SAFETY DATA SHEET according to 1907/2006/EC, Article 31
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1 SAFETY DATA SHEET according to 1907/2006/EC, Article 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name 1.2. Relevant identified uses of the substance or mixture and uses advised against Product Use Description 1.. Details of the supplier of the safety data sheet Company Address date [SU] Industrial uses: Uses of substances as such or in preparations at industrial sites; [SU0] Other; [PC7] Water treatment chemicals; High ph RO Membrane Cleaner - Powder. FOR INDUSTRIAL USE. Avista Technologies (UK) Ltd 1 Nasmyth Square Houstoun Industrial Estate Livingston EH54 5GG United Kingdom Telephone +44 (0) Fax +44 (0) address of the competent person 1.4. Emergency telephone number productsupport@avistatech.co.uk sds@avistatech.co.uk Emergency telephone number +44 (0) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification - 67/548/EEC Main hazards Classification - EC 1272/ Label elements Hazard pictograms (GMT, English spoken, Mon - Fri; ) Xn; R22 Xi; R8-41 Symbols: Xn: Harmful. Harmful if swallowed. Irritating to skin. Risk of serious damage to eyes. Acute Tox. 4: H02+H2; Eye Dam. 1: H18; 1/6 Signal Word Hazard Statement Precautionary Statement: Prevention Danger Acute Tox. 4: H02+H2 - Harmful if swallowed or if inhaled. Eye Dam. 1: H18 - Causes serious eye damage. P260 - Do not breathe dust/fume/gas/mist/vapours/spray. P262 - Do not get in eyes, on skin, or on clothing. P264 - Wash hands thoroughly after handling.
2 2.2. Label elements Precautionary Statement: Response Precautionary Statement: Disposal 2.. Other hazards Other hazards P270 - Do no eat, drink or smoke when using this product. P271 - Use only outdoors or in a well-ventilated area. P280 - Wear protective gloves/protective clothing/eye protection/face protection. date 2/6 P01+P12 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P0+P61+P5 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P04+P40 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P05+P51+P8 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P10 - Immediately call a POISON CENTER or doctor/physician. P12 - Call a POISON CENTER or doctor/physician if you feel unwell. P0 - Rinse mouth. P501 - Dispose of contents/container to local and national regulations SECTION : Composition/information on ingredients.1. Substances 67/548/EEC / 1999/45/EC Chemical Name Index No. CAS No. EC No. REACH Registration Number Conc. (%w/w) Classification Sodium Percarbonate % O; R8 Xn; R22 Xi; R6/8 tetrasodium ethylene diamine % Xn; R22 Xi; R41 Sodium carbonate % Xi; R6 EC 1272/2008 Chemical Name Index No. CAS No. EC No. REACH Registration Number Conc. (%w/w) Classification Sodium Percarbonate % Ox. Sol. 2: H272; Acute Tox. 4: H02; Skin Irrit. 2: H15; Eye Irrit. 2: H19; tetrasodium ethylene diamine % Acute Tox. 4: H02; Eye Dam. 1: H18; Sodium carbonate % Eye Irrit. 2: H19;.2. Mixtures SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Eye contact Skin contact Ingestion See section.1 for further information. If you feel unwell, seek medical advice (show the label where possible). Immediate medical attention is required. If you feel unwell, seek medical advice (show the label where possible). If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label Most important symptoms and effects, both acute and delayed Inhalation Eye contact Skin contact Ingestion Harmful by inhalation. CAUSES EYE BURNS. Irritating to skin. Harmful by inhalation and if swallowed.
3 4.. Indication of any immediate medical attention and special treatment needed Inhalation Skin contact Ingestion SECTION 5: Firefighting measures 5.1. Extinguishing media 5.2. Special hazards arising from the substance or mixture 5.. Advice for firefighters SECTION 6: Accidental release measures date Move the exposed person to fresh air. Seek medical attention if irritation or symptoms persist. Rinse immediately with plenty of water for 15 minutes holding the eyelids open. Seek medical attention if irritation or symptoms persist. /6 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. Use extinguishing media appropriate to the surrounding fire conditions. EXTINGUISHING MEDIA:. Water spray. Foam. Dry chemical. Carbon dioxide (CO2). In case of fire and/or explosion do not breathe fumes. Burning produces irritating, toxic and obnoxious fumes. Wear suitable respiratory equipment when necessary Personal precautions, protective equipment and emergency procedures 6.2. Environmental precautions 6.. Methods and material for containment and cleaning up 6.4. Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Ensure adequate ventilation of the working area. Wear suitable protective clothing, gloves and eye/face protection. Do not allow runoff water to enter sewers or drains. Do not empty into drains; dispose of this material and its container in a safe way. Prevent further spillage if safe. Absorb with inert, absorbent material. Sweep up. Transfer to suitable, labelled containers for disposal. Clean spillage area thoroughly with plenty of water. See section 8 for further information Conditions for safe storage, including any incompatibilities 7.. Specific end use(s) Suitable packaging Adopt best Manual Handling considerations when handling, carrying and dispensing. Avoid contact with eyes and skin. Use in a well ventilated area. Keep container tightly closed. Keep in a cool, dry, well ventilated area. Store in correctly labelled containers. Keep away from food, drink and animal feedingstuffs. Water treatment chemicals. Plastic containers. SECTION 8: Exposure controls/personal protection 8.2. Exposure controls Appropriate engineering controls Ensure adequate ventilation of the working area.
4 8.2. Exposure controls Individual protection measures Wear protective clothing. Eye / face protection Face shield. (Standard EN 166). Skin protection - Handprotection Respiratory protection SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties date 4/6 Chemical resistant gloves (PVC). (Standard EN74-1). Material of Gloves: Nitrile Rubber NBR; Penetration time of Glove material: Thickness 0.4 mm; break-through time: 480 min: material: Nitrile; permeation: level 6. In case of insufficient ventilation, wear suitable respiratory equipment. Suitable half mask respirator with filter P2 (EN 14). State Powder Colour White Odour Slight ph (2% w/w in DI water) Melting point No data available Boiling point No data available Flash point No data available Evaporation rate No data available Flammability limits No data available Autoignition temperature No data available 9.2. Other information Explosive No data available Oxidising No data available Partition coefficient No data available Viscosity No data available Vapour Flammability No data available Solubility Miscible in water Conductivity No data available Surface tension No data available Bulk Density Not determined SECTION 10: Stability and reactivity Reactivity Chemical stability 10.. Possibility of hazardous reactions Conditions to avoid Incompatible materials Stable under normal conditions. Stable under normal conditions Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Keep away from direct sunlight. Keep in a cool, dry, well ventilated area. Avoid contact with: Oxidising agents, Acids.
5 11.1. Information on toxicological effects Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard Repeated or prolonged exposure Toxicological Information Irritating to skin. CAUSES EYE BURNS. No sensitizaton effects reported. No mutagenic effects reported. No carcinogenic effects reported. No teratogenic effects reported. Avoid prolonged or repeated exposure. date 5/6 Sodium Percarbonate Oral Rat LD50: 2400 mg/kg Oral Mouse LD50: 2200 mg/kg tetrasodium ethylene diamine SECTION 12: Ecological information Toxicity Inhalation Rat LC50/6 h: mg/m (OECD guideline 40) Oral Rat LD50: 1,780-2,000 mg/kg Sodium Percarbonate Daphnia EC50/48h: mg/l Fish LC50/96h: mg/l tetrasodium ethylene diamine Persistence and degradability 12.. Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 1: Disposal considerations 1.1. Waste treatment methods Disposal methods Disposal of packaging SECTION 14: Transport information ADR/RID IMDG Daphnia EC50/48h: > 100 mg/l mg/l Not readily biodegradable. Does not bioaccumulate. Fish LC50/96h: > 100 mg/l mg/l This material and its container must be disposed of in a safe way. Dispose of in compliance with all local and national regulations. Algae IC50/72h: > 100 mg/l mg/l Empty containers can be sent for disposal or recycling. Empty containers can be sent to landfill after cleaning, if in compliance with local and national regulations. The product is not classified as dangerous for carriage.
6 6/6 date IMDG The product is not classified as dangerous for carriage. IATA The product is not classified as dangerous for carriage. SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Regulations Chemical safety assessment Further information SECTION 16: Other information Other information Text of risk phrases in Section Text of Hazard Statements in Section Further information COMMISSION REGULATION (EU) No 45/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 79/9 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 9/67/EEC, 9/105/EC and 2000/21/EC. REGULATION (EC) No 1907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 79/9 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 9/67/EEC, 9/105/EC and 2000/21/EC. Not applicable. FOR INDUSTRIAL USE. Water Hazard Class:. WGK 1. This document differs from the previous version in the following areas: Information on basic physical and chemical properties (Odour). R8 - Contact with combustible material may cause fire. R22 - Harmful if swallowed. R6/8 - Irritating to eyes and skin. R6 - Irritating to eyes. R41 - Risk of serious damage to eyes. Ox. Sol. 2: H272 - May intensify fire; oxidiser. Acute Tox. 4: H02 - Harmful if swallowed. Skin Irrit. 2: H15 - Causes skin irritation. Eye Irrit. 2: H19 - Causes serious eye irritation. Eye Dam. 1: H18 - Causes serious eye damage. The information supplied in this Safety Data Sheet is designed only as guidance for the safe use, storage and handling of the product. This information is correct to the best of our knowledge and belief at the date of publication however no guarantee is made to its accuracy. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any other process.
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