Safety Data Sheet COFC EnBio Waylube Identification

Transcription

1 1. Identification 1.1. Product identifier Product Identity Alternate Names 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet Intended use Application Method See Technical Data Sheet. See Technical Data Sheet. Company Name Central Ohio Farmers CO-OP 730 Bellefontaine Ave. Marion, OH Emergency 24 hour Emergency Telephone No Customer Service: Hazard(s) identification 2.1. Classification of the substance or mixture Skin Irrit. 2;H315 Causes skin irritation Label elements Using the Toxicity Data listed in section 11 and 12 the product is labeled as follows. H315 Causes skin irritation. [Prevention]: P260 Do not breathe mist / vapors / spray. P262 Do not get in eyes, on skin, or on clothing. P264 Wash thoroughly after handling. Warning P280 Wear protective gloves / eye protection / face protection. [Response]: P IF SWALLOWED: Immediately call a POISON CENTER or doctor / physician. Page 1 of 9

2 P IF ON SKIN: Wash with plenty of soap and water. P321 Specific treatment (see information on this label). P331 Do NOT induce vomiting. P If skin irritation occurs: Get medical advice / attention. P362 Take off contaminated clothing and wash before reuse. [Storage]: No GHS storage statements [Disposal]: No GHS disposal statements 3. Composition/information on ingredients This product contains the following substances that present a hazard within the meaning of the relevant State and Federal Hazardous Substances regulations. Ingredient/Chemical Designations Weight % GHS Classification Notes Distillates (petroleum), hydrotreated middle Gasoil - unspecified CAS Number: Asp. Tox. 1;H304 Skin Irrit. 2;H315 [1] Soybean oil, Me ester CAS Number: Canola Oil CAS Number: Not Classified [1] Not Classified [1] In accordance with paragraph (i) of , the specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. [1] Substance classified with a health or environmental hazard. [2] Substance with a workplace exposure limit. [3] PBT-substance or vpvb-substance. *The full texts of the phrases are shown in Section First aid measures 4.1. Description of first aid measures General Inhalation Eyes Skin Ingestion In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, give artificial respiration. If unconscious place in the recovery position and obtain immediate medical attention. Give nothing by mouth. Irrigate copiously with clean water for at least 15 minutes, holding the eyelids apart and seek medical attention. Remove contaminated clothing. Wash skin thoroughly with soap and water or use a recognized skin cleanser. If swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. Page 2 of 9

3 4.2. Most important symptoms and effects, both acute and delayed Overview Skin Exposure to solvent vapor concentrations from the component solvents in excess of the stated occupational exposure limits may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible damage. See section 2 for further details. Causes skin irritation. 5. Fire-fighting measures 5.1. Extinguishing media Use carbon dioxide, foamite, sand or sodium bicarbonate Special hazards arising from the substance or mixture Oil soaked rags can cause spontaneous combustion if not handled properly. Wash rags with soap and water before disposal. Hazardous decomposition: Thermal- carbon monoxide and/or carbon dioxide after content have evaporated and residue is exposed to excessive heat Advice for fire-fighters Avoid breathing vapors or dusts. Use self contained breathing apparatus with full face piece and protective clothing. None ERG Guide No Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Put on appropriate personal protective equipment (see section 8). Oil soaked rags can cause spontaneous combustion if not handled properly. Wash rags with soap and water before disposal Environmental precautions Do not allow spills to enter drains or waterways. Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse. Page 3 of 9

4 6.3. Methods and material for containment and cleaning up Oil soaked rags can cause spontaneous combustion if not handled properly. Wash rags with soap and water before disposal. Contain spill and transfer to a suitable container. 7. Handling and storage 7.1. Precautions for safe handling None noted 7.2. Conditions for safe storage, including any incompatibilities Store in closed containers between 50F and 120F Incompatible materials: Avoid contact with strong oxidizing agents. Observe all federal, state and local regulations when storing or disposing of this substance Specific end use(s) Control parameters Exposure 8. Exposure controls and personal protection CAS No. Ingredient Source Value Distillates (petroleum), hydrotreated middle Gasoil - unspecified OSHA ACGIH NIOSH Supplier Soybean oil, Me ester OSHA ACGIH NIOSH Supplier Canola Oil OSHA ACGIH NIOSH Supplier Contains mineral oil. The exposure limits for oil mist are 5 mg/m3 OSHA PEL and 10 mg/m3 ACGIH. Carcinogen Data CAS No. Ingredient Source Value Distillates (petroleum), hydrotreated middle Gasoil - unspecified OSHA NTP IARC Select Carcinogen: No Known: No; Suspected: No Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; Page 4 of 9

5 Soybean oil, Me ester OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; Canola Oil OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 8.2. Exposure controls Respiratory Eyes Skin Engineering Controls If workers are exposed to concentrations above the exposure limit they must use the appropriate, certified respirators. Wear safety goggles to prevent eye contact with substance. Impervious apron if needed to avoid prolonged or repeated skin contact. Wear appropriate protective gloves to prevent direct contact. Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and any vapor below occupational exposure limits suitable respiratory protection must be worn. Other Work Practices See section 2 for further details. - [Prevention]: Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse. 9. Physical and chemical properties Appearance Odor Odor threshold ph Melting point / freezing point Initial boiling point and boiling range Flash Point Evaporation rate (Ether = 1) Flammability (solid, gas) Upper/lower flammability or explosive limits Vapor pressure (Pa) Vapor Density Amber Liquid Bland Not determined 320F min. Not Applicable Lower Explosive Limit: Upper Explosive Limit: Specific Gravity >1 Solubility in Water Insoluble Partition coefficient n-octanol/water (Log Kow) Page 5 of 9

6 Auto-ignition temperature Decomposition temperature Viscosity (cst) 9.2. Other information No other relevant information. 40C 10. Stability and reactivity Reactivity Hazardous Polymerization will not occur Chemical stability Stable under normal circumstances Possibility of hazardous reactions Conditions to avoid Keep away from oxidizing agents, excessive heat, and ignition sources Incompatible materials Avoid contact with strong oxidizing agents Hazardous decomposition products Thermal- carbon monoxide and/or carbon dioxide after content have evaporated and residue is exposed to excessive heat. 11. Toxicological information Acute toxicity Exposure to solvent vapor concentrations from the component solvents in excess of the stated occupational exposure limits may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible damage. Ingredient Oral LD50, mg/kg Skin LD50, mg/kg Inhalation Vapor LC50, mg/l/4hr Inhalation Dust/Mist LC50, mg/l/4hr Inhalation Gas LC50, ppm Distillates (petroleum), hydrotreated middle Gasoil - unspecified - ( ) > 5,000.00, Rat - Category: NA Soybean oil, Me ester - ( ) Page 6 of 9

7 Canola Oil - ( ) Note: When no route specific LD50 data is for an acute toxin, the converted acute toxicity point estimate was used in the calculation of the product's ATE (Acute Toxicity Estimate). Classification Category Hazard Description Acute toxicity (oral) --- Not Applicable Acute toxicity (dermal) --- Not Applicable Acute toxicity (inhalation) --- Not Applicable Skin corrosion/irritation 2 Causes skin irritation. Serious eye damage/irritation --- Not Applicable Respiratory sensitization --- Not Applicable Skin sensitization --- Not Applicable Germ cell mutagenicity --- Not Applicable Carcinogenicity --- Not Applicable Reproductive toxicity --- Not Applicable STOT-single exposure --- Not Applicable STOT-repeated exposure --- Not Applicable Aspiration hazard --- Not Applicable 12. Ecological information Toxicity The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and GHS and is not classified as dangerous for the environment, but contains substance(s) dangerous for the environment. See section 3 for details Aquatic Ecotoxicity Ingredient Distillates (petroleum), hydrotreated middle Gasoil - unspecified - ( ) 96 hr LC50 fish, mg/l 48 hr EC50 crustacea, mg/l ErC50 algae, mg/l 54.00, Jordanella floridae 68.00, Daphnia magna Not Available Soybean oil, Me ester - ( ) Not Available Not Available Not Available Canola Oil - ( ) Not Available Not Available Not Available Persistence and degradability There is no data on the preparation itself Bioaccumulative potential Page 7 of 9

8 12.4. Mobility in soil Results of PBT and vpvb assessment This product contains no PBT/vPvB chemicals Other adverse effects. 13. Disposal considerations Waste treatment methods Observe all federal, state and local regulations when disposing of this substance. 14. Transport information DOT (Domestic Surface Transportation) IMO / IMDG (Ocean Transportation) ICAO/IATA UN number Not Applicable Not Regulated Not Regulated UN proper shipping name Transport hazard class(es) Not Regulated Not Regulated Not Regulated DOT Hazard Class: Not Applicable IMDG: Not Applicable Sub Class: Not Applicable Air Class: Not Applicable Packing group Not Applicable Not Applicable Not Applicable Environmental hazards IMDG Marine Pollutant: No Special precautions for user No further information 15. Regulatory information Regulatory Overview Toxic Substance Control Act ( TSCA) WHMIS Classification US EPA Tier II Hazards The regulatory data in Section 15 is not intended to be all-inclusive, only selected regulations are represented. All components of this material are either listed or exempt from listing on the TSCA Inventory. D2B Fire: No Sudden Release of Pressure: No Reactive: No Immediate (Acute): Yes Delayed (Chronic): No Page 8 of 9

9 EPCRA 311/312 Chemicals and RQs: EPCRA 302 Extremely Hazardous: EPCRA 313 Toxic Chemicals: Proposition 65 - Carcinogens (>0.0%): Proposition 65 - Developmental Toxins (>0.0%): Proposition 65 - Female Repro Toxins (>0.0%): Proposition 65 - Male Repro Toxins (>0.0%): New Jersey RTK Substances (>1%) : Pennsylvania RTK Substances (>1%) : 16. Other information The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to our products. Customers/users of this product must comply with all applicable health and safety laws, regulations, and orders. The full text of the phrases appearing in section 3 is: H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. This is the first version in the GHS SDS format. Listings of changes from previous versions in other formats are not applicable. The information accumulated herein is believed to be accurate but not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable and suitable to their circumstances. End of Document Page 9 of 9