SAFETY DATA SHEET 1. Identification Product identifier Product name Product number W1000,WB100 Recommended use of the chemical and restrictions on use Application Sealant. Details of the supplier of the safety data sheet Supplier Huntsman Pigments Americas LLC P.O. Box 4980 The Woodlands, TX 77387 +1 301 210 3400 / +1 323 269 7311 MSDS@huntsman.com Emergency telephone number Emergency telephone CHEMTREC: (800) 424-9300 (Contract number: 191118) 2. Hazard(s) identification Classification of the substance or mixture Physical hazards Health hazards Environmental hazards Not Classified Skin Irrit. 2 - H315 Eye Irrit. 2A - H319 Not Classified Label elements Pictogram Signal word Hazard statements Precautionary statements Warning H315 Causes skin irritation. H319 Causes serious eye irritation. P264 Wash contaminated skin thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 If on skin: Wash with plenty of water. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P321 Specific treatment (see medical advice on this label). P332+P313 If skin irritation occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. 1/5
3. Composition/information on ingredients Mixtures 2-BUTOXYETHANOL 1-5% CAS number: 111-76-2 REACH registration number: Proprietary Classification Acute Tox. 4 - H302 Acute Tox. 4 - H312 Acute Tox. 4 - H332 Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Ammonium hydroxide 1-5% CAS number: 1336-21-6 REACH registration number: Proprietary M factor (Acute) = 1 Classification Skin Corr. 1B - H314 Eye Dam. 1 - H318 STOT SE 3 - H335 Aquatic Acute 1 - H400 The Full Text for all Hazard Statements are Displayed in Section 16. 4. First-aid measures Description of first aid measures Inhalation Ingestion Skin Contact Eye contact If exposed to excessive levels of dust or fumes, remove to fresh air. Get medical attention if cough or other symptoms develop. Get medical attention immediately. Rinse mouth thoroughly with water. Do not induce vomiting unless under the direction of medical personnel. Wash skin thoroughly with soap and water. Get medical attention if irritation persists after washing. Rinse immediately with plenty of water. Get medical attention if any discomfort continues. 5.Fire-fighting measures Extinguishing media Suitable extinguishing media The product is not flammable. The product is non-combustible. Use fire-extinguishing media suitable for the surrounding fire. Extinguish with the following media: Water spray, foam, dry powder or carbon dioxide. Special hazards arising from the substance or mixture Flammability Class No Uniform Fire Code noted. Advice for firefighters Protective actions during firefighting Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Wear self-contained breathing apparatus as combustion may produce hazardous fumes. 2/5
6. Accidental release measures Methods and material for containment and cleaning up Methods for cleaning up Wear suitable protective equipment, including gloves, goggles/face shield, respirator, boots, clothing or apron, as appropriate. Contain and absorb spillage with sand, earth or other noncombustible material. Collect and place in suitable waste disposal containers and seal securely. Label the containers containing waste and contaminated materials and remove from the area as soon as possible. Flush contaminated area with plenty of water. Avoid runoff into storm sewers and ditches which lead to waterways. 7. Handling and storage Precautions for safe handling Usage precautions Avoid breathing vapours. Avoid contact with eyes. Avoid contact with skin. Wash skin thoroughly after handling. Conditions for safe storage, including any incompatibilities Storage precautions Store dry at ambient temperature away from food, beverage, excessive heat, sources of flame. Protect from freezing and direct sunlight. 8. Exposure Controls/personal protection Control parameters Occupational exposure limits 2-BUTOXYETHANOL Long-term exposure limit (8-hour TWA): OSHA 50 ppm 240 mg/m³ Long-term exposure limit (8-hour TWA): ACGIH 20 ppm 97 mg/m³ Sk, A3 OSHA = Occupational Safety and Health Administration. ACGIH = American Conference of Governmental Industrial Hygienists. Sk = Danger of cutaneous absorption. A3 = Confirmed Animal Carcinogen with Unknown Relevance to Humans. 9. Physical and Chemical Properties Information on basic physical and chemical properties Appearance Color Odor Colored liquid. Milky. White. Ammonia. ph ph (concentrated solution): 9-10 Initial boiling point and range > 100 deg. C (212 deg. F) Vapour pressure Solubility(ies) Volatile organic compound 24 mm Hg @ 25 C/77 F Major portion is soluble in water. 60 g/l 10. Stability and reactivity Stability Conditions to avoid Stable at normal ambient temperatures. Avoid excessive heat for prolonged periods of time. Avoid freezing. 3/5
Materials to avoid Hazardous decomposition products Strong oxidizing agents. Water-reactive materials. Avoid contact with acids and alkalis. Carbon dioxide (CO2). Carbon monoxide (CO). 11. Toxicological information Information on toxicological effects Toxicological effects No specific toxicity tests have been carried out on this product. Acute toxicity - oral ATE oral (mg/kg) 12,500.0 Acute toxicity - dermal ATE dermal (mg/kg) 27,500.0 Acute toxicity - inhalation ATE inhalation (gases ppm) 112,500.0 ATE inhalation (vapours mg/l) 275.0 ATE inhalation (dusts/mists mg/l) 37.5 12. Ecological Information Ecotoxicity There are no data on the ecotoxicity of this product. 13. Disposal considerations Waste treatment methods General information Disposal of this product, process solutions, residues and by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any local authority requirements. 14. Transport information General The product is not covered by international regulations on the transport of dangerous goods (IMDG, IATA, DoT). 15. Regulatory information US Federal Regulations SARA Section 302 Extremely Hazardous Substances Tier II Threshold Planning Quantities None of the ingredients are listed or exempt. CERCLA/Superfund, Hazardous Substances/Reportable Quantities (EPA) Ammonium hydroxide Final CERCLA RQ: 1000(454) pounds (Kilograms) SARA 313 Emission Reporting Ammonium hydroxide 1.0 % 2-BUTOXYETHANOL 1.0 % 4/5
CAA Accidental Release Prevention None of the ingredients are listed or exempt. US State Regulations State Regulations Comments California Prop 65 Warning: This product contains chemicals, as trace impurities and not intentionally added, known to the state of California to cause cancer (C) and birth defects or other reproductive (R) harm. Inventories Canada - DSL/NDSL All the ingredients are listed or exempt. US - TSCA All the ingredients are listed or exempt. US - TSCA 12(b) Export Notification No. 16. Other information Revision date 4/20/2015 Supersedes date 10/1/2014 SDS No. 21086 Hazard statements in full H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H318 Causes serious eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H400 Very toxic to aquatic life. 5/5