Material Safety Data Sheet This MSDS is prepared in accordance with OSHA 29 CFR 1910.1200 WHMIS (Pictograms) Sanigel Instant Hand Sanitizer CLASS B-2: Flammable liquid with a flash point lower than 7.8 C (100 F). Betco Corporation 1001 Brown Avenue Toledo, Oh 4607 (419) 241-2156 WHMIS (Classification) Section 1. Chemical Product and Company Identification Product Name/ Trade name Synonym Chemical Family Chemical Formula Manufacturer/ Supplier TSCA DSL/ NDSL TSCA Inventory: All components listed or are exempt from listing. All components listed unless noted elsewhere on this MSDS Code CAS # Class: Flammable liquid having a flash point lower than 7.8 C (100 F). Print Date In Case of Emergency HCS 176 Mixture. Validation Date /22/2004 /27/2004 Chemtrec (800) 424-900 Protective Clothing Section 2. Composition and Information on Ingredients Name CAS # % by Weight Exposure Limits LC 50/LD 50 1) Ethanol 64-17-5 62 TWA: 1000 (ppm) from ACGIH (TLV) [United TWA: 1880 (mg/m ) from ACGIH (TLV) [United TWA: 1000 (ppm) from OSHA (PEL) [United TWA: 1900 (mg/m ) from OSHA (PEL) [United 2) Water 772-18-5 >0 ) Glycerin 56-81-5 0-5 4) Polyol 102-60- 0-5 5) PEG-9 Dimethicone 6897-55- 0-5 6) PEG-9 Isostearate 56002-14- 0-5 7) Acrylic Polymer <1 8) Perfume Oil <1 9) Propylene Glycol 57-55-6 0-5 ORAL (LD50): Acute: 5000 mg/kg [Rat]. Section. Hazards Identification Potential Acute Health Effects This product is an eye irritant. Harmful if swallowed. Potential Chronic Health Effects Carcinogenic Effects Over-exposure by inhalation may cause respiratory irritation. If skin redness of irritation develops, discontinue use. Not classified or listed by IARC, NTP, OSHA, EU and ACGIH.
Section 4. First Aid Measures Eye Contact Skin Contact Inhalation Ingestion In case of contact with eyes, rinse immediately with plenty of water. Discontinue use if redness or irritation develops Remove to fresh air. Call a poison control center immediately for treatment advice. NEVER give an unconscious person anything to ingest. Section 5. Fire Fighting Measures Products of Combustion Fire Fighting Media and Instructions Special Remarks on Fire Hazards Special Remarks on Explosion Hazards Foam, CO2, water fog. Section 6. Accidental Release Measures Small Spill and Leak Absorb with an inert material and place in an appropriate waste disposal container. Large Spill and Leak Personal Protection in Case of a Large Spill Absorb with DRY earth, sand or other non-combustible material. Prevent entry into sewers, basements or confined areas. Splash goggles. Gloves. Section 7. Handling and Storage Precautions Incompatibility Storage Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not breathe gas/fumes/ vapor/spray. acids, oxidizing materials Flammable materials should be stored in a separate safety storage cabinet or room. Keep out of reach of children. For Institutional and Commercial Use Section 8. Exposure Controls/Personal Protection Engineering Controls Personal Protection Good general ventilation should be sufficient to control airborne levels. Eyes Avoid Contact with eyes. Protective Clothing (Pictograms) Body No special protective clothing is required. Respiratory A respirator is not needed under normal and intended conditions of product use. Hands Not applicable. Exposure Limits Ethanol TWA: 1000 (ppm) from ACGIH (TLV) [United TWA: 1880 (mg/m ) from ACGIH (TLV) [United TWA: 1000 (ppm) from OSHA (PEL) [United TWA: 1900 (mg/m ) from OSHA (PEL) [United Consult local authorities for acceptable exposure limits.
Section 9. Physical and Chemical Properties Physical State and Appearance Liquid. Odor Pleasant. Molecular Weight Not applicable. Taste ph 7. [Neutral.] Color Clear Boiling/Condensation Point 7.778 C (100 F) Melting/Freezing Point Critical Temperature Instability Temperature Specific Gravity 0.8929 (Water = 1) Vapor Pressure Vapor Density >1 (Air = 1) Volatility >90% (w/w). VOC 61 (%) Evaporation Rate >1 compared to Water Dispersion Properties Solubility The Product is: Auto-ignition Temperature Flash Points Flammable Limits Fire Hazards in Presence of Various Substances Explosion Hazards in Presence of Various Substances Very slightly soluble in cold water. Flammable. CLOSED CUP: 16.667 C (62 F). Not Determined Drums Heated By Fire Can explode Section 10. Stability and Reactivity Data Stability Incompatibility with Various Substances Hazardous Decomposition Products The product is stable. acids, oxidizing materials
Section 11. Toxicological Information Routes of Entry Toxicity to Animals Acute oral toxicity (LD50): 5000 mg/kg [Rat]. (Propylene Glycol). Acute Effects on Humans Eyes Irritant. Inflammation of the eye is characterized by redness, watering, and itching. Skin Non-irritating. Inhalation According to our data base, the product will not easily enter the human body. Ingestion May cause nausea, vomiting and diarhea. Harmful if swallowed. Chronic Effects on Humans Special Remarks on Toxicity to Animals Special Remarks on Chronic Effects on Humans Over-exposure by inhalation may cause respiratory irritation. If skin redness of irritation develops, discontinue use. Section 12. Ecological Information Ecotoxicity BOD5 and COD Products of Biodegradation Toxicity of the Products of Biodegradation Special Remarks on the Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Section 1. Disposal Considerations Waste Information Waste Stream Waste must be disposed of in accordance with federal, state and local environmental control regulations. Section 14. Transport Information DOT (U.S.A) (Pictograms) TDG Classification TDG Class : Flammable liquid. PIN UN, Proper Shipping Name, PG Maritime Transportation Shipping name: FLAMMABLE LIQUIDS, N.O.S. (Contains Ethanol) UNNA: 199 PG: II Special Provisions for Transport
Section 15. Other Regulatory Information and Pictograms WHMIS (Classification) CLASS B-2: Flammable liquid with a flash point lower than 7.8 C (100 F). Regulatory Lists Other Regulations CEPA DSL: No products were found. OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). Other Classifications HCS (U.S.A.) USA Regulatory Lists Class: Flammable liquid having a flash point lower than 7.8 C (100 F). No products were found. DSD (EEC) International Regulations Lists R11- Highly flammable. No products were found. Hazardous Material Information System (U.S.A.) Health Flammability Physical Hazard 2 0 National Fire Protection Association (U.S.A.) The Hazard Ranking systems presented on this MSDS provide only a quick reference for hazard information. The ENTIRE MSDS must be consulted to determine any specific hazards, First Aid measures, and PPE associated with this product. Health 2 0 Flammability Instability Specific Hazard Section 16. Other Information Validated by CRushton on /22/2004. Verified by CRushton. Printed /27/2004. Information Contact Betco Corporation 1001 Brown Avenue Toledo, Ohio 4607 Notice to Reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Validated on /22/2004. Sanigel Page: 5/5 Continued on Next Page