MATERIAL SAFETY DATA SHEET PINE GEL DISINFECTANT

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MATERIAL SAFETY DATA SHEET PINE GEL DISINFECTANT No. 1 Date Issued: 07/03/2011 COMPANY DETAILS NAME: Hygiene Systems (Pty) Ltd EMERGENCY TEL: 0860 494 4363 ADDRESS: 7 Hargan Road, TEL: 011 552 8403 SECTION 1 PRODUCT AND COMPANY IDENTIFICATION TRADE NAME: CHEMICAL FAMILY: CHEMCIAL NAME: SYNONYMS: CHEMICAL ABSTRACT NO.: Pine Gel Disinfectant Detergent Sanitiser SECTION 2 COMPOSITION INFORMATION ON INGREDIENTS DESCRIPTION: % EC NUMBER: CLASSIFICATION: ALKYL DIMENTHYL BENZENE AMMONIUM CHLORIDE (CAS NO.: 85409-22-9) 5-10 Xn; R22 Xi; R36/38 Page 1 of 6

SECTION 3 HAZARD IDENTIFICATION MAIN HAZARD: FLAMMABILITY: CHEMICAL HAZARD: BIOLOGICAL HAZARD: REPRODUCTIVE HAZARD: HEALTH EFFECTS EYE CONTACT: HEALTH EFFECTS SKIN CONTACT: HEALTH EFFECTS INGESTION: HEALTH EFFECTS INHALATION: Harmful Not flammable Harmful Prolonged skin contact may defat the skin Not known Stinging sensation (irritant) Irritating to skin Harmful if swallowed Not expected to be a hazard under normal use conditions with good ventilation SECTION 4 FIRST AID MEASURES PRODUCT IN EYE: PRODUCT ON SKIN: PRODUCT INGESTED: PRODUCT INHALED: Immediately flush with water for at least 15 minutes or until irritation stops. Seek medical advice. Immediately flush skin with plenty of water and remove any contaminated clothing. Seek medical advice Do not induce vomiting. Give copious amounts of water to drink. Seek medical attention. Remove to fresh air. Consult physician, should breathing still be difficult. SECTION 5 FIRE RESPONSE MEASURES EXTINGUISHING MEDIA: SPECIAL HAZARDS: PROTECTIVE CLOTHING: Page 2 of 6

SECTION 6 ACCIDENTAL RELEASE MEASURES Splash goggles, overalls, boots and gloves PERSONAL PRECAUTIONS: ENVIRONMENTAL PRECAUTIONS: SMALL SPILLS: LARGE SPILLS: Do not allow to enter waterways Flush to approved drain with plenty of water. Absorbed onto inert material. May be buried in an approved landfill site. SECTION 7 HANDLING AND STORAGE SUITABLE MATERIAL: HANDLING / STORAGE PRECAUTIONS: Polyethylene containers (original container) Avoid contact with skin and eyes. Store in a cool dry place. SECTION 8 EXPOSURE CONTROL / PERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMITS: ENGINEERING CONTROL MEASURES: (respiratory) (hand) (eye) (skin) OTHER PROTECTION: HYGIENE MEASURES: Rubber gloves if contact is prolonged Goggles/Face shield Overalls Ventilation (local exhaust) Wash hands, forearms and face thoroughly after handling product and before eating, smoking and before going home. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: ODOUR: Clear, fluorescent green liquid That of pine ph (as is): 7.5 9.5 BOILING POINT: Approx. 100 o C Page 3 of 6

FREEZING POINT: FLASH POINT: FLAMMABILITY: EXPOSURE PROPERTIES: OXIDIZING PROPERTIES: VAPOUR PRESSURE: Not determined Not flammable Not flammable Not considered as a product that has an explosion risk Not determined DENSITY @ 20 C: 1.00 +/- 0.01g/cm 3 SOLUBILITY WATER: SOLUBILITY SOLVENT: Complete Soluble in polar solvents SOLUBITLIYT COEEFICIENT: This product is more soluble in water SECTION 10 STABILITY AND REACTIVITY STABILITY: INCOMPATIBLE MATERIALS: This product is stable Strong acids and oxidizing agents SECTION 11 TOXICOLOGICAL INFORMATION LOCAL EFFECTS: SKIN IRRITATION: EYE IRRITATION: ACUTE TOXICITY: CHRONIC TOXICITY: SPECIFIC EFFECTS: CARCINOGENIC EFFECTS: Hazardous in case of skin contact (irritant) Hazardous in case of eye contact (irritant) LD50 (rat): 240 mg/kg (quaternary ammonium compound) Severe eye and skin irritation may be produced with repeated or prolonged contact with concentrated product., as classified by OSHA and NIOSH SECTION 12 ECOLOGICAL INFORMATION ECO-TOXICITY IN WATER: BIODEGRADABILITY: Harmful to aquatic organisms Not determined. If used responsibly, this product is not expected to cause adverse effects to the environment. Page 4 of 6

SECTION 13 DISPOSAL CONSIDERATIONS DISPOSAL CONSIDERATION: DISPOSAL METHODS: WASTE CLASSIFICATION: EUROPEAN WASTE CATALOGUE (EWC): HAZARDOUS WASTE: Do not re-use containers. Puncture all plastic containers. Waste must be disposed of in accordance with local government and environmental control regulations. No additional information No known data The classification of this product does not meet the criteria for a hazardous waste. SECTION 14 TRANSPORT INFORMATION INTERNATIONAL TRANSPORT REGULATIONS: REGULATORY INFORMATION: ADR/RID CLASS: Land Road / Railway ADN CLASS: Inland Waterways IMDG CLASS: Sea IATA-DGR CLASS: Air UN NUMBER: PROPER SHIPPING NAME: CLASS: PACKING GROUP: LABEL: ADDITIONAL INFORMATION: Not regulated - - III - - Not regulated - - - - - Not regulated - - - - - Not regulated - - - - - SECTION 15 REGULATORY INFORMATION EU REGULATIONS: HAZARD SUMBOL(S): CLASSIFICATION: HAZARD STATEMENTS: PRECAUTIONARY STATEMENTS: PRODUCT USE: Irritant R22 Harmful if swallowed R36/38 irritating to eyes and skin S2 Keep out of reach of children S46 If swallowed, seek medical advice immediately and show this container or label. Consumer applications Classification and labeling have been performed as close as possible according to EU directives 67/548/EEC, 1999/45/EC including any amendments and the intended use. Page 5 of 6

SECTION 15 REGULATORY INFORMATION OTHER SPECIAL CONSIDIRATIONS: DISCLAIMER: No additional remarks. Hygiene Systems believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this material safety data sheet. However, because the conditions of handling and possible addition of other chemicals, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials and makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for user s consideration and examination. It is the responsibility of the user to determine the final suitability of this information and data to comply with all applicable international, state, and local laws and regulations. Page 6 of 6