchls listed in 21 CFR 175.300 (b)(3)(vii)(c), in the prductin f plyester can catings used in the manufacture f articles r cmpnent f articles fr cntact with fd. 2) As a mnmer in the prductin f plyester resins used as cmpnents f adhesives fr fd cntact applicatins, cmpliant with 21 CFR 175.105 and 175.125. With limitatins specified in FCN. Prduct Grup TEGO AddBnd page 3
Prperties and Applicatins General Because f free carbxyl grups present in the resins, reactins may ccur with basic pigments (e.g., zinc xide). This reactin culd be beneficial and lead t a higher paint film density. On the ther hand, this may lead t an undesirable increase in viscsity. Using smaller amunts f TEGO AddBnd r chsing a mre cmpatible grade culd be helpful. Adhesin may deterirate if resins are used alng with surfactants. Resins may be cmbined with ply silxanes in the usual dsages. TEGO AddBnd HS TEGO AddBnd HS is a high slids c-binder. The use f TEGO AddBnd HS in paint frmulatins enables the VOC cntent t be reduced. The prduct results in excellent adhesin prperties n metals and plastics. TEGO AddBnd LTW, LTW-B and 2220 ND The sft TEGO AddBnd LTW, LTW-B and 2220 ND have a flexibilizing effect and differ frm ne anther primarily in their supply frm. TEGO AddBnd 2220 ND is particularly suitable in the can cating and cil cating sectrs. Systems based n saturated plyester resins, amine resins and iscyanate resins demnstrate better strage and prcessing prperties. TEGO AddBnd The swelling f hard TEGO AddBnd in water is very minimal. Disslved in plasticizers, it can be used in the manu facture f self-adhering rgansls and plastisls. One ntewrthy feature is that plasticizers d nt migrate int TEGO AddBnd when it is applied t plasticizer-cntaining PVC. In radiatincuring systems TEGO AddBnd tends t increase the curing speed. Furthermre, vlume shrinkage that ccurs during curing can be reduced. T achieve shrt disslving times, heat shuld be used alng with fast stirrers in the prductin f resin slutins. A minimum disslving temperature between 50 and 60 C is recmmended fr slvents and mnmers. Fr plasticizers this temperature shuld be between 90 and 100 C. TEGO AddBnd 2325 TEGO AddBnd 2325 is particularly suitable fr use in systems in which ther TEGO AddBnd prducts are incmpatible. TEGO AddBnd 1270 TEGO AddBnd leads t a significant increase f adhesin and crrsin resistance f paints. After neutralizing with amines, it is water reducible and can be used in water-dilutable paints. TEGO AddBnd DS 1300 TEGO AddBnd DS 1300 is used in waterbrne air-drying and thermsetting catings. page 4 Prduct Grup TEGO AddBnd
Hw t use TEGO AddBnd Kind f drying Rm temperature Stving systems/ir-drying Radiatin-curing systems HS LTW if higher flexibility is needed 1270 2325 if /LTW are incmpatible DS 1300 fr waterbrne frmulatins HS LTW Can cating if higher hardness is needed 2220 ND frequently better rhelgical prfiles than LTW 2325 if /LTW/2220 ND are incmpatible Catinic crsslinked Radically crsslinked Aqueus Others DS 1300 1270 HS LTW if higher hardness is needed 1270 We recmmend adding 5 t 15% by wt. (slid) TEGO AddBnd t 100% binder, r fr can catings, a maximum f 3% by wt. t the ttal frmulatin, and in radically crsslinked radiatin-curing frmulatins, a maximum f 35% by wt. t the ttal frmulatin. 2325 if /LTW are incmpatible Prduct Grup TEGO AddBnd page 5
Typical prperties Nn-vlatile matter % by wt. Viscsity, 23 C mpa s Acid number mg KOH/g Melting pint C ph-value Prduct DIN EN ISO 3251 DIN EN ISO 3219 DIN EN ISO 2114 DIN 53181 DIN ISO 976 TEGO AddBnd HS 74-76 2 1500-2500 2 20-30 1 TEGO AddBnd 600-1500 4 12-20 90-102 TEGO AddBnd LTW 59-61 2 350-650 2 20-30 1 TEGO AddBnd LTW-B 59-61 2 350-650 2 20-30 1 TEGO AddBnd 2220 ND 59-61 2 1500-2700 2 18-22 1 TEGO AddBnd 2325 58-62 2 300-700 2 15-25 1 TEGO AddBnd 1270 68-72 2 4000-9000 2 56-65 1 TEGO AddBnd DS 1300 3 43-47 2 6.0-8.0 1 Slid resin 2 Supply frm 3 Experimental prducts 4 60 % by wt. in xylene Tg C OH number mg KOH/g Clr number Gardner Melting pint C Prduct DIN 53 765 DIN EN ISO 4629 DIN ISO 4630 DIN 53 181 TEGO AddBnd HS apprx. 5 1 apprx. 100 1 apprx. 2 2 Sft resin TEGO AddBnd apprx. 70 apprx. 25 apprx. 2 4 Specificatin see abve TEGO AddBnd LTW apprx. 20 1 apprx. 30 1 apprx. 2 2 Sft resin TEGO AddBnd LTW-B apprx. 20 1 apprx. 30 1 apprx. 2 2 Sft resin TEGO AddBnd 2220 ND apprx. 20 1 apprx. 30 1 apprx. 2 2 Sft resin TEGO AddBnd 2325 apprx. 30 1 apprx. 16 1 apprx. 2 2 apprx. 60 1 TEGO AddBnd 1270 apprx. 2 1 apprx. 25 1 apprx. 2 2 Sft resin TEGO AddBnd DS 1300 3 apprx. 30 1 apprx. 60 1 (milky white) apprx. 55 1 1 Slid resin 2 Supply frm 3 Experimental prducts 4 60 % by wt. in xylene Areas f applicatin HS LTW/LTW-B 2220 ND 2325 1270 DS 1300 Can/Cil Cating Cntainer paints Dispersin paints Flr paints Metal paints Paints fr fd packaging * Paints fr plastics Paints fr galvanized steel Primer (air drying) Primer (stving) Printing inks Radmarking paints Radiatin-curing systems Water-thinnable stving paints * Infrmatin can be supplied upn request cncerning the status f prduct in each instance under natinal and internatinal regulatins page 6 Prduct Grup TEGO AddBnd
Slubility Slvent HS LTW/LTW-B 2220 ND 2325 1270 Aliphatic hydrcarbns Armatics Alchls Ketnes Slubility was determined up t 50% by wt. This slubility table was prepared with a selectin f different slvents. Thus the findings listed therein are nt generally applicable. Prir t using a TEGO AddBnd prduct, its slubility shuld be tested. Esters Glycl ethers Ethers sluble O limited sluble insluble Cmpatibility Binder HS Acrylic resins Methacrylic Acrylic cplymers OH-acrylic LTW/LTW-B 2220 ND 2325 1270 Aldehyde resins Alkyd resins shrt ily medium ily lng ily styrenated alkyds Cmpatibility was determined up t 20% by wt. Slid resin t ttal binder. This cmpatibility table was prepared with a selectin f different binders. Thus the findings listed therein are nt generally applicable. Prir t using a TEGO AddBnd prduct, its cmpatibility shuld be tested. Calcium resinates Carbamide resins Cellulse esters Cyclized rubber Epxy resins lw mlecular medium mlecular Glycerine ester resins Urea resins Ketne resins Rsin-mdified resins Rsin-mdified phenlic resins Hydrcarbn resins Maleic resins Melamine resins Nitrcellulse Phthalic resins Plyamide resins Plyester resins Resls, nn-plasticized VC-cplymers Zinc-resinates cmpatible O limited cmpatible incmpatible Prduct Grup TEGO AddBnd page 7
Sales/Technical Supprt Htline 49 201 173-2222 Africa Egypt Egyptian Prmters Center phne 202 2291-8272 fax 202 2415-5023 Suth Africa Evnik Degussa Africa Pty. Ltd. phne 27 31 825572478 fax 27 31 765 1658 Americas Argentina Mayerhfer Argentina S.A. phne 54 11 4555-4003 fax 54 11 4554-3915 Brazil Evnik Degussa Brasil Ltda. phne 55 11 3146-4124 fax 55 11 3146-4140 Canada Degussa Gldschmidt Chemical Canada phne 1 905 829-2233 fax 1 905 829-2575 Clmbia INCOPACK S.A. phne 57 2331-1531 fax 57 2331-1530 Mexic Degussa Mexic, S.A. DE C.V. phne 52 555 483-1004 fax 52 555 673-6649 USA Evnik Gldschmidt Crp. phne 1 804 541-8658 fax 1 804 541-6290 Australia Australia (Sydney) Internatinal Sales & Marketing Pty. Ltd. phne 61 2 9580-2400 fax 61 2 9580-8045 New Zealand Internatinal Sales & Marketing (NZ) Ltd. phne 64 9 275-0745 fax 64 9 275-0746 Asia P.R. China Evnik Degussa (China) C. Ltd., Shanghai Branch phne 86 21 6119-1000 fax 86 21 6119-1149 Hng Kng Evnik Degussa Hng Kng Ltd. phne 852 2249-6100 fax 852 2249-6179 India Evnik Degussa India Pvt. Ltd. phne 91 22 6723-8800 fax 91 22 6723-8811 Indnesia PT Jebsen & Jessen Chemicals Indnesia phne 62 21 2753-7177 fax 62 21 2753-7188 Japan (Osaka) Evnik Degussa Japan C., Ltd. phne 81 6 6644-1542 fax 81 6 6644-1578 Krea Evnik Degussa Krea Ltd. phne 82 2 2071-2300 fax 82 2 785-5247 Malaysia Jebsen & Jessen Chemicals (M) Sdn Bhd phne 60 3 7861-6788 fax 60 3 7861-6799 Philippines Jebsen & Jessen Chemicals (P) Inc. phne 63 2 786-7700 fax 63 2 786-7716 Singapre Evnik Degussa (SEA) Pte. Ltd. phne 65 6899-0080 fax 65 6890-6058 Taiwan Evnik Degussa Taiwan Ltd. phne 886 2 2717-1242 fax 886 2 2717-2106 Thailand DKSH (Thailand) Ltd. phne 66 2 790-4000 fax 66 2 730-3195 Vietnam Viet Ha Sinh C., Ltd. phne 84 8 3512-8128 fax 84 8 3512-7127 Eurpe Austria Evnik Teg Chemie GmbH phne 49 201 173-2222 fax 49 201 173-1939 Belgium Evnik Teg Chemie GmbH phne 49 201 173-2222 fax 49 201 173-1939 Bulgaria HSH Chemie EOOD phne 359 2808-8283 fax 359 2808-8260 Czech Republic HSH Chemie s.r.. phne 420 2 612-23555 fax 420 2 612-25971 France Evnik Teg Chemie GmbH phne 33 800 914-091 fax 49 201 173-1939 Germany Evnik Teg Chemie GmbH phne 49 201 173-2222 fax 49 201 173-1939 Great Britain Evnik Teg Chemie GmbH phne 0808 2343051 fax 49 201 173-1939 Greece Gldchem EPE phne 30 210 68-25802 fax 30 210 68-34537 Hungary HSH - Chemie Kft. phne 36 1 450-3210 fax 36 1 450-3229 Italy Evnik Teg Chemie GmbH phne 800 871276 fax 49 201 173-1939 Netherlands Evnik Teg Chemie GmbH phne 49 201 173-2222 fax 49 201 173-1939 Pland Evnik Degussa Plska Sp.z... phne 48 42 71536-10 fax 48 42 71536-05 Prtugal Hrquim - Representações, Lda. phne 351 22 967-0496 fax 351 22 967-3287 Rmania HSH Chemie SRL phne 40 21 313-7778 fax 40 21 315-7864 Russia OOO Evnik Chimia phne 7 495 721-2862 fax 7 495 721-2852 Scandinavia Evnik Teg Chemie GmbH phne 49 201 173-2222 fax 49 201 173-1939 Slvenia Parka d... phne 386 4 502-2813 fax 386 4 502-2819 Spain Evnik Teg Chemie GmbH phne 0900 968309 fax 49 201 173-1939 Switzerland Evnik Teg Chemie GmbH phne 49 201 173-2222 fax 49 201 173-1939 Turkey Evnik Degussa Ticaret Ltd. Sti. phne 90 216 395-9961 fax 90 2164 4627-90 Fr further infrmatin abut listed and nt listed cuntries please cntact the Internatinal Sales/Technical Supprt Htline r get yur infrmatin at www.teg.de. Evnik Teg Chemie GmbH Gldschmidtstraße 100 45127 Essen Germany phne 49 201 173-2222 fax 49 201 173-1939 www.teg.de www.evnik.cm This infrmatin and all further technical advice is based n ur present knwledge and experience. Hwever, it implies n liability r ther legal respnsibility n ur part, including with regard t existing third party intellectual prperty rights, especially patent rights. In particular, n warranty, whether express r implied, r guarantee f prduct prperties in the legal sense is intended r implied. We reserve the right t make any changes accrding t technlgical prgress r further develpments. The custmer is nt released frm the bligatin t cnduct careful inspectin and testing f incming gds. Perfrmance f the prduct described herein shuld be verified by testing, which shuld be carried ut nly by qualified experts in the sle respnsibility f a custmer. Reference t trade names used by ther cmpanies is neither a recmmendatin, nr des it imply that similar prducts culd nt be used. 03_2011