SAFETY DATA SHEET according to 29 CFR

Transcription

1 SAFETY DATA SHEET according to 29 CFR /7 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier date Product name Product Code 11635, , , , , , , Details of the supplier of the safety data sheet Company Address Web Neogen Corporation 62 Lesher Place Lansing MI USA Telephone / Emergency telephone number Emergency telephone number Emergency Telephone Number Manufactured By Registered By EPA Registration No SECTION 2: Hazards identification 2.1. Classification of the substance or mixture regulatorysupport@neogen.com Hotline Number: (United States and Canada), (All other areas). HACCO, Inc. 11 Hopkins Dr. Randolph, WI HACCO, Inc.; a wholly owned subsidiary of Neogen Corporation Classification - GHS Skin Irrit. 2: H315; Eye Irrit. 2B: H32; 2.2. Label elements Hazard pictograms Signal Word Hazard Statement Warning Skin Irrit. 2: H315 - Causes skin irritation. Eye Irrit. 2B: H32 - Causes eye irritation. Copyright 217 ChemSoft. All rights reserved

2 date 2/ Label elements Precautionary Statement: Prevention Precautionary Statement: Response P264 - Wash thoroughly after handling. P28 - Wear protective gloves/protective clothing/eye protection/face protection. P32+P352 - IF ON SKIN: Wash with plenty of water/. P35+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332+P313 - If skin irritation occurs: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical advice/attention. SECTION 3: Composition/information on ingredients 3.2. Mixtures EC 1272/28 Chemical Name Index No. CAS No. EC No. REACH Registration Number Conc. (%w/w) Classification Diphacinone % Acute Tox. 2: H3; Acute Tox. 2: H31; Skin Irrit. 2: H315; Oats, Rolled 1-2% Acute Tox. 3: H31+H331; Skin Irrit. 2: H315; Eye Irrit. 2B: H32; Xylene (Xylene (o, m & p isomers)) Flam. Liq. 3: H226; Acute Tox. 4: H332; Acute Tox. 4: H312; Skin Irrit. 2: H315; SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Eye contact Skin contact Ingestion 4.2. Most important symptoms and effects, both acute and delayed Inhalation Eye contact Skin contact Ingestion In case of accident by inhalation: remove casualty to fresh air and keep at rest. Rinse immediately with plenty of water for 15 minutes holding the eyelids open. Remove contact lenses, if present and easy to do. Continue rinsing. After contact with skin, take off immediately all contaminated clothing, and wash immediately with plenty of water. Immediate medical attention is required. Have person sip a glass of water if able to swallow. Do not induce vomitting unless told to do so by the poison control center or doctor. May cause irritation to respiratory system. Causes eye irritation. Harmful if absorbed through the skin. Harmful if swallowed Indication of any immediate medical attention and special treatment needed Eye contact Skin contact Ingestion NOTE TO PHYSICIAN TREATMENT FOR PET POISONING NOTE TO VETERINARIAN Immediate medical attention is required. Immediate medical attention is required. Immediate medical attention is required. If swallowed, this material may reduce the clotting ability of the blood and cause bleeding. If ingested, administer Vitamin K1, intramuscularly or orally. Repeat as necessary based on monitoring of prothrombin times. If animal eats bait, call veterinarian or at once. Anticoagulant Diphacinone: For animals ingesting bait and/or showing poisoning signs (bleeding Copyright 217 ChemSoft. All rights reserved

3 3/7 date or elevated prothrombin times), give Vitamin K1. SECTION 5: Firefighting measures 5.1. Extinguishing media 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters SECTION 6: Accidental release measures Use extinguishing media appropriate to the surrounding fire conditions. Burning produces irritating, toxic and obnoxious fumes. Wear:. Protective equipment. Self-contained breathing apparatus Personal precautions, protective equipment and emergency procedures 6.2. Environmental precautions 6.3. Methods and material for containment and cleaning up 6.4. Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid contact with skin and eyes. Wear suitable protective clothing, gloves and eye/face protection. This product is extremely toxic to mammals, birds and other wildlife. Dogs, cats and scavenging mammals and birds might be poisoned if they feed upon animals that have eaten this bait. Do not apply directly to water, or to areas where surface water is present or to intertidal areas below the mean high water mark. Do not allow bait to be exposed on soil surface. Do not apply where runoff is likely to occur. Do not contaminate water when disposing of equipment wash water or rinsate. Sweep up. Dispose of in compliance with all local and national regulations. See section 7, 8, 13 for further information Conditions for safe storage, including any incompatibilities Suitable packaging 7.3. Specific end use(s) All handlers (including applicators) must wear long pants, shoes, socks and barrier laminate gloves. Any person who retrieves carcasses or unused bait following application of this product must wear barrier laminate gloves. Do not handle the product near food, animal foodstuffs, or drinking water. Wash hands after handling the product and dead rodents. Keep out of reach of children, pets, and non-target animals. Keep away from food, drink and animal feedingstuffs. Keep container tightly closed. Store in a cool, dry area. Store in original container. See section 1.2 for further information. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Exposure Limit Values Copyright 217 ChemSoft. All rights reserved

4 4/7 date Exposure Limit Values Oats, Rolled ACGIH TLV TWA: 4mg/m3 ACGIH TLV STEL: Notations: OSHA PEL 8hr TWA mg m3: 1mg/m3 OSHA PEL 8hr TWA ppm: Skin Designation: Wax (Paraffin wax fume) ACGIH TLV TWA: 2 mg/m³ ACGIH TLV STEL: - Xylene (Xylene (o, m & p isomers)) Notations: - OSHA PEL 8hr TWA ppm: - OSHA PEL 8hr TWA mg m3: - Skin Designation: - ACGIH TLV TWA: 1 ppm ACGIH TLV STEL: 15 ppm Notations: A4; BEI OSHA PEL 8hr TWA ppm: 1 OSHA PEL 8hr TWA mg m3: 435 Skin Designation: Exposure controls Eye / face protection Skin protection - Hand protection Skin protection - Other Respiratory protection Thermal hazards Not normally required. Any person who retrieves carcasses or unused bait following application of this product must wear barrier laminate gloves. Wash hands after handling the product and dead rodents. All handlers (including applicators) must wear long pants, shoes, socks and barrier laminate gloves. Not normally required. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties State Solid Color Green/Yellow Odor Slight Odour threshold No data available ph Not applicable. Melting point 37-1 C Freezing Point No data available Boiling point No data available Flash point > 175 C Evaporation rate <.1 Flammability limits No data available Vapor pressure Not applicable. Vapor density Not applicable. Relative density No data available Fat Solubility No data available Partition coefficient No data available Autoignition temperature No data available Viscosity Not applicable. Explosive properties No data available Oxidising properties No data available Solubility Insoluble in water 9.2. Other information Copyright 217 ChemSoft. All rights reserved

5 5/7 date Other information Conductivity Not applicable. Surface tension Not applicable. Gas group Not applicable. Benzene Content No data available Lead content No data available VOC (Volatile organic compounds) SECTION 1: Stability and reactivity 1.1. Reactivity 1.2. Chemical stability 1.3. Possibility of hazardous reactions 1.4. Conditions to avoid No data available 1.6. Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects Stable under normal conditions. Heat, sparks and open flames. Burning produces irritating, toxic and obnoxious fumes. Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard Toxicological information No Significant Hazard. Not found to be a potential carcinogen in the International Agency for Research on Cancer (IARC) Monographs, Volumes Not listed in the National Toxicology Program (NTP) 13th Report on Carcinogens. Not listed in the OSHA standard Carcinogens. May cause damage to human organs based on animal data. May cause damage to human organs based on animal data. No Significant Hazard. Diphacinone Oral Rat LD5: 23 mg/kg Dermal Rabbit LD5: 3, mg/kg SECTION 12: Ecological information Persistence and degradability Bioaccumulative potential Copyright 217 ChemSoft. All rights reserved

6 6/7 date Bioaccumulative potential Partition coefficient No data available Wax < Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Disposal methods Disposal of packaging SECTION 14: Transport information UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Special precautions for user This product is extremely toxic to mammals, birds, and other wildlife. Dogs, cats, and scavenging mammals, and birds might be poisoned if they feed upon animals that have eaten this bait. Dispose of in compliance with all local and national regulations. Dispose of in compliance with label directions. Dispose of in compliance with all local and national regulations. Do NOT reuse empty containers Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Regulations Chemical safety assessment Hazard Communication Standard: 29 Code of Federal Regulations : Occupational Safety and Health Standards: Z: Toxic and Hazardous Substances: Hazard Communication. No data available. Copyright 217 ChemSoft. All rights reserved

7 7/7 date Inventories Ingredient TSCA MA SARA313 CALPROP65 CWA37 CAA112 CWA311 SARA32 SARA34 Diphacinone N N N N N N N Y 1/1, Y 1 Wax (Paraffin waxes and Hydrocarbon Y N N N N N N N N waxes) Xylene (Benzene, dimethyl-) Y Y Y 1. N N Y Y N N FIFRA EPA Registration No FIFRA Signal Word FIFRA Warning SECTION 16: Other information Other information This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. CAUTION. Harmful if swallowed or absorbed through the skin. Causes moderate eye irritation. Avoid contact with eyes, skin, or clothing. Keep away from children, domestic animals and pets. Text of Hazard Statements in Section 3 General information Acute Tox. 2: H3+H31 - Fatal if swallowed or in contact with skin Skin Irrit. 2: H315 - Causes skin irritation. Acute Tox. 3: H31+H331 - Toxic if swallowed or if inhaled Eye Irrit. 2B: H32 - Causes eye irritation. Flam. Liq. 3: H226 - Flammable liquid and vapour. Acute Tox. 4: H312 - Harmful in contact with skin. Acute Tox. 4: H332 - Harmful if inhaled. HACCO, Inc. is a wholly owned subsidiary of Neogen Corporation. It is a violation of Federal law to use this product in a manner inconsistent with its labeling. DISCLAIMER: The information and recommendations set forth herein ("Information") are presented in good faith and believed to be correct as of the date issued. No representation is made regarding the completeness or accuracy of the Information. Further, because of the many factors that affect the use of this product, the Information is supplied upon the condition that the person(s) receiving it will make their own determination regarding its suitability for their own unique purpose(s), prior to use. Except as expressly stated herein, NO WARRANTIES, GUARANTEES, OR REPRESENTATIONS OF ANY KIND, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, IMPLIED WARRANTY OF MECHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, COURSE OF PERFORMANCE, USAGE OF TRADE, OR RESULTS TO BE OBTAINED BY USE OF THIS PRODUCT are made with respect to this product or use of this product. The product covered is furnished "as is" and only subject to the warranties herein provided, no liability is assumed resulting from the use of this product. Copyright 217 ChemSoft. All rights reserved