Material Safety Data Sheet KEYSTONE WASH N WALK FLOOR CLEANER 1. Trade name of product Product use Code Date of issue Product and company identification Product dilution information Supplier's information 2. Physical state Emergency overview KEYSTONE WASH N WALK FLOOR CLEANER Floor Cleaner Up to 2 oz/gal or 16 ml/l in water Ecolab Co. 515 Tomken Road Mississauga ON L4W 2X5 1-8-352-5326 91179-5 18-June-212 EMERGENCY HEALTH INFORMATION 1-8-328-26 Outside United States and Canada CALL 1-651-222-5352 (in USA) Hazards identification Routes of entry Skin contact, Eye contact, Inhalation, Ingestion Potential acute health effects Eyes Moderately irritating to eyes. Skin Inhalation Ingestion Liquid. CAUTION! MAY CAUSE EYE IRRITATION. Avoid contact with eyes. Wash thoroughly after handling. Slightly irritating to the respiratory system. See toxicological information (Section 11) 3. Composition/information on ingredients Liquid. CAUTION! No specific hazard. No specific hazard. Name CAS number % by weight PROPYLENE GLYCOL 57-55-6 3-7 GLYCERIN 56-81-5 3-7 BORIC ACID 143-35-3 3-7 alcohols, c12-16, ethoxylated 68551-12-2 3-7 TETRASODIUM EDTA 64-2-8.5-1.5 COCAMINE OXIDE 61788-9-7.5-1.5 boric acid (h3bo3), compd. with 2-aminoethanol (11) 68586-7-2.5-1.5 lipase, triacylglycerol 91-62-1.1-1 1/6
KEYSTONE WASH N WALK FLOOR CLEANER 18 June 212 3. Composition/information on ingredients Within the present knowledge of the supplier, this product does not contain any hazardous ingredients in quantities requiring reporting, in accordance with local regulations. 4. Eye contact Skin contact Inhalation Ingestion 5. First-aid measures In case of contact, immediately flush eyes with plenty No known effect after eye contact. Rinse with of water. Remove contact lenses and flush again. Get water for a few minutes. medical attention if irritation persists. No known effect after skin contact. Rinse with water for a few minutes. No special measures required. Treat symptomatically. Get medical attention if symptoms occur. Fire-fighting measures Auto-ignition temperature Flammable limits Hazardous thermal decomposition products Special remarks on fire hazards Special remarks on explosion hazards Fire-fighting media and instructions Special protective equipment for fire-fighters 6. Personal precautions Environmental precautions Methods for cleaning up Accidental release measures No known effect after skin contact. Rinse with water for a few minutes. No special measures required. Treat symptomatically. Get medical attention if symptoms occur. Decomposition products may include the following materials carbon dioxide carbon monoxide nitrogen oxides sulfur oxides metal oxide/oxides Use an extinguishing agent suitable for the surrounding fire. Dyke area of fire to prevent runoff. In a fire or if heated, a pressure increase will occur and the container may burst. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Use personal protective equipment as required. Avoid contact of large amounts of spilt material and runoff with soil and surface waterways. Use a water rinse for final clean-up. Use personal protective equipment as required. Avoid contact of large amounts of spilt material and runoff with soil and surface waterways. Use a water rinse for final clean-up. 2/6
KEYSTONE WASH N WALK FLOOR CLEANER 18 June 212 7. Handling Storage 8. Engineering measures Handling and storage Avoid contact with eyes. Wash thoroughly after handling. Do not mix with bleach or other chlorinated products - will cause chlorine gas. Keep out of reach of children. Store in a closed container. Do not store above the following temperature 35 C Exposure controls/personal protection Personal protection Eyes Eye protection should be used when splashing may occur. Hands No protective equipment is needed under normal use conditions. Skin Respiratory Good general ventilation should be sufficient to control worker exposure to airborne contaminants. No protective equipment is needed under normal use conditions. No special protection is required. Wash thoroughly after handling. Keep out of reach of children. Good general ventilation should be sufficient to control worker exposure to airborne contaminants. No protective equipment is needed under normal use conditions. No protective equipment is needed under normal use conditions. No protective equipment is needed under normal use conditions. No special protection is required. Occupational exposure limits TWA (8 hours) STEL (15 mins) Ceiling Ingredient List name ppm mg/m³ Other ppm mg/m³ Other ppm mg/m³ Other Notations boric acid US ACGIH 2/21-2 - - 6 - - - - [a] BC 9/21-2 - - 6 - - - - [b] ON 7/21-2 - - 6 - - - - [1][3][4] propylene glycol - 1 - - - - - - - [c] 5 155 - - - - - - - [d] glycerin US ACGIH 2/21-1 - - - - - - - AB 4/29-1 - - - - - - - [3] [e] BC 9/21-1 - - - - - - - [e] - 3 - - - - - - - [f] ON 7/21-1 - - - - - - - QC 6/28-1 - - - - - - - [g] [1]Absorbed through skin. [3]Skin sensitisation [4]Respiratory sensitisation Form [a]inhalable fraction [b]inhalable [c]aerosol only. [d]vapour and aerosol. [e]mist [f]respirable mist [g]mist 9. Physical and chemical properties Physical state Liquid. Flash point > 1 C Product does not support combustion. Colour Green Odour Fragrance-like ph 6.2 to 9.4 [Conc. (% w/w) 1%] >1 C (>212 F) Boiling/condensation point Melting/freezing point Relative density Vapour pressure Vapour density Odour threshold 1.71 Liquid. > 1 C fluorescent [Light] Fragrance-like 8 to 9.8 3/6
KEYSTONE WASH N WALK FLOOR CLEANER 18 June 212 9. Physical and chemical properties Evaporation rate Viscosity Dispersibility properties Solubility LogKow 1. Easily dispersible in the following materials cold water and hot water. Easily soluble in the following materials cold water and hot water. Stability and reactivity Stability Conditions of instability Reactivity Hazardous decomposition products The product is stable. Under normal conditions of storage and use, hazardous polymerisation will not occur. Do not mix with bleach or other chlorinated products - will cause chlorine gas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Hazardous polymerisation Under normal conditions of storage and use, hazardous polymerisation will not occur. 11. Toxicity data Toxicological information Potential acute health effects Eyes Moderately irritating to eyes. Skin Inhalation Ingestion Slightly irritating to the respiratory system. Potential chronic health effects Carcinogenic effects Mutagenic effects Teratogenic effects Reproductive effects Contains material which may cause reproductive effects, based on animal data. Sensitization to Product Synergistic products (toxicologically) Product/ingredient name Test Route Result Species acetic acid, (ethylenedinitrilo)tetra-, LD5 Oral 17 mg/kg Rat tetrasodium salt boric acid LD5 Dermal >2 mg/kg Rabbit LD5 Oral >26 mg/kg Rat LC5 Inhalation 2.12 mg/l Rat amines, coco alkyldimethyl, n-oxides LD5 Dermal >2174 mg/kg Rat LD5 Oral 846 mg/kg Rat alcohols, c12-16, ethoxylated LD5 Dermal >2 mg/kg Rabbit LD5 Oral 11 mg/kg Rat propylene glycol LD5 Dermal >2 mg/kg Rabbit LD5 Oral 22 mg/kg Rat LC5 Inhalation >158.5 mg/l Rat 4/6
KEYSTONE WASH N WALK FLOOR CLEANER 18 June 212 11. Toxicological information glycerin LD5 Dermal 23 mg/kg Rabbit LD5 Oral 183 mg/kg Rat LC5 Inhalation >2.75 mg/l Rat Other adverse effects Target organs 12. Ecological information Ecotoxicity 13. Waste disposal 14. Contains material which may cause damage to the following organs kidneys, the nervous system, gastrointestinal tract, upper respiratory tract. Not reported Disposal considerations Diluted product can be flushed to sanitary sewer. Discard empty container in trash. Transport information Diluted product can be flushed to sanitary sewer. Discard empty container in trash. Certain shipping modes or package sizes may have exceptions from the transport regulations. The classification provided may not reflect those exceptions and may not apply to all shipping modes or package sizes. TDG Classification For transport in bulk or using IMDG regulations, see shipping documents for specific transportation information. Not intended for transport. Not regulated. 15. WHMIS Regulatory information Class D-2A Material causing other toxic effects (Very toxic). Class D-2B Material causing other toxic effects (Toxic). Not hazardous by WHMIS criteria. Canada inventory All components are listed or exempted. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. 16. Other information Hazardous Material Information System (U.S.A.) Health * 1 Health Physical hazards Physical hazards National Fire Protection Association (U.S.A.) 5/6
KEYSTONE WASH N WALK FLOOR CLEANER 18 June 212 16. Other information Health 1 Instability/Reactivity Health Instability/Reactivity Special Special Date of issue Responsible name 18-June-212 Regulatory Affairs 1-8-352-5326 Indicates information that has changed from previously issued version. Notice to reader The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION. 6/6