MATERIAL SAFETY DATA SHEET 1. Product and Company Identification - Product Name: TOP COP with Sulfur - Manufacturing Number: Not available - Producer: Stoller Enterprises P.O. Box 2347 Parlands 2121 South Africa - Telephone Number: +27 (0)82 921 8428 - Fax No: +27 (0) 865 476 711 - Email: jonathan@mbfi.co.za - Supplier: MBF International cc 2. Information on the Composition of Ingredients - Product Description: Flowable mixture of sulfur (as elemental) 500g/l; basic copper sulphate 84 g/l and metallic copper equivalent 44g/l. - Dangerous Ingredients: Copper is not metabolized by people affected with Wilson s disease, so it may accumulate in various tissues and result in severe organ damage. 3. Hazardous Identification - Possible Hazards: Harmful if swallowed. Avoid breathing vapour or spray mist. May cause irritation of eyes, nose, throat or skin. May cause skin sensitization reactions in certain individuals. Avoid contact with skin and eyes. 4. First Aid Measures - Inhalation: Move patient to fresh air. Supplemental oxygen may be indicated. Assure mucous does not obstruct airway. Seek medical attention if the victim s breathing becomes difficult. - Skin Contact: Rinse thoroughly with plenty soap and water. Be sure to remove any contaminated clothing. Seek medical attention if irritation occurs or if an allergic reaction is noticed.
- Eye Contact: Rinse slowly and gently with water for 15-20minutes. Seek medical attention if irritation occurs or if an allergic reaction is noticed. - Ingestion: Contact a doctor for treatment advice. The victim should drink milk, egg whites or large quantities of water and be induced to vomiting. Seek medical attention if any reaction or adverse effects are noticed. Never give anything by mouth to someone who is unconscious, having convulsions or is unable to swallow. 5. Fire Fighting Measures - Type of Material: Non-flammable liquid - Extinguishing Media: Use all means adequate to fight surrounding fire. Water mist, foam, carbon dioxide and dry chemicals are all suitable for use as an extinguishing media. - Hazardous Decomposition Products: Toxic fumes under fire conditions (SO, SO 2, Co, CO 2, etc.). 6. Accidental Release Measures - Environmental Precautions: All work practices must be aimed at preventing environmental contamination. Do not apply directly to water, and avoid application where runoff may occur. Because of its nutritional nature, this product may cause eutrophication if discharged into water bodies. - Personal Precautions: Personal Protective Equipment (PPE) in the form of gloves, safety goggles, protective footwear and overalls are recommended. - Destruction and Clean Up: In case of a large spill, protect people by clearing and isolating the affected area. It is necessary to contain spill into the smallest area possible; recovering liquid in an appropriate container (labelling it accordingly if necessary). If the product is clean, use as intended following the original label directions; if contaminated, salvage for proper disposal as waste. Absorb residual product with absorbent substance (i.e. dirt, sand, sawdust) and then scrape up and dispose of appropriately.
7. Handling and Storage - Handling: Avoid breathing vapours or mists; ensure adequate ventilation when handling. - Storage: Store in original labelled container only. Keep lid tightly sealed and store under cool, dry conditions, away from direct sunlight, sources of heat or where freezing is possible. Store away from children, animals, foods, feeds, seeds and other agricultural products. Avoid prolonged storage or exposure to mild steel. - Incompatible Materials: Avoid strong oxidising agents. 8. Exposure Control/Personal Protective Equipment - TLV: Sulphur - Not established. Basic Copper Sulfate 1mg/m 3 as Cu. - Technical Measures/precautions: General ventilation is usually adequate. Local exhaust should be used if needed for safe, comfortable working conditions. - Personal Protection: Respiratory Protection: Hand Protection: Eye Protection: Skin Protection: Prolonged exposure may cause temporary discomfort of respiratory tract and headache. Respiratory protection (face mask) is recommended. As this product could cause irritation to the skin, it is recommended that gloves be worn as a precaution during handling. This product may cause eye irritation if contact/exposure occurs. Therefore the use of safety goggles/glasses is recommended. This product may cause skin irritation/allergic reactions in some individuals. Overalls are recommended to avoid any such reactions. 9. Physical and Chemical Properties - Physical State: Viscous liquid. - Colour: Green-greyish. - Odour: Very slight rotten egg odour. - ph: N/A
- Moisture (%): N/A - Density (Specific Gravity): 1.42 1.45 g/cm 3 - Solubility/Miscibility in Water: Miscible but insoluble. - Partition Coefficient: N/A - Vapour Pressure: 30mm/Hg - Boiling Point: Not established - Melting Point: N/A - Flash Point: N/A; product is non-flammable. - Oxidizing Properties: Avoid strong oxidizing agents. - Explosive Properties: Not explosive - Auto-ignition Temperature: N/A 10. Stability and Reactivity - Hazardous Decomposition Products: Toxic fumes under fire (SO 2, CO, CO 2, etc.) - Materials to Avoid: Strong oxidizing agents. - Conditions to Avoid: N/A 11. Toxological Information - LD 50 Oral (Rat): Sulfur - >5000mg/kg Cupric sulphate 300mg/kg - LD 50 Dermal (Rat): Sulfur - > 2000mg/kg - Local Effects: Inhalation TCLO: Sulfur 5490 mg/m 3 ; Cupric sulphate (rats) 2950 mg/m 3. - Skin Irritant (Rabbit): > 8000 mg/kg - Eye Irritant (Rabbit): Not known - Chronic Toxicity: Non-carcinogenic, non-teratogenic, and non-mutagenic or reproductive. 12. Ecological Information The available data on this plant nutrient material does not indicate any undue hazard to the environment, if used correctly and according to the instructions on this MSDS and product label. Any waste due to spillage or leakage should be dealt with appropriately (see Accidental Release Measures). Due to the nutrient value, the product may contribute to eutrophication in water bodies.
13. Disposal Considerations Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal site. If unaltered by use, the product should be disposed of as advised by your local waste regulatory authority. 14. Transportation Data - Shipping Name: UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S (Contains Copper Sulfate) 9, III, Marine Pollutant, RQ. - Hazard Class: 9 - UN No.: UN3082 - Packaging Group: III 15. Regulations - EEC Classification: Miscellaneous dangerous substances and goods. - Hazardous Symbols: R20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R36/37/38 Irritating to eyes, respiratory system and skin. - S-phases: S1/2 Keep locked up and out of children s reach. S20/21 When using do not eat, drink or smoke. S24/25 Avoid contact with skin and eyes. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. - National Regulations: National Road Traffic Act (Act 93 of 1996); - Other Regulations: None Fire Brigade Service Act (Act 99 of 1987); Occupational Health and Safety Act (Act 85 of 1993). 16. Other Information
The purpose of the above information is to describe the product only in terms of health and safety requirements. The information given should not therefore be construed as guaranteeing specific properties or as a specification. Customers should satisfy themselves as to the suitability and completeness of such information for their own particular use. Contact Person: Mr. Jonathan Etherington Contact Number: +27 82 924 8428