01. IDENTIFICATION OF THE SUBSTANCE/PREPARATION & THE COMPANY/UNDERTAKING Product Name Biological Definition INCI Name Synonyms & Trade Names - - - Supplier Reach Registration Number (According to EU Reg 1907/2006) Cumin Seed Oil Cumin seed oil is the volatile oil steam distilled from the dried seeds of the Cumin plant Cuminum cyminum L., Umbelliferae. Cuminum cyminum seed oil. Emergency Tel No: 01493 600045 N/A FEMA No. 2343 FDA No. 182.20 CoE No. 161 CAS- No 8014-13-9 EC No. 283-881-6 EINECS No. 283-881-6 02. HAZARDS IDENTIFICATION Classification (1999/45) Classification (EC 1272/2008) Label in accordance with (EC) No 1272/2008 Xn; R10-38-43-52/53-65, S24-36/37-62 UN-GHS: FL 3, AH 1, ATO 5(2300), ATD 5(3600), SCI 2, SS 1, EH A3,C3 EU-CLP: FL 3, AH 1, SCI 2, SS 1 GHS02 GHS07 GHS08 Signal Word Danger Contains Cuminaldehyde, pinenes, p-cymene, Hazard Statements H226 Flammable liquid and vapour H304 May be fatal if swallowed and enters airways H315 May cause skin irritation H317 May cause an allergic skin reaction Precautionary Statements P273: Avoid release to the environment. P280: Wear protective gloves. P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302+P352: IF ON SKIN: Wash with plenty of soap and water. P331: Do NOT induce vomiting. Supplementary Precautionary P362: Take off contaminated clothing and wash before reuse. Statements PBT or vpvb according to Annex XIII No Adverse physio- chemical Combustible but will not normally self-ignite. However paper/packaging soaked properties with cumin seed oil has been known to smoulder and produce smoke especially if exposed to sunlight. All combustible oil-soaked material should be gathered up and placed in a closed metal bin and left outside the building awaiting dispoal. Adverse effects on human health May cause sensitisation by skin contact.
03. COMPOSITION/INFORMATION ON INGREDIENTS 41% Cuminaldehyde UN-GHS: ATO 4(1400); ATD 5(2800); SCI 3; SS 1 22% Pinenes UN-GHS: ATO 5(3700), SCI 2, SS 1 10% p-cymene UN-GHS: ATO 5(4750); SCI 3; EH A2,C2 04. FIRST AID MEASURES General Information Inhalation Ingestion Skin Contact Eye Contact See categories below Remove from exposure area to fresh air. Contact a doctor if necessary. Wash mouth out with water and obtain medical advice immediately. Remove contaminated clothing. Wash thoroughly with soap and water. Seek medical advice if irritation persists or there is any sign of tissue damage. Flush with plenty of water and seek medical advice if necessary. 05. FIRE-FIGHTING MEASURES Extinguishing Media Use CO 2, Dry Powder or Foam type extinguishers, spraying extinguishing media to base of flames. Do not use direct water jet on burning material. Special Fire Fighting Procedures Specific Hazards Protective Measures in Fire Wear protective clothing. Avoid inhalation of vapours. None Closed containers may build up pressure when exposed to heat and should be cooled with water spray 06. ACCIDENTAL RELEASE MEASURES Personal Precautions Environmental Precautions Spill Clean Up Methods 07. HANDLING AND STORAGE Usage Precautions Maintain good occupational and personal hygiene. Avoid contact with skin and eyes Do not discharge directly into drains or soil. Keep away from surface and ground water Soak up spillage with sand or other inert material. Transfer soaked material to suitable waste container and dispose according to prevailing regulations. Apply good manufacturing practice & industrial hygiene practices, ensuring proper workplace ventilation. Observe good personal hygiene, and do not eat, drink or smoke whilst handling. Storage Precautions Store in tightly closed original container, in a cool, dry & ventilated area away from heat sources & protected from light. Keep air contact to a minimum. 08. EXPOSURE CONTROLS/PERSONAL PROTECTION Protective Equipment
Goggles Gloves Engineering Measures Respiratory Equipment Hand Protection Eye Protection Other Protection Hygiene Measures Ensure good ventilation of working area. As required. Avoid breathing product vapour. Avoid all skin contact. Use chemically resistant gloves if required. Use safety glasses. As required Wash hands with soap & water after handling 09. PHYSICAL AND CHEMICAL PROPERTIES Appearance Colour Odour Relative Density Flash Point ( C) Refractive Index Melting Point ( C) Boiling Point ( C) Vapour Pressure Solubility in Water @20 C Auto- ignition temperature ( C) Mobile liquid Pale yellow to brown Powerful, characteristic, spicy, fatty. 0.900 to 0.950 @ 25⁰C >62 c/c 1.4790 to 1.5090 @ 25⁰C Insoluble Not determined 10. STABILITY AND REACTIVITY Stability Conditions to Avoid Materials to Avoid Hazardous Decomposition Products 11. TOXOLOGICAL INFORMATION It presents no significant reactivity hazards, by itself or in contact with water. Avoid storage temperatures above 25⁰C Avoid contact with strong acids, alkalis and oxidising agents. Liable to cause smoke & acrid fumes during combustion: carbon monoxide, carbon dioxide & other non-identified organic compounds may be formed. Acute Toxicity Acute oral toxicity LD50 orl-rat 2500 mg/kg Food & Cosmetics Toxicology 12, 869 (1974) Dermal toxicity LD50 skn-rbt 3560 mg/kg Food & Cosmetics Toxicology 12, 869 (1974) Skin corrosion / irritation Serious eye damage / irritation Skin corrosion/irritation Hazard Category 2 under UN-GHS & EU-CLP following EC 1272/2008 guidelines Not listed for serious eye damage/irritation under UN-GHS & EU-CLP following EC 1272/2008
Respiratory or skin sensitisation Germ Cell Mutagenicity Skin sensitiser Hazard Category 1 according to UN-GHS & EU-CLP following EC 1272/2008 Not listed as a mutagen Carcinogenicity Reproductive toxicity STOT- single exposure Not listed as a carcinogen Not identified as a reprotoxicant STOT- repeated exposure Aspiration hazard Aspiration Hazard, Hazard Category 1 under UN-GHS & EU-CLP following EC 1272/2008 Photo- toxicity Photo-toxic. For areas of skin exposed to sunshine conc. limit for cumin seed oil is 0.4% for leave-on cosmetic products ref IFRA s 43 rd Amendment. Other Information None 12. ECOLOGICAL INFORMATION Ecotoxicity Mobility Hazardous to the aquatic environment long-term hazard, Category Chronic 3.under UN-GHS & EU-CLP following EC 1272/2008 Persistence & Biodegradability Bioaccumulation Potential PBT Assessment Results Precautions Do not discharge into the environment especially into watercourses, sewers and the sea. 13. DISPOSAL CONSIDERATIONS Disposal Methods 14. TRANSPORT INFORMATION Warning Icon Do not release into the environment. Collect waste into suitable containers and contact hazardous chemical disposal company. Proper Shipping Name EXTRACTS, AROMATIC, LIQUID (not viscous) UN No. Road UN 1169 ADR Class 3 Hazard No (ADR) Data not found Hazchem Code Data not found
UN No. SEA UN 1169 IMDG Class Class 3 IMDG Pack Gr. Pk Gp III EMS F-E, S-D UN No. AIR UN 1169 Air Class Class 3 Air Pack Gr. Pk Gp III 15. REGULATORY INFORMATION EU Directives Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 th Dec 2006 Concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 199/45/EC and repealing Council Regulation Council Regulation (EEC) No793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, and 93/105/EEC and 2000/21/EC including amendments. Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply Regulations 2009 (S.I. 2009 No 716). Approved Code of Classification and Labelling of Substances and Preparations Dangerous for Supply. Safety Data Practice Sheets for Substances and Preparations Guidance Notes Workplace Exposure Limits EH40. CHIP for everyone HSG 108. 16. OTHER INFORMATION Revision Date 03/2015 Rev No/Repl, SDS Generated Risk Phrases in Full Hazard Statements in Full 1 R10 Flammable R38 Irritating to skin R43 May cause sensitisation by skin contact R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment R65 Harmful: may cause lung-damage if swallowed H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects. Other Information Complies with REACH guidance for SDS as circulated by ECHA 2011. DISCLAIMER: This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.