glycolic acid formaldehyde free CROSS P U R E C H E M I S T R Y

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GlyAcid glycolic acid formaldehyde free CROSS P U R E C H E M I S T R Y

Pure Chemistry Purity is a fundamental strategy at CrossChem and inherent to the GlyAcid product line. Our unique chemistry and purification process creates a new benchmark for personal care formulations. GlyAcid Technology For more than 40 years, glycolic acid has been predominately produced by either the carbonylation of formaldehyde or with glycolonitrile as a starting material. Both processes leave residual traces of formaldehyde in the finished commercial product. By contrast, CrossChem s GlyAcid is produced using a proprietary acid saponification and purification process that does not use formaldehyde in the process while delivering a high purity glycolic acid in 57% solution, 70% solution and 99% crystalline.

Glycolic Acid In Personal Care Skin Care Glycolic acid is the smallest molecule in the alpha hydroxy acid family. Due to its small molecular size, glycolic acid has proven more effective in helping to release the bonds holding together the top skin cell layers. By removing these old skin cells, the body uncovers fresher, more youthful skin. Nail & Hair Care Glycolic acid continues to see growth in nail and hair care formulations. Nail care benefits include cuticle softening and facilitates healthier looking nails. Hair care benefits include improved manageability, making hair feel softer and easier to style.

FTIR Spectrum Glycolic Acid Standard Glycolic acid is actually an equilibrium between glycolic acid and glycolide (1,4-dioxane-2,5-dioine). This equilibrium is evident in the IR by the two peaks found in the carbonyl region at 1720 cm -1 and 1630 cm -1. FTIR Spectrum Comparative Overlay To ensure formulation consistency and efficacy, we compared the FTIR spectrum of three CrossChem GlyAcid lots with a leading competitor. As shown in the overlay below, GlyAcid possesses an identical infrared spectrum. Upgrade to GlyAcid with confidence and eliminate unwanted impurities in your personal care fomulations. 1083 Absorbance 0.5 0.3 0.2 glycolic acid 1720 1222 3369 1630 1354 1431 994 884 655 Absorbance 0.5 0.5 0.3 0.3 0.2 0.2 0.1 0.1 0.0 3800 3400 3000 2600 2200 1800 1400 1000 600 Wavenumber 0.0 3800 3400 3000 2600 2200 1800 1400 1000 600 3800 3400 3000 2600 2200 1800 1400 1000 600 Wavenumber

GlyAcid 57 HP GlyAcid 57 HP is a high purity glycolic acid in a 57% aqueous solution. It is a clear, virtually colorless liquid with a mild burnt sugar odor. SPECIFICATIONS Limits Typical Results Analytical Method Packaging: 250 Kg Drums Total Acid % Free Acid % Color (APHA) Formaldehyde mg/kg 56-58 52-54 15 Max Report 57.1 52.7 8 U* WQTM - 13 WQTM - 13 WQTM - 03 WQTM - 08 *U: Undetectable - tests show property not detected. Appearance: Clear liquid Stability: GlyAcid 57 HP is stable when stored under normal conditions. If stored at temperatures below 14C (57F), precipitation may occur. This precipitation does not affect product quality. To re-dissolve, heat product to 40C (104F) with agitation. PHYSICAL PROPERTIES Formula Precipitation Point, C (F) Molecular Weight ph, 25C (77F) Density @ 15.6 (60F), lbs/gal g/ml (Mg/m3) Value HOCH2COOH 14 (57) 76.05 10.5 1.27

GlyAcid 70 HP GlyAcid 70 HP is a high purity glycolic acid in a 70% aqueous solution. It is a clear, virtually colorless liquid with a mild burnt sugar odor. SPECIFICATIONS Limits Typical Results Analytical Method Packaging: 25 Kg Pails and 250 Kg Drums Total Acid % Free Acid % Color (APHA) Formaldehyde mg/kg 70-72 63-66 15 Max Report 71.1 64.7 8 U* WQTM - 13 WQTM - 13 WQTM - 03 WQTM - 08 *U: Undetectable - tests show property not detected. Appearance: Clear liquid Stability: GlyAcid 70 HP is stable when stored under normal conditions. If stored at temperatures below 14C (57F), precipitation may occur. This precipitation does not affect product quality. To re-dissolve, heat product to 40C (104F) with agitation. PHYSICAL PROPERTIES Formula Precipitation Point, C (F) Molecular Weight ph, 25C (77F) Density @ 15.6 (60F), lbs/gal g/ml (Mg/m3) Value HOCH2COOH 14 (57) 76.05 10.5 1.27

GlyAcid 99 HP GlyAcid 99 HP is a high purity glycolic acid in 99% crystalline form. Applications include anhydrous formulations or where water is minimized. Packaging: 20 Kg Fiber Drum SPECIFICATIONS Total Acid % Formaldehyde mg/kg Limits 99 Min Report Typical Results 99.3 U* *U: Undetectable - tests show property not detected. Appearance: Clear crystal Analytical Method WQTM - 14 WQTM - 08 PHYSICAL PROPERTIES Formula Molecular Weight State of Matter Melting Point C(F) ph Value HOCH2COOH 76.05 Solid 77 (171) NA

CrossChem LP 5816 Dryden Place Ste 200 Carlsbad CA 92008 USA T +1 (619) 578-0021 F +1 (619) 578-0022 www.crosschem.net/glycolicacid 2014 CrossChem LP All statements in this publication are believed to be accurate and reliable. The user assumes all risks and liability for results obtained by use of the products or applications of the suggestions described. SELLER MAKES NO WARRANTY OF ANY KIND, EITHER EXPRESS OR IMPLIED, BY FACT OR LAW, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. Statements or suggestions concerning possible use of the products are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The claims and supporting data provided in this publication have not been evaluated for compliance with any jurisdiction s regulatory requirements and the results reported may not be generally true under other conditions. Users must evaluate what claims and information are appropriate and comply with a jurisdiction s regulatory requirements. Recipients of this publication agrees to (i) indemnify and hold harmless CrossChem LP for any and all regulatory action arising from recipient s use and any claims or information in this publication including but not limited to use in advertising and finished product label claims, and (ii) not present this publication as evidence of finished product claim substantiation to any regulatory authority.