SAFETY DATA SHEET. Acute toxicity, dermal Skin corrosion/irritation Serious eye damage/eye irritation

Transcription

1 SAFETY DATA SHEET 1. Identification Product identifier means of identification Item Recommended use Recommended restrictions Semi-Volatiles Mixture #6-8250A M-SV82506X4 For Laboratory Use Only ne known. Manufacturer/Importer/Supplier/Distributor information Manufacturer Company name Chem Service, Inc. Address 660 Tower Lane West Chester, PA Telephone United States Toll Free Direct Website Emergency phone number Chemtrec US Chemtrec outside US Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Label elements t classified. toxicity, oral toxicity, dermal Skin corrosion/irritation Serious eye damage/eye irritation Carcinogenicity Reproductive toxicity (fertility) Specific target organ toxicity, repeated exposure Hazardous to the aquatic environment, acute hazard Hazardous to the aquatic environment, long-term hazard t classified. Category 4 Category 4 Category 2 Category 2A Category 1A Category 2 Category 2 Category 3 Category 3 Signal word Hazard statement Precautionary statement Prevention Response Danger Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. May cause cancer. Suspected of damaging fertility. May cause damage to organs through prolonged or repeated exposure. Harmful to aquatic life. Harmful to aquatic life with long lasting effects. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. If swallowed: Call a poison center/doctor if you feel unwell. If on skin: Wash with plenty of water. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If exposed or concerned: Get medical advice/attention. Call a poison center/doctor if you feel unwell. Specific treatment (see this label). Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse. 1 / 17

2 Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. ne known. 0.6% of the mixture consists of component(s) of unknown acute oral toxicity. 1.2% of the mixture consists of component(s) of unknown acute dermal toxicity. 98% of the mixture consists of component(s) of unknown acute hazards to the aquatic environment. 97.9% of the mixture consists of component(s) of unknown long-term hazards to the aquatic environment. 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % Methylene chloride DICHLOROMETHANE; METHYLENE DICHLORIDE 1,2,4,5-Tetrachlorobenzene Chloronaphthalene ,3,4,6-Tetrachlorophenol ,4,5-Trichlorophenol ,4,6-Trichlorophenol ,4-Dinitrophenol (min 15wt% water) ,4-Dinitrotoluene ,6-Dinitrotoluene Chloronaphthalene Chlorophenyl phenyl ether Nitrophenol Acenaphthene Acenaphthylene a-naphthylamine b-naphthylamine Dibenzofuran Diethyl phthalate Dimethyl phthalate Fluorene m-nitroaniline o-nitroaniline Pentachlorobenzene p-nitroaniline *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret First-aid measures Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed Move to fresh air. Call a physician if symptoms develop or persist. Wash with plenty of soap and water. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Rinse mouth. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. Prolonged exposure may cause chronic effects. Provide general supportive measures and treat symptomatically. In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed. 2 / 17

3 General information 5. Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions Specific methods General fire hazards IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire. During fire, gases hazardous to health may be formed. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Move containers from fire area if you can do so without risk. Use standard firefighting procedures and consider the hazards of other involved materials. unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Environmental precautions 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe mist or vapor. Do not taste or swallow. Avoid contact with skin. Avoid contact with eyes. Avoid contact during pregnancy/while nursing. Avoid prolonged exposure. Avoid contact with clothing. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. When using, do not eat, drink or smoke. Wash hands thoroughly after handling. Wash contaminated clothing before reuse. Avoid release to the environment. Do not empty into drains. Store locked up. Store in original tightly closed container. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Specifically Regulated Substances (29 CFR ) Type Methylene chloride (CAS STEL ) US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) Type Value 125 ppm 25 ppm Value 2,4-Dinitrotoluene (CAS ) 2,6-Dinitrotoluene (CAS ) 4-Chlorophenyl phenyl ether (CAS ) Dimethyl phthalate (CAS ) p-nitroaniline (CAS ) PEL PEL PEL PEL PEL 1.5 mg/m3 1.5 mg/m3 0.5 mg/m3 5 mg/m3 6 mg/m3 1 ppm 3 / 17

4 US. ACGIH Threshold Limit Values Type Value 2,4-Dinitrotoluene (CAS ) 2,6-Dinitrotoluene (CAS ) Diethyl phthalate (CAS ) Dimethyl phthalate (CAS ) Methylene chloride (CAS ) p-nitroaniline (CAS ) US. NIOSH: Pocket Guide to Chemical Hazards Type 0.2 mg/m3 0.2 mg/m3 5 mg/m3 5 mg/m3 50 ppm 3 mg/m3 Value 2,4-Dinitrotoluene (CAS ) 2,6-Dinitrotoluene (CAS ) 4-Chlorophenyl phenyl ether (CAS ) Diethyl phthalate (CAS ) Dimethyl phthalate (CAS ) p-nitroaniline (CAS ) Biological limit values 1.5 mg/m3 1.5 mg/m3 0.5 mg/m3 5 mg/m3 5 mg/m3 3 mg/m3 ACGIH Biological Exposure Indices Value Determinant Specimen Sampling Time Methylene chloride (CAS ) 0.3 mg/l Dichlorometha ne * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation US - Minnesota Haz Subs: Skin designation applies US - Tennesse OELs: Skin designation US ACGIH Threshold Limit Values: Skin designation Urine * Skin designation applies. Skin designation applies. Skin designation applies. US NIOSH Pocket Guide to Chemical Hazards: Skin designation US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. 4 / 17

5 Individual protection measures, such as personal protective equipment Eye/face protection Wear eye/face protection. Wear safety glasses with side shields (or goggles). Skin protection Hand protection Respiratory protection Thermal hazards General hygiene considerations Wear appropriate chemical resistant gloves. Wear appropriate chemical resistant clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Wear appropriate thermal protective clothing, when necessary. When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Odor Physical state Form Color Odor threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Liquid. Liquid -139 F (-95 C) estimated F (39.75 C) estimated Upper/lower flammability or explosive limits Flammability limit - lower 15.5 % estimated (%) Flammability limit - upper (%) 66.4 % estimated Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Relative density Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity information Density Percent volatile Specific gravity VOC (Weight %) hpa estimated 1033 F ( C) estimated g/cm3 estimated 97.9 % estimated 1.33 estimated 97.9 % estimated 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. Hazardous polymerization does not occur. Contact with incompatible materials. Strong oxidizing agents. 5 / 17

6 Hazardous decomposition products Toxic gas. 11. Toxicological information Information on likely routes of exposure Ingestion Harmful if swallowed. Skin contact Eye contact Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects toxicity 1-Chloronaphthalene (CAS ) Prolonged inhalation may be harmful. May cause damage to organs by inhalation. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. Harmful if swallowed. Harmful in contact with skin. Species 2,3,4,6-Tetrachlorophenol (CAS ) Rabbit Gerbil Dog Rabbit Dog Test Results 2000 mg/kg 1091 mg/kg 1540 mg/kg 250 mg/kg 698 mg/kg 250 mg/kg 131 mg/kg 140 mg/kg 82 mg/kg 130 mg/kg 820 mg/kg 0.82 g/kg 355 mg/kg 820 mg/kg 276 mg/kg 20 mg/kg 45 mg/kg 30 mg/kg 30 mg/kg 20 mg/kg 6 / 17

7 Species Test Results 26 mg/kg 20 mg/kg > 2500 mg/kg 0.24 mg/l Cat 27 mg/kg 1300 mg/kg 750 mg/kg 268 mg/kg TD Dog 1 mg/kg > 500 mg/kg > 2500 mg/kg 0.24 mg/l Cat 27 mg/kg 1300 mg/kg 621 mg/kg 177 mg/kg TD Dog 4 mg/kg > 500 mg/kg 2-Chloronaphthalene (CAS ) 886 mg/kg 2078 mg/kg 380 mg/kg Rabbit 220 mg/kg mg/kg 75 mg/kg 447 mg/kg > mg/l, 4 Hours 680 mg/kg 96 mg/kg 7 / 17

8 Diethyl phthalate (CAS ) - Species Rabbit Rabbit Hen Rabbit Test Results 620 mg/kg > mg/kg > 10 ml/kg > 511 ppm, 6 Hours > 4.64 mg/l, 6 Hours 2500 mg/kg 1000 mg/kg mg/kg 8.2 ml/kg 3.22 g/kg 2.87 ml/kg > mg/kg mg/kg 6.76 mg/l > 10.4 mg/l, 6 Hours 2400 mg/kg mg/kg 7200 mg/kg 5300 mg/kg 2400 mg/kg 1380 mg/kg 324 mg/kg > 2000 mg/kg ppm, 6 Hours 40.2 mg/l, 6 Hours ppm, 7 Hours 51.5 mg/l, 2 Hours 49.1 mg/l, 6 Hours 49 mg/l, 7 Hours 2000 mg/l, 15 Minutes 88 mg/l, 900 Days 79 mg/l, 2 Hours 52 mg/l, 6 Hours ppm, 7 Hours 8 / 17

9 m-nitroaniline (CAS ) o-nitroaniline (CAS ) Species Rabbit Test Results 1600 mg/kg 437 mg/kg 450 mg/kg 308 mg/kg 535 mg/kg > 7940 mg/kg > mg/l, 4 Hours 2350 mg/kg 1070 mg/kg 1600 mg/kg 1175 mg/kg 940 mg/kg > 2500 mg/kg 450 mg/kg 810 mg/kg 750 mg/kg 250 mg/kg * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity Causes skin irritation. Causes serious eye irritation. This product is not expected to cause skin sensitization. data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. May cause cancer. IARC Monographs. Overall Evaluation of Carcinogenicity 2,3,4,6-Tetrachlorophenol (CAS ) Acenaphthene (CAS ) Fluorene (CAS ) 2B Possibly carcinogenic to humans. 2B Possibly carcinogenic to humans. 2B Possibly carcinogenic to humans. 2B Possibly carcinogenic to humans. 2B Possibly carcinogenic to humans. 3 t classifiable as to carcinogenicity to humans. 3 t classifiable as to carcinogenicity to humans. 1 Carcinogenic to humans. 3 t classifiable as to carcinogenicity to humans. 9 / 17

10 2B Possibly carcinogenic to humans. US. National Toxicology Program (NTP) Report on Carcinogens Reasonably Anticipated to be a Human Carcinogen. Known To Be Human Carcinogen. Reasonably Anticipated to be a Human Carcinogen. US. OSHA Specifically Regulated Substances (29 CFR ) Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects 12. Ecological information Ecotoxicity Suspected of damaging fertility. t classified. Cancer Cancer Cancer May cause damage to organs through prolonged or repeated exposure. 1,2,4,5-Tetrachlorobenzene (CAS ) Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects. May cause damage to organs through prolonged or repeated exposure. Harmful to aquatic life with long lasting effects. Accumulation in aquatic organisms is expected. 1-Chloronaphthalene (CAS ) 2,3,4,6-Tetrachlorophenol (CAS ) Crustacea EC50 Crustacea EC50 Species Crustacea EC50 Crustacea EC50 Crustacea EC50 4-Chlorophenyl phenyl ether (CAS ) Fathead minnow (Pimephales promelas) Sheepshead minnow (Cyprinodon variegatus) Bluegill (Lepomis macrochirus) Bluegill (Lepomis macrochirus) Bluegill (Lepomis macrochirus) Asiatic knifefish (topterus notopterus) Zebra danio (Danio rerio) Fathead minnow (Pimephales promelas) Brook trout (Salvelinus fontinalis) Test Results 0.32 mg/l, 96 hours 0.69 mg/l, 96 hours mg/l, 96 hours mg/l, 48 hours mg/l, 96 hours mg/l, 48 hours mg/l, 96 hours mg/l, 48 hours 0.9 mg/l, 96 hours mg/l, 48 hours mg/l, 96 hours 21.7 mg/l, 48 hours mg/l, 96 hours mg/l, 96 hours 10 / 17

11 Acenaphthene (CAS ) Dibenzofuran (CAS ) Diethyl phthalate (CAS ) Fluorene (CAS ) m-nitroaniline (CAS ) o-nitroaniline (CAS ) Species Zebra danio (Danio rerio) Fathead minnow (Pimephales promelas) Fathead minnow (Pimephales promelas) Rainbow trout,donaldson trout (Oncorhynchus mykiss) Sheepshead minnow (Cyprinodon variegatus) Water flea (Daphnia pulex) Rainbow trout,donaldson trout (Oncorhynchus mykiss) Fathead minnow (Pimephales promelas) Guppy (Poecilia reticulata) Bluegill (Lepomis macrochirus) Fathead minnow (Pimephales promelas) Test Results mg/l, 48 hours mg/l, 96 hours mg/l, 48 hours mg/l, 96 hours mg/l, 96 hours 86 mg/l, 48 hours 12 mg/l, 96 hours 45.9 mg/l, 48 hours 29 mg/l, 96 hours mg/l, 48 hours mg/l, 96 hours 1250 mg/l, 48 hours mg/l, 96 hours mg/l, 48 hours mg/l, 96 hours mg/l, 48 hours mg/l, 96 hours 17 mg/l, 48 hours mg/l, 96 hours * Estimates for product may be based on additional component data not shown. Persistence and degradability Bioaccumulative potential data is available on the degradability of this product. data available. Partition coefficient n-octanol / water (log Kow) 1,2,4,5-Tetrachlorobenzene Chloronaphthalene 4 2,3,4,6-Tetrachlorophenol ,4,5-Trichlorophenol ,4,6-Trichlorophenol ,4-Dinitrophenol (min 15wt% water) / 17

12 Partition coefficient n-octanol / water (log Kow) 2,4-Dinitrotoluene ,6-Dinitrotoluene Chloronaphthalene Chlorophenyl phenyl ether Nitrophenol 1.91 Acenaphthene 3.92 Acenaphthylene 4.07 a-naphthylamine 2.25 Dibenzofuran 4.12 Diethyl phthalate 2.47 Dimethyl phthalate 1.6 Methylene chloride 1.25 m-nitroaniline 1.37 Pentachlorobenzene 5.18 p-nitroaniline 1.39 Mobility in soil adverse effects 13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code data available. US RCRA Hazardous Waste P List: Reference US RCRA Hazardous Waste U List: Reference 1,2,4,5-Tetrachlorobenzene (CAS ) 2-Chloronaphthalene (CAS ) Diethyl phthalate (CAS ) Waste from residues / unused products Contaminated packaging other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material and its container must be disposed of as hazardous waste. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. P048 P077 U207 U105 U106 U047 U170 U167 U168 U088 U102 U080 U183 Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group Special precautions for user Special provisions Packaging exceptions Packaging non bulk Packaging bulk UN1593 Dichloromethane, solution 6.1(PGIII) III Read safety instructions, SDS and emergency procedures before handling. IB3, IP8, N36, T7, TP / 17

13 IATA UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Packing group Environmental hazards ERG Code Special precautions for user information Passenger and cargo aircraft Cargo aircraft only IMDG UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Packing group Environmental hazards Marine pollutant EmS Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code DOT UN1593 Dichloromethane solution 6.1(PGIII) - III. 6L Read safety instructions, SDS and emergency procedures before handling. Allowed. Allowed. UN1593 DICHLOROMETHANE SOLUTION 6.1(PGIII) - III. F-A, S-A Read safety instructions, SDS and emergency procedures before handling. IATA; IMDG 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR One or more components are not listed on TSCA. TSCA Section 12(b) Export tification (40 CFR 707, Subpt. D) 1,2,4,5-Tetrachlorobenzene (CAS ) CERCLA Hazardous Substance List (40 CFR 302.4) 1,2,4,5-Tetrachlorobenzene (CAS ) 1-Chloronaphthalene (CAS ) 2,3,4,6-Tetrachlorophenol (CAS ) 1.0 % One-Time Export tification only. 0.1 % One-Time Export tification only. 1.0 % One-Time Export tification only. 1.0 % One-Time Export tification only. 13 / 17

14 2-Chloronaphthalene (CAS ) 4-Chlorophenyl phenyl ether (CAS ) Acenaphthene (CAS ) Acenaphthylene (CAS ) Dibenzofuran (CAS ) Diethyl phthalate (CAS ) Fluorene (CAS ) SARA 304 Emergency release notification t regulated. US. OSHA Specifically Regulated Substances (29 CFR ) Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Pressure Hazard - Reactivity Hazard - SARA 302 Extremely hazardous substance t listed. SARA 311/312 Hazardous chemical Cancer Cancer Cancer Skin irritation toxicity Heart toxicity Central nervous system Liver Skin irritation Eye irritation SARA 313 (TRI reporting) Chemical name CAS number % by wt. Methylene chloride ,3,4,6-Tetrachlorophenol ,4,6-Trichlorophenol ,4-Dinitrotoluene ,6-Dinitrotoluene a-naphthylamine b-naphthylamine federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Acenaphthene (CAS ) Acenaphthylene (CAS ) Dibenzofuran (CAS ) Fluorene (CAS ) 14 / 17

15 Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) t regulated. Safe Drinking Water Act (SDWA) US state regulations t regulated. US. Massachusetts RTK - Substance List 1,2,4,5-Tetrachlorobenzene (CAS ) 2,3,4,6-Tetrachlorophenol (CAS ) 2-Chloronaphthalene (CAS ) 4-Chlorophenyl phenyl ether (CAS ) Acenaphthene (CAS ) Acenaphthylene (CAS ) Dibenzofuran (CAS ) Diethyl phthalate (CAS ) Fluorene (CAS ) US. New Jersey Worker and Community Right-to-Know Act 2,3,4,6-Tetrachlorophenol (CAS ) 2-Chloronaphthalene (CAS ) Dibenzofuran (CAS ) Diethyl phthalate (CAS ) US. Pennsylvania RTK - Hazardous Substances 1,2,4,5-Tetrachlorobenzene (CAS ) 1-Chloronaphthalene (CAS ) 2,3,4,6-Tetrachlorophenol (CAS ) 2-Chloronaphthalene (CAS ) 4-Chlorophenyl phenyl ether (CAS ) Acenaphthene (CAS ) Acenaphthylene (CAS ) Dibenzofuran (CAS ) Diethyl phthalate (CAS ) Fluorene (CAS ) 15 / 17

16 US. Rhode Island RTK 1,2,4,5-Tetrachlorobenzene (CAS ) 1-Chloronaphthalene (CAS ) 2,3,4,6-Tetrachlorophenol (CAS ) 2-Chloronaphthalene (CAS ) 4-Chlorophenyl phenyl ether (CAS ) Acenaphthene (CAS ) Acenaphthylene (CAS ) Dibenzofuran (CAS ) Diethyl phthalate (CAS ) Fluorene (CAS ) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/carcinogenic substance Listed: January 1, 1988 Listed: July 1, 1988 Listed: July 1, 1995 Listed: October 1, 1989 Listed: February 27, 1987 Listed: April 1, 1988 US - California Proposition 65 - CRT: Listed date/female reproductive toxin Listed: August 20, 1999 Listed: August 20, 1999 US - California Proposition 65 - CRT: Listed date/male reproductive toxin Listed: August 20, 1999 Listed: August 20, 1999 International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Japan Korea New Zealand Philippines Domestic Substances List (DSL) n-domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. information, including date of preparation or last revision Issue date Version # 01 NFPA ratings Health: 2 Flammability: 1 Instability: 0 Yes Yes 16 / 17

17 Disclaimer The above information is believed to be correct on the date it was last revised and must not be considered all inclusive. The information has been obtained only by a search of available literature and is only a guide for handling the chemicals. OSHA regulations require that if other hazards become evident, an upgraded SDS must be made available to the employee within three months. RESPONSIBILITY for updates lies with the employer and not with CHEM SERVICE, Inc. Persons not specifically and properly trained should not handle this chemical or its container. This product is furnished FOR LABORATORY USE ONLY! Our products may NOT BE USED as drugs, cosmetics, agricultural or pesticide products, food additives or as household chemicals. This Safety Data Sheet (SDS) is intended only for use with Chem Service, Inc. products and should not be relied on for use with materials from any other supplier even if the chemical name(s) on the product are identical! Whenever using an SDS for a solution or mixture the user should refer to the SDS for every component of the solution or mixture. Chem Service warrants that this SDS is based upon the most current information available to Chem Service at the time it was last revised. THIS WARRANTY IS EXCLUSIVE, AND CHEM SERVICE, INC. MAKES NO OTHER WARRANTY, EXPRESSED OR IMPLIED, INCLUDING ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR ANY PARTICULAR PURPOSE. This SDS is provided gratis and CHEM SERVICE, INC. SHALL NOT BE LIABLE FOR ANY INCIDENTAL, CONSEQUENTIAL OR CONTINGENT DAMAGES. Copyright Chem Service, Inc. All rights reserved except that this SDS may be printed for the use of a customer or prospective customer of Chem Service, Inc provided the entire SDS is printed. The SDS may not be placed in any database or otherwise stored or distributed in electronic or any other form. This product is furnished FOR LABORATORY USE ONLY. 17 / 17