Formaldehyde solution 35-37%, stabilized with approx. 10 % methanol

Transcription

1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : Formaldehyde solution 35-37%, stabilized with approx. 10 % SDS-number : Type of product : Mixture Remarks : SDS according to Art. 31 of Regulation (EC) 1907/ Relevant identified uses of the substance or mixture and uses advised against Use of the Substance/Mixture Uses advised against : none : Laboratory chemicals 1.3. Details of the supplier of the safety data sheet Company : Honeywell Specialty Chemicals Seelze GmbH Wunstorfer Straße Seelze Germany Telephone : (49) Telefax : (49) For further information, please contact: 1.4. Emergency telephone number : PMTEU Product Stewardship: SafetyDataSheet@Honeywell.com Honeywell International, Inc. 115 Tabor Road Morris Plains, NJ USA Emergency telephone number Country based Poison Control Center : (ChemTrec-Transport) (Medical) : see chapter 15.1 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture REGULATION (EC) No 1272/2008 Acute toxicity Category 3 - Oral H301 Toxic if swallowed. Acute toxicity Category 3 - Inhalation H331 Toxic if inhaled. Page 1 / 16

2 Acute toxicity Category 3 - Dermal H311 Toxic in contact with skin. Skin corrosion Category 1B H314 Causes severe skin burns and eye damage. Skin sensitisation Category 1 H317 May cause an allergic skin reaction. Germ cell mutagenicity Category 2 H341 Suspected of causing genetic defects. Carcinogenicity Category 1B H350 May cause cancer. Specific target organ toxicity - single exposure Category 1 H370 Causes damage to organs. Specific target organ toxicity - single exposure Category 3 - Respiratory system H335 May cause respiratory irritation Label elements REGULATION (EC) No 1272/2008 Hazard pictograms : Signal word : Danger Hazard statements : H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H341 Suspected of causing genetic defects. H350 May cause cancer. H370 Causes damage to organs. Precautionary statements : P201 Obtain special instructions before use. P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P280 Wear protective gloves/protective clothing/eye protection/face protection. P284 Wear respiratory protection. P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P302 + P352 IF ON SKIN: Wash with plenty of water. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. Page 2 / 16

3 Hazardous components which must be listed on the label Special labelling of certain products: : formaldehyde : Restricted to professional users Other hazards Dermal absorption possible Aspiration hazard if swallowed - can enter lungs and cause damage. SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture CAS-No. Index-No. Chemical name REACH Registration Number EC-No. formaldehyde X Classification 1272/2008 Acute Tox. 3; H301 Acute Tox. 3; H331 Acute Tox. 3; H311 Skin Corr. 1B; H314 Skin Sens. 1; H317 Muta. 2; H341 Carc. 1B; H350 STOT SE 3; H335 Flam. Liq. 2; H225 Acute Tox. 3; H331 Acute Tox. 3; H311 Acute Tox. 3; H301 STOT SE 1; H370 Concentration Remarks >= 25 % - < 50 % 1* >= 10 % - < 20 % 1* 1* - For specific concentration limits see Annexes of 1272/2008 Remaining components of this product are non-hazardous and/or are present at concentrations below reportable limits. Occupational Exposure Limit(s), if available, are listed in Section 8. For the full text of the H-Statements mentioned in this Section, see Section 16. Page 3 / 16

4 SECTION 4: First aid measures 4.1 Description of first aid measures General advice: First aider needs to protect himself. Take off all contaminated clothing immediately. Move out of dangerous area. Inhalation: If breathed in, move person into fresh air. If symptoms persist, call a physician. Skin contact: Wash off with soap and plenty of water. Call a physician immediately. Eye contact: Rinse thoroughly with plenty of water, also under the eyelids. Protect unharmed eye. Remove contact lenses. Call a physician immediately. Ingestion: When swallowed, allow water to be drunk. Do NOT induce vomiting. Call a physician immediately Most important symptoms and, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed See Section 11 for more detailed information on health and symptoms. : SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media: Water spray Foam Carbon dioxide (CO2) Dry powder Extinguishing media which shall not be used for safety reasons: High volume water jet 5.2. Special hazards arising from the substance or mixture Formaldehyde vapors Page 4 / 16

5 5.3. Advice for firefighters Wear self-contained breathing apparatus and protective suit. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.collect contaminated fire extinguishing water separately. This must not be discharged into drains.do not use a solid water stream as it may scatter and spread fire. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Pay attention to flashback. Remove all sources of ignition Environmental precautions Do not flush into surface water or sanitary sewer system. If the product contaminates rivers and lakes or drains inform respective authorities Methods and materials for containment and cleaning up Soak up with inert absorbent material. Pick for disposal in tightly closed containers Dispose of contaminated material as prescribed 6.4. Reference to other sections For personal protection see section 8. SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling: Exhaust ventilation at the object is necessary. Advice on protection against fire and explosion: Normal measures for preventive fire protection. Hygiene measures: General industrial hygiene practice Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers: Store in original container. Keep containers tightly closed in a cool, well-ventilated place. Protect from extreme heat and cold Specific end use(s) Page 5 / 16

6 no additional data available SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits: Components Basis / Value type Value / Form of exposure Exceeding Factor Remarks formaldehyde ELV (IE) STEL 2,5 mg/m3 2 ppm formaldehyde ELV (IE) TWA 2,5 mg/m3 2 ppm ELV (IE) SKIN_DES Can be absorbed through the skin. ELV (IE) TWA 260 mg/m3 200 ppm Indicative OELV EU ELV SKIN_DES EU ELV TWA 260 mg/m3 200 ppm Can be absorbed through the skin. Indicative STEL - Short term exposure limit TWA - Time w eighted average SKIN_DES - Skin designation: DNEL/ PNEC-Values Component End-use / Impact Exposure duration Value Exposure routes Remarks formaldehyde Workers / formaldehyde Workers / local formaldehyde Workers / Acute local 9 mg/m3 Inhalation 0,5 mg/m3 Inhalation 1 mg/m3 Inhalation formaldehyde Workers / 240mg/kg Skin contact formaldehyde Workers / 0,037mg/kg Skin contact Page 6 / 16

7 local formaldehyde Consumers / formaldehyde Consumers / local 3,2 mg/m3 Inhalation 0,1 mg/m3 Inhalation formaldehyde Consumers / formaldehyde Consumers / local formaldehyde Consumers / Consumers / Acute Workers / Acute Consumers / Workers / 102mg/kg 0,012mg/kg 4,1mg/kg 8mg/kg 40mg/kg 8mg/kg 40mg/kg Skin contact Skin contact Ingestion Skin contact Skin contact Skin contact Skin contact Consumers / Acute local Workers / Acute local Consumers / Acute Workers / Acute Page 7 / mg/m3 Inhalation 260 mg/m3 Inhalation 50 mg/m3 Inhalation 260 mg/m3 Inhalation

8 Consumers / local Workers / local Consumers / Workers / 50 mg/m3 Inhalation 260 mg/m3 Inhalation 50 mg/m3 Inhalation 260 mg/m3 Inhalation Component formaldehyde formaldehyde formaldehyde formaldehyde formaldehyde formaldehyde Environmental compartment / Value Fresh w ater: 0,47 mg/l Marine w ater: 0,47 mg/l Sew age treatment plant: 0,19 mg/l Fresh w ater sediment: 2,44 mg/kg dw Marine sediment: 2,44 mg/kg dw Soil: 0,21 mg/kg dw Sew age treatment plant: 100 mg/l Fresh w ater: 20,8 mg/l Marine w ater: 2,08 mg/l Fresh w ater sediment: 77 mg/kg Marine sediment: 7,7 mg/kg Soil: 3,18 mg/kg Remarks Assessment factor: 10 Assessment factor: 10 Assessment factor: 100 Page 8 / 16

9 8.2. Exposure controls Occupational exposure controls The Personal Protective Equipment must be in accordance with EN standards:respirator EN 136, 140, 149; safety glasses EN 166; protective suit: EN 340, 463, 468, 943-1, 943-2; gloves EN 374, safety shoes EN-ISO Ensure that eyewash stations and safety showers are close to the workstation location. Recommended preventive skin protection Engineering measures Use with local exhaust ventilation. Personal protective equipment Respiratory protection: In the case of vapour formation use a respirator with an approved filter. Hand protection: Glove material: Nitrile rubber Break through time: > 480 min Glove thickness: 0,4 mm Camatril 730 Gloves must be inspected prior to use. Replace when worn. Remarks:Supplementary note: The specifications are based on information and tests from similar substances by analogy. Due to varying conditions ( e.g.temperature or other strains) it must be considered that the usage of a chemical protective glove in practice may be much shorter than the permeation time determined in accordance with EN 374. Since actual conditions of practical use often deviate from standardised conditions according EN 374 the glove manufacturer reccomends to use the chemical protective glove in practice not longer than 50% of the recomended permeation time. Manufacturer s directions for use should be observed because of great diversity of types. Suitable gloves tested according EN 374 are supplied e.g. from KCL GmbH, D Eichenzell, Vertrieb@kcl.de Eye protection: Safety goggles Skin and body protection: Protective suit Environmental exposure controls Handle in accordance with local environmental regulations and good industrial practices. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Page 9 / 16

10 Form : liquid Colour : colourless Odour : stinging Melting point/range : < -15 C Boiling point/boiling range : C at hpa Flash point : 64 C Method: DIN Flammability (solid, gas) : Not applicable Ignition temperature : > 400 C Auto-ignition temperature : not auto-flammable Oxidizing properties : The substance or mixture is not classified as oxidizing. Lower explosion limit : Upper explosion limit : Vapour pressure : 1,3 hpa at 20 C Density : 1,080-1,090 g/cm3 at 20 C Viscosity, dynamic : ca. 2,6 mpa.s at 20 C ph : 3,5-4,5 at 20 C (undiluted) Water solubility : completely miscible Partition coefficient: n- octanol/water : log Pow 0,779 at: 20 C 9.2 Other Information no additional data available Page 10 / 16

11 SECTION 10: Stability and reactivity Reactivity Stable under normal conditions Chemical stability No decomposition if used as directed Possibility of hazardous reactions Reactions with strong alkalies. Reactions with organic substances. Formation of explosive gas/air mixtures Conditions to avoid Heating will cause pressure rise with risk of bursting Protect from frost, heat and sunlight Incompatible materials Uncleaned empty vessels may contain product gases which can form explosive mixtures with air. Strong oxidizing agents Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological Acute oral toxicity: Acute toxicity estimate Value: 215,05 mg/kg Method: Calculation method Acute dermal toxicity: Acute toxicity estimate Value: 645,16 mg/kg Method: Calculation method Acute inhalation toxicity: Acute toxicity estimate Value: 1505 ppm Exposure time: 4 h Method: Calculation method Page 11 / 16

12 Skin irritation: Classification based on Annex VI of regulation 1272/2008/EC. Eye irritation: Classification based on Annex VI of regulation 1272/2008/EC. Respiratory or skin sensitisation: Classification based on Annex VI of regulation 1272/2008/EC. Aspiration hazard: Other information: SECTION 12: Ecological information Toxicity Toxicity to fish: Toxicity to aquatic plants: Toxicity to Microorganisms: Toxicity to aquatic invertebrates: Persistence and degradability Biodegradability: Inherently biodegradable Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Page 12 / 16

13 12.6. Other adverse Do not flush into surface water or sanitary sewer system. SECTION 13: Disposal considerations Waste treatment methods Product: Dispose according to legal requirements. Packaging: Legal requirements are to be considered in regard of reuse or disposal of used packaging materials Further information: Provisions relating to waste: EC Directive 2006/12/EC; 2008/98/EEC Regulation No. 1013/2006 For personal protection see section 8. SECTION 14: Transport information ADR/RID UN Number : 2209 Description of the goods : FORMALDEHYDE SOLUTION Class : 8 Packaging group : III Classification Code : C9 Hazard Identification : 80 Number ADR/RID-Labels : 8 Environmentally hazardous : no IATA UN Number : 2209 Description of the goods : Formaldehyde solution Class : 8 Packaging group : III Hazard Labels : 8 IMDG UN Number : 2209 Description of the goods : FORMALDEHYDE SOLUTION Class : 8 Packaging group : III Hazard Labels : 8 EmS Number : F-A, S-B Marine pollutant : no IMDG Code segregation group 1 ACIDS, Page 13 / 16

14 Other information : Storage-/Transp.-Temp. > 10 C SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison Control Center Country Phone Number Country Phone Number Austria Latvia Belgium Liechtenstein Bulgaria (+) Lithuania Croatia (+3851) Luxembourg ; (+352) Cyprus Malta Czech Republic ; Netherlands Denmark Norw ay Estonia 16662; (+372) Poland Finland Portugal France +33(0) Romania Greece Slovakia (NTIC) Hungary (+36-80) Slovenia Iceland Spain (begär Ireland +353(1) Sw eden Giftinformation); Italy United Kingdom Berlin : 030/19240 Bonn : 0228/19240 Erfurt : 0361/ Germany Freiburg : 0761/19240 Göttingen : 0551/19240 Homburg : 06841/19240 Mainz : 06131/19240 Munich : 089/19240 Other inventory information US. Toxic Substances Control Act On TSCA Inventory Page 14 / 16

15 Australia. Industrial Chemical (Notification and Assessment) Act On the inventory, or in compliance with the inventory Canada. Canadian Environmental Protection Act (CEPA). Domestic Substances List (DSL) All components of this product are on the Canadian DSL Japan. Kashin-Hou Law List On the inventory, or in compliance with the inventory Korea. Toxic Chemical Control Law (TCCL) List On the inventory, or in compliance with the inventory Philippines. The Toxic Substances and Hazardous and Nuclear Waste Control Act On the inventory, or in compliance with the inventory China. Inventory of Existing Chemical Substances On the inventory, or in compliance with the inventory New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand On the inventory, or in compliance with the inventory 15.2 Chemical safety assessment A Chemical Safety Assessment has not been carried out. SECTION 16: Other information Text of H-statements referred to under heading 3 Formaldehyde : H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H341 Suspected of causing genetic defects. H350 May cause cancer. Methanol : H225 Highly flammable liquid and vapour. H331 Toxic if inhaled. H311 Toxic in contact with skin. H301 Toxic if swallowed. H370 Causes damage to organs. Further information All directives and regulations refer to amended versions. Vertical lines in the left hand margin indicate a relevant amendment from the previous version. Page 15 / 16

16 Abreviations: EC European Community CAS Chemical Abstracts Service DNEL Derived no effect level PNEC Predicted no effect level vpvb Very persistent and very biaccumulative substance PBT Persistent, bioaccmulative und toxic substance The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Final determination of suitability of any material is the sole responsibility of the user. This information should not constitute a guarantee for any specific product properties. Page 16 / 16