BONDERM 10 OLIVE (CETEARYL GLUCOSIDE, SORBITAN OLIVATE)

Transcription

1 BONDERM 10 OLIVE (CETEARYL GLUCOSIDE, SORBITAN OLIVATE)

2 BONDERM 10 OLIVE This product, based on olive oil, is able to form particularly fresh and light O/W emulsions that are pleasantly velvety to the touch and enriched with the eudermic functional properties of precious Italian olive oil. The INCI name of BONDERM 10 OLIVE is Cetearyl Glucoside (and) Sorbitan Olivate. BONDERM 10 OLIVE creates liquid crystal lamellar structures regardless of the chemical structure and polarity of the substances present in the internal phase of the emulsion. The great versatility of this product is of considerable interest. It is able to create systems that are organized in liquid crystal lamellar phases without the help of other co-emulsifiers, regardless of the composition of the internal phase. When present at the oil/water interface, the liquid crystals help give the system rigidity and, by limiting the fluctuation of the components at the interface, give the emulsion great stability. Furthermore, the liquid crystal system enhances the moisturizing ability of the emulsion. In this special network, the quantity of inter-lamellar water can be extremely high and become immediately available when the cream is applied to the skin. For these reasons, these emulsions have a shinny surface, a fresh and original feel and they leave a light and pleasant sensation on the skin. Very small quantities of BONDERM 10 OLIVE are sufficient to emulsify oils and other lipophile ingredients. It is possible to obtain stable emulsions that are easily water able and that offer moisturizing and emollient properties and a pleasant light and silky sensation even when they contain large quantities of oily substances. BONDERM 10 OLIVE responds to the current market trends by offering a natural, pure, non-animal-tested product with outstanding properties, whilst retaining its skin-feel benefits of smoothness and lightness with excellent spreadability. The product functions are self-emulsifying, self-bodying oil-in-water emulsifier offering distinct technical advantages: A wide range of cosmetics oils, including mineral, vegetable and silicone oils, can be used without affecting the stability of the emulsion. Creams and milks can be produced by simply adjusting the emulsifier concentration. The product is composed by very mild surfactants. Human patch tests have shown that the blend does not cause skin or eye irritation and no sensitising potential of the components has been demonstrated. Emulsions created with BONDERM 10 OLIVE have notable stability at high or low temperatures and good resistance to water thanks to the formation of a hydrophobic film on the surface. Product in procedure Mix the BONDERM 10 OLIVE in the heated water phase at 70 C under moderate stirring until a homogeneous dispersion is formed. Disperse the hydrocolloid in the heated aqueous phase at 75 C with moderate stirring. Add the heated oil phase to the aqueous phase under intensive stirring. Homogenise the mixture intensively t 60 C. Cool to 35 C whilst stirring moderately. Add heat-sensitive ingredients whilst stirring moderately and homogenise the mixture. Emulsions with ph values below 5 have a tendency to become unstable. This can be overcome by the use of suitable buffer systems. The stabilisation mechanism of formulations derived from BONDERM 10 OLIVE is based on the formation of distinct liquid crystalline structures in the water phase into which the oil phases is dispersed.

3 PRODUCT CHARACTERISTICS BONDERM 10 OLIVE is free of chemical impurities, solvents, ethylene oxide and dioxane. The emulsification energy input should be checked so as not to destroy the liquid crystalline phase. It is a flexible single oil-in-water emulsifier that permits the production of both creams and milks without needing an additional hydrophilic ethoxylated co-emulsifier. The percentage of use of BONDERM 10 OLIVE is 3-4% in milks or lotions and in creams 4-6% depending on the oil volume and characteristic. TOXICITY BONDERM 10 OLIVE has not been tested on animals. It has been tested in vitro (dermal and ocular) and on human skin (for primary potential irritation.). Results show that the use of this ingredient in cosmetic formulations is absolutely safe. This product can more easily be defined as a Peg free functionalized emulsifying system capable of forming particularly fresh and light O/W emulsions that are pleasantly velvety to the touch and enriched with the eudermic functional properties of precious Italian olive oil. BONDERM 10 OLIVE is able to form liquid crystal lamellar structures regardless of the chemical structure and polarity of the substances present in the internal phase of the emulsion. Under a microscope with polarised light their liquid crystal structure is quiet clear as the following photograph, taken at x 250, demonstrates. The great versatility of this product is of considerable interest. It is able to create systems that are organised in liquid crystal lamellar phases without the help of other coemulsifiers, regardless of the composition of the internal phase. When present at the oil/water interface, the liquid crystals help give the system rigidity and, by limiting the fluctuation of the components at the interface, give the emulsion great stability. Furthermore, the liquid crystal system enhances the moisturising ability of the emulsion. In this special network, the quantity of inter-lamellar water can be extremely high and become immediately available when the cream is applied to the skin. For these reasons these emulsions have a shinny surface, a fresh and original feel and they leave a light and pleasant sensation on the skin. Emulsions created with BONDERM 10 OLIVE have the following properties: Notable stability at high and low temperatures. Good resistance to water thanks to the formation of a hydrophobic film on the surface. Quality sensorial characteristics: long lasting emollient/ moisturising effect. Particularly shiny appearance, easy and pleasant to apply.

4 LIQUID CRYSTALS Phase Ingredient % A Water 68,05 A Glycerin 6,00 A Butylen Glycol 4,00 A Methylparaben 0,30 A BONDERM 10 OLIVE 5,00 B Caprylic/Capric Triglycerides 15,00 B Propylparaben 0,30 C Water 1,00 C Imidizolydinil Urea 0,35 BONDERM 10 OLIVE water phase at 75 C BONDERM 10 OLIVE Emulsion 2 hours after manufacturing. BONDERM 10 OLIVE Emulsion 24 hours after manufacturing.

5 BONDERM 10 OLIVE SPECIFICATIONS

6 Specifications BONDERM 10 OLIVE Trade name: Use: Chemical Nature: PRODUCT IDENTIFICATION BONDERM 10 OLIVE PEG-free emulsifying system derived from olive oil for cosmetic O/W creams and lotions. Blend of cetearyl polyglucose and monoester of sorbitol with fatty acids from olive. IUPAC Denomination: D-glucopyranose, C16-18 alkyl glucosides + D-glucitol, 1,4-anidrous-, 6- monoester with fatty acids from olive. INCI Name: CETEARYL GLUCOSIDE, SORBITAN OLIVATE CAS N : Origin: Vegetal/Natural DESCRIPTION REF. MIN. MAX. Appearance Odour Colour Waxy solid, Flakes Slight characteristic Ivory to slightly yellow Melting point C Water % (K.F.) % 1.0 HLB 9.5 Acid Value mg.koh/gr 5 N Saponification mg.koh/gr ph (5% sol.) 5 7 Notes/Observations: The product, if correctly stored, in the original packaging, properly closed, maintains its characteristics for 36 months. BONDERM 10 OLIVE does not contain preservatives. BONDERM 10 OLIVE is biodegradable over 90% (OECD) : Main parameters checked on production of each batch. The values are shown on the certificate of analysis. This product must be preserved, handled and used following hygienic and safety rules of good industrial use and in compliance with effective law disposal. All information and data given herein are based on our present knowledge and experience but are presented without warranty or responsibility of any kind. Revision: 03 Date: 14/02/2006

7 BONDERM 10 OLIVE FORMULATIONS

8 Formulations BONDERM 10 OLIVE BONDERM 10 OLIVE shows remarkable emulsifying properties with a wide range of fatty phase. Oils that are difficult to emulsify, such as vegetable oils and silicon oils do not pose any problems; quite the contrary, it is possible to formulate stable creams and lotions with a 100% vegetable origin and pleasant feel. The following formulations are here indicated in order to give general directions for the employment of BONDERM 10 OLIVE. Although they have been realised according to best information we owe, this does not exonerate the user from verifying their validity.

9 OIL-IN-WATER SUN PROTECTION CREAM Description % Paraffinum Liquidum Caprylyc/Capric Triglyceride 5.00 C12-15 Alkyl Benzoate 4.00 Ethylhexyl Metoxycinnamate 5.00 Butyl Methoxydibenzoylmethane 1.00 Tocopheryl Acetate 1.00 Benzyl Alcohol 2.00 Dimethicone 1.00 BONDERM 10 OLIVE 5.00 Aqua at 100 Glycerin 4.00 NMF 1.00 Parfum q.s. Preservatives q.s. NATURAL CREAM Description % Helianthus Annuus Seed Oil Vitis Vinifera Seed Oil 7.00 Prunus Amygdalus Dulcis Oil 4.00 Hydrogenated Olive Oil 3.00 Orbignya Oleifera Seed Oil 1.50 BONDERM 10 OLIVE 5.50 Aqua at 100 Glycerin 3.00 Parfum q.s. Preservatives q.s.

10 BABY CREAM Description % Caprylic/Capric Triglyceride 6.00 Triticum Vulgare OIl 3.00 Bisabolol 1.00 Glyceryl Stearate 1.20 Cetyl Palmitate 1.00 Butyrospermum Parkii 1.00 BONDERM 10 OLIVE 5.00 Aqua at 100 Glycerin 2.00 Zinc Oxide 7.00 Parfum q.s. Preservatives q.s. MOISTURIZING CREAM Description % C10-18 Triglycerides 3.00 Ethylhexyl Palmitate 2.00 Simmondsia Chinensis Seed Oil 2.00 Hydrogenated Lanolin 1.50 Cetearyl Alcohol 1.30 Glyceryl Stearate 1.20 Dimethicone 0.70 BONDERM 10 OLIVE 4.50 Aqua at 100 Ethylhexylglycerin 1.00 NMF 2.50 Parfum q.s. Preservatives q.s.

11 BONDERM 10 OLIVE MATERIAL SAFETY DATA SHEET

12 Material Safety Data Sheet Safety material sheet in compliance with Directive 91/155/CE and updates. Revision date: 18/12/ Version N PRODUCT AND COMPANY IDENTIFICATION Product name BONDERM 10 OLIVE Use Raw material for cosmetics Producer / Distributor BONDERALIA Tel: Fax: info@bonderaliaitalia.191.it Emergency calls COMPOSITION / INFORMATION ON INGREDIENTS Subject to directive 67/548/EEC of 27 th June 1967 and any amendments. Chemical Nature of the product Molecular weight Mixture of esters and anionic surfactants CAS Number EINECS Number INCI Name (USA) INCI Name (EEC) Italian law n / CETEARYL GLUCOSIDE, SORBITAN OLIVATE No limits on use Components CAS N Weight % Hazard Symbol Hazard sentence (R) / / / / / 3.HAZARD IDENTIFICATION This mixture has not been evaluated as a whole. Information provided on the health effects of this product is based on individual components. All ingredients are bound and potential for hazardous exposure as shipped is minimal. However, some vapours may be released upon heating and the end-user (fabricator) must take the necessary precautions (mechanical ventilation, respiratory protection, etc) to protect employees from exposure. Routes of exposure Health risks Environment risks Other risks Inhalation, Ingestion, Skin/Eye contact. Experience shows no acute irritancy or toxic effects. Belonging to directive 67/548/EEC and any amendments the product is not classified in hazard categories. Handle the product with good working practice avoiding dispersion into the environment. Belonging to directive 67/548/EEC and any amendments the product is not classified in hazard categories. Handle the product with good working practice avoiding dispersion into the environment. None known.

13 4. FIRST AID MEASURES Inhalation Contact with eyes Contact with skin Ingestion Notes for medical advice: Move to fresh air in case of accidental inhalation of fumes from overheating or combustion. When symptoms persist or in all cases of doubt seek medical advice. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If eye irritation persists or in all cases of doubt seek medical advice. Wash off with soap and plenty of water. If skin irritation persists or in all cases of doubt seek medical advice. The product as a low level of oral toxicity. Do not induce vomiting without medical advice. In case of gastric washing adopt a silicone anti-foam (Dimethicone) 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Special fire-fighting procedures Unusual fire/explosion hazards Carbon dioxide (CO2), Carbon monoxide (CO), water spray, dry powder. None known. Full-face self-contained breathing apparatus (SCBA) used in positive pressure mode should be worn to prevent inhalation of vapour/fumes. May emit irritant/toxic vapour/fumes under fire conditions. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Methods for cleaning up Wear appropriate personal protection during cleanup, such as gloves, boots and safety glasses with side shields. Should not be released into the environment. The product should not be allowed to enter drains, water courses or the soil. Clean up promptly by sweeping or vacuum. Package all material in plastic, cardboard or metal containers for disposal. Refer to section 13 of this MSDS for proper disposal methods. 7. HANDLING AND STORAGE Handling Storage Type of container Take measures to prevent the build up of electrostatic charge. Heat only in areas with appropriate exhaust ventilation. Avoid contact with the product. Handle in accordance with good industrial and hygiene practice. Keep containers dry and tightly closed to avoid moisture absorption and contamination. Keep in a dry, cool place. Compatible with: Steel, inox, Kraft, HDPE/LDPE. Avoid temperatures > 70 C

14 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Respiratory protection Hand protection Eye/face protection Skin and body protection Exposure limit(s) General hygiene considerations Engineering measures Facial mask Protective PVC gloves Safety glasses with side-shields Long sleeved clothing and safety shoes TLV not established Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Heat only in areas with appropriate exhaust ventilation. Provide appropriate exhaust ventilation at machinery. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Solid Appearance Flakes Colour From white to yellowish Odour Characteristic Melting point/range > 200 C Boiling point > 250 C Water solubility Dispersible Evaporation rate Specific gravity Bulk density Vapour pressure Vapour density ph 1% in water STABILITY AND REACTIVITY Stability Hazardous Polymerization Conditions to avoid Incompatible materials Hazardous decomposition products None in particular None in particular May emit irritant/toxic vapour/fumes under fire conditions. 11. TOXICOLOGICAL INFORMATION The information has been deduced from bibliographic literature and scientific lectures. Acute toxicity (LD50 rat) Eye irritation (rabbit) Skin irritation (rabbit 4 hours) Sensitisation Inhalation > 2000 mg/kg Not irritant Not irritant Not sensitizing Inhalation is possible only under aerosol conditions, and vapour/fumes might be irritant/toxic.

15 12. ECOLOGICAL INFORMATION Derived from literature of products of analogous composition. Persistence & Biodegradability COD TOXIC EFFECTS Acute toxicity on Daphnia Fish toxicity AOX Bioaccumulation potential Heavy metals Additional advice Readily biodegradable. The product can be considered easily biodegradable accordingly to EEC Directives. The product has a biodegradability accordingly to OECD methods such as to be employed into detergent products as conformed by EEC Directive N 648/2004. EC50 (48h) 1 10 mg/l CL50 (96h) 1 10 mg/l Carassius Auratus The product does not contain organohalogenic compounds The product does not contain heavy metals in concentrations that could be relevant for disposal waters. The product is a surfactant agent, do not disperse into the environment. 13. DISPOSAL CONSIDERATIONS Product Contaminated packaging Where possible recycling is preferred to disposal or incineration. The generator of waste material has the responsibility for proper waste classification, transportation and disposal in accordance with applicable federal, state/provincial and local regulations. Recycling is preferred when possible. The generator of waste material has the responsibility for proper waste classification, transportation and disposal in accordance with applicable federal, state/provincial and local regulations. 14.TRANSPORT INFORMATION ROAD - RAIL Road/Rail (ADR/RID) Classification of the product N Hazard SEA IMDG Class AIR ICAO/IATA Class Not hazardous. Not regulated for transportation. Not hazardous. Not hazardous. 15. REGULATORY INFORMATION ( Directive EEC 67/548 and amendments) D. Lgs n 65 del 14/03/03 Classification / Symbol Hazard sentence Safety sentence Not classified Not required. BONDERM 10 OLIVE is a non hazardous substance and thus does not requires special labelling.

16 16. OTHER INFORMATION BIBLIOGRAPHY: CESIO Classification and Labelling of Anionic, Nonionic Surfactants (2000) CESIO Classification and Labelling of Surfactants as Dangerous for the Environment (2003) NIOSH Registry of TOxic Effects of Chemical Substances (1983) N. Irving Sax, R.J. Lewis Sr. Dangerous Properties of Industrial Materials Ed. Van Nonstrand, Reinhold 1989, 7 th edition. ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents 1995/1996 EINECS European Inventory of Existing Commercial Chemical Substances. CID Contributo alla compilazione delle schede di sicurezza dei tensioattivi. SAX Dangerous properties of industrial materials. SINTALEX Versione 7.0. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for the safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material when used in combination with any other materials and/or in any particular process or processing conditions. This Data Sheet replaces and substitutes any previous edition.