Revision Date: 12/02/2011 Issuing Date: 12/02/2011 Company/Undertaking Identification: Material Safety Data Sheet PVP/VA S-630 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING International Specialty Products 1361 Alps Rd. Wayne, N.J. 07470 U.S.A. Telephone: (973) 628-4000 Distributed by: ISP CANADA Corp. 4055 Sladeview Cr. #7 Mississauga, Ontario L5L 5Y1 TEL: (905) 607-2392 or (800) 465-5094 FAX: (905) 607-9086 Emergency Telephone: Prepared By: Product Code: CHEMTREC: 1-800-424-9300 or 703-527-3887 (Outside of the USA) (Spill Related Emergencies) PROSAR: 1-800-241-7439 (Health Related Emergencies) Product Stewardship Product Name: PVP/VA S-630 INCI Name(s): Product Use Description: VP/VA Copolymer Personal Care 2. HAZARDS IDENTIFICATION Emergency Overview CAUTION! POWDERED MATERIAL MAY FORM EXPLOSIVE DUST-AIR MIXTURES. MAY CAUSE RESPIRATORY TRACT IRRITATION. CAUSES SLIGHT EYE IRRITATION White Powder Hazard Summary Target Organs: Primary Routes of Entry: Acute Health Hazard: Chronic Health Hazard: Symptoms of Overexposure Eye Contact: Skin contact: Respiratory System Eyes. Skin. Inhalation. Ingestion. May cause respiratory tract irritation. Causes slight eye irritation None known Slight irritation Not hazardous Ingestion: Not hazardous Page 1 of 5
Inhalation: May cause respiratory tract irritation. 3. COMPOSITION/INFORMATION ON INGREDIENTS Components: CAS-No Weight % Acetic acid ethenyl ester, polymer with 1-ethenyl-2- pyrrolidinone 25086-89-9 97 Eye Contact: Skin Contact: Ingestion: Inhalation: Suitable Extinguishing Media: Combustion/Explosion Hazards: 4. FIRST AID MEASURES Flush with plenty of water. Wash off with soap and water. Do not induce vomiting. If conscious, give 2 glasses of water. Get immediate medical attention. If inhaled, remove to fresh air. If breathing is irregular or stopped, administer artificial respiration. Get medical attention. 5. FIRE FIGHTING MEASURES Use extinguishing measures that are appropriate to local circumstances and the surrounding environment May form explosive dust-air mixture. Special Protective Equipment For Wear self-contained breathing apparatus and protective suit. Fire-Fighters: Personal Precautions: Methods for Cleaning Up: Handling: 6. ACCIDENTAL RELEASE MEASURES Avoid creating dust. Avoid breathing dust. Use with adequate ventilation. Wear suitable protective equipment. Clean up promptly by scoop or vacuum. Avoid dust formation. Avoid dust accumulation in enclosed space. Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE Avoid contact with eyes. Avoid dust formation. Avoid dust accumulation in enclosed space. Avoid breathing mist. Wash thoroughly after handling. Storage: Keep container tightly closed. Keep in a dry, cool place. Keep away from direct sunlight. Engineering Measures: Respiratory Protection: Hand Protection: Eye Protection: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Use only in well-ventilated areas. Use only in well-ventilated areas. In case of insufficient ventilation wear suitable respiratory equipment Wear protective gloves. Safety glasses. Exposure Limits: Components: Acetic acid ethenyl ester, polymer with 1-ethenyl-2- pyrrolidinone 25086-89-9 (97) ACGIH - Threshold Limit Values - Time Weighted Averages (TLV-TWA) No TLV/TWA Established Page 2 of 5 U.S. - OSHA - Final PELs - Time Weighted Averages (TWAs) No TLV/TWA Established
Respirable dust Physical State: Color: Odor: Odor Threshold: ACGIH - Threshold Limit Values - Time Weighted Averages (TLV-TWA): 10mg/m³ (inhalable particles) 3mg/m³ (respirable particles) U.S.- OSHA- Final PELs- Time Weighted Averages (TWAs): 15mg/m³ (Total dust) 5mg/m³ (respirable dust fraction) 9. PHYSICAL AND CHEMICAL PROPERTIES Powder White Not available ph: >=3.0 - <=7.0 Specific Gravity: 1.27 Boiling Point ( F): Melting/Freezing Point ( F): Vapor Pressure: Solubility: Flash Point ( F): Chemical Stability: Conditions to Avoid: Materials to Avoid: Hazardous decomposition products: Toxicity Test: Acute Oral Toxicity (LD50): Eye Irritation: Skin Irritation: Carcinogenicity: Other Information: Dispersible in water 10. STABILITY AND REACTIVITY Stable under normal conditions. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid dust formation. Avoid dust accumulation in enclosed space. Strong oxidizing agents, Strong reducing agents nitrogen oxides (NOx) 11. TOXICOLOGICAL INFORMATION >5000 mg/kg (Rat) (based on similar products) Slight irritation (rabbit) No skin irritation (rabbit) identified as a known or anticipated carcinogen by NTP. identified as probable, possible or confirmed human carcinogen by IARC. identified as a carcinogen or potential carcinogen by OSHA. 28 day dietary feeding study in rats. NOEL=1000mg/kg/day (highest dose tested). 90 day dietary feeding study in rats. NOEL=1000mg/kg/day (highest dose tested). Page 3 of 5
Persistence and Degradability: Ecotoxicity: Waste Disposal Methods: 12. ECOLOGICAL INFORMATION Not readily biodegradable. (tested at a concentration of 100 mg/l) EC50=>1000 mg/l 48hour (Daphnia magna (Water flea)) 13. DISPOSAL CONSIDERATIONS Dispose of in accordance with local regulations. Land Transport: DOT (Non-Bulk): DOT (Bulk): Air Transport (IATA): Sea Transport (IMO): TDG (Canada): 14. TRANSPORT INFORMATION Not regulated DOT Not regulated IATA Not regulated IMDG Not regulated TDG 15. REGULATORY INFORMATION TSCA DSL NDSL ENCS AICS EINECS ELINCS NZIoC KECI PICCS IECSC Inventories Status Not Not Not Not California Proposition 65 Carcinogens & Reproductive Toxicity (CRT) List: EPCRA (SARA Title III): This product does not contain any chemicals known to State of California to cause cancer, birth, or any other reproductive defects. Not applicable WHMIS Ingredient Disclosure List: One or more components of this product is listed on the WHMIS Ingredient Disclosure list. WHMIS: WHMIS Hazard Class: This preparation is classified as dangerous according to Canadian legislation D2B TOXIC MATERIALS Page 4 of 5
16. OTHER INFORMATION NFPA Rating: Health: 1 Flammability: 1 Reactivity: 0. HMIS RATING: HEALTH 1 FLAMMABILITY 1 PHYSICAL HAZARD 0 Prepared By: MSDS sections updated: Legend: Disclaimer: Product Stewardship None N.Av.= Not Available; N.A.= Not Applicable For purposes of this MSDS, International Specialty Products, as responsible party, provides the information herein which is intended for use by persons who have or should obtain professional knowledge and experience in the subjects discussed. ISP s industrial products are used as materials in the production of products by industrial customers. ISP usually has only limited information about the products of its customers and their composition, methods of manufacture and use. Accordingly, ISP MAKES NO WARRANTY, EXPRESS OR IMPLIED, AS TO THE ACCURACY, COMPLETENESS OR RELIABILITY OF INFORMATION HEREIN EXCEPT THAT SUCH INFORMATION IS, TO THE BEST OF ISP'S KNOWLEDGE AND BELIEF, ACCURATE AS OF THE DATE INDICATED. ISP recommends that customers independently test and evaluate its products and their products and processes in which ISP products are used in order to decide their safety and effectiveness. ***End of Safety Data Sheet*** Page 5 of 5