BONDERM 9 OLIVE (SORBITAN OLIVATE)

Transcription

1 BONDERM 9 OLIVE (SORBITAN OLIVATE)

2 BONDERM 9 OLIVE The formation of an W/O emulsion is bound to the action of the emulsifier that must possess the capacity of decreasing the interface tension of the two phases and protecting the dispersed droplets of watery phase from the trend to get together. In a W/O system, the surfactant will concentrate itself at the surface of separation of the not mixing liquids, orienting the hydro-soluble portion toward the water and the liposoluble portion toward the oil. So, it will cause the formation of an emulsion in which the watery phase will present itself as small droplets dispersed in the continual oily phase. BONDERM 9 OLIVE allows the realization of emulsions of appreciable cosmetic grade, shiny and creamy, light and easily absorbed and with a smooth feel and they allow the incorporation of any type of oil, even of high polarity. The gelling activity of the watery phase can be obtained with hydrosolvatables polymers or with an emulsifier that is able to form an organized reticular structure, and allows to substitute waxy substances not more in tuning with the modern conception of the W/O emulsions, wish is preferred to be fresh and light, not impacted, smooth and easy to spread. BONDERM 9 OLIVE, INCI name = SORBITAN OLIVATE, consents the employment of any type of lipids, apolar or polar, without particular final differences and it reveals such properties to can be used in those cosmetic preparations where are required: The formation of a structure stable at cold or in warm temperatures. A formulating versatility. Facility and quickness of production. BONDERM 9 OLIVE acts as W/O emulsifier, building up a liquid crystal network and has hydrating and filming properties that create very mild creams, suitable even for the most sensitive skins. In make up products, it helps the dispersion of any kind of powder, from Titanium dioxide to iron oxides, so it becomes a versatile material for make up and sun care formulations; it can also improve brilliance of colour cosmetics. In fact, it is a very effective dispersant for any kind of powder, from fillers as talc or kaolin, to coloured iron oxides and lakes. It also acts as a brilliance enhancer in lip gloss and colour cosmetics in general. BONDERM 9 OLIVE helps to: Make rich, nutritive W/O creams and lotions for sensitive skin. Disperse homogeneously physical filters in sun products, assuring the most effective skin protection from UV. Keep skin protected from sun even in water (water resistance). Improve brilliance in make up products. Reduce lip dryness caused by lipsticks Increasing the percentage of employment of BONDERM 9 OLIVE, the clamminess of the emulsions increase in consequence.

3 BONDERM 9 OLIVE capability of giving a structural network to lipids has been evaluated at high and low percentages. With different oil, it shows gelling properties, independently of the polarity of them. Behaviour of a blend of BONDERM 9 OLIVE 30% and lipid 70%. Gel type Emulsion type Mineral Oil Soft, easy to spread O/W Castor Oil Pasty, moderately easy to spread W/O Sesame Oil Pasty, moderately easy to spread W/O Almond Oil Pasty W/O Isopropyl Myristate Pasty, easy to spread W/O C12-15 Alkyl Benzoate Pasty, easy to spread W/O Octyldodecyl Lactate Fluid, easy to spread W/O Caprylic/capric Triglyceride Pasty, moderately easy to spread W/O Behaviour of a blend of BONDERM 9 OLIVE 10% and lipid 90%. Gel type Emulsion type Mineral Oil Soft, easy to spread O/W Castor Oil Soft /glossy, moderately easy to spread W/O Sesame Oil Soft, easy to spread W/O Almond Oil Soft/pasty, easy to spread W/O Isopropyl Myristate Pasty, easy to spread W/O C12-15 Alkyl Benzoate Fluid, moderately easy to spread W/O Octyldodecyl Laccate Fluid, moderately easy to spread W/O Caprylic/capric Triglyceride Pasty, moderately easy to spread W/O

4 BONDERM 9 OLIVE SPECIFICATIONS

5 Specifications BONDERM 10 OLIVE PRODUCT IDENTIFICATION Trade Name: Chemical Name: INCI Name: Use: Origin: Formula: BONDERM 9 OLIVE Fatty acids, olive, monoesters with sorbitan. SORBITAN OLIVATE W/O non ionic emulsifying system (PEG free) of natural origin and functional lipid for cosmetic applications. Vegetal/synthetic HO OH O CHCH 2 O OH O CR where RCO- represents the fatty acids derived form olive oil DESCRIPTION REF. MIN. MAX. Appearance at 25 C Waxy solid Colour Ivory Melting point C HLB 4 Acid Value mg.koh/gr N Saponification mg.koh/gr Notes/Observations: The product, if correctly stored, in the original packaging, properly closed, maintains its characteristics for 36 months. BONDERM 9 OLIVE does not contain preservatives. BONDERM 9 OLIVE is biodegradable over 90% (OECD) : Main parameters checked on production of each batch. The values are shown on the certificate of analysis. This product must be preserved, handled and used following hygienic and safety rules of good industrial use and in compliance with effective law disposal. All information and data given herein are based on our present knowledge and experience but are presented without warranty or responsibility of any kind. Revision: 03 Date: 14/02/2006

6 BONDERM 9 OLIVE FORMULATIONS

7 Formulations BONDERM 9 OLIVE To prepare finely dispersed W/O creams which will maintain their stability, powerful, high-shear emulsification equipment has to be used. The amount of emulsifier necessary to obtain W/O emulsions is always higher than for O/W emulsions. Usually 5 to 10% is needed for creams, depending on the amount of aqueous internal phase. About 0.5 to 0.8 w/w of hydrated magnesium sulphate is necessary to achieve a practical shelf life, improving the high temperature stability. Some 2 to 5 % of polyol is often used as providing a moisturizing effect and improving stability in the cold. SUN PROTECTION CREAM BONDERM 9 OLIVE 7.00 Shea Butter 2.00 Caprylic/Capric Triglyceride 4.00 Isotridecyl Stearate 7.00 Jojoba Oil 5.00 Bees Wax 3.00 Octyl Methoxycinnamate 4.50 Butyl Methoxydibenzoilmethan 2.00 Water up to 100 Glycerin 2.00 MgSO 4. 7H 2 O 0.70 Perfume Preservatives EMOLLIENT BABY CREAM BONDERM 9 OLIVE 6.00 Decyl Oleate 5.50 Hydrogenated Polydecene 8.00 Ethylhexyl Stearate 3.50 Caprylic/Capric Triglyceride 5.00 Almond Oil 5.50 Wheat Germ Oil Water up to 100 Glycerin 2.00 Zinc Oxide MgSO 4. 7H 2 O 0.50 Perfume Preservatives

8 WATER FREE BABY PASTE BONDERM 9 OLIVE 4.00 Castor Oil Zinc Oxide Perfume Preservatives NOURISHING NIGHT CREAM BONDERM 9 OLIVE 7.50 Caprylic/Capric Triglyceride 6.50 Triisostearin 3.00 Paraffinum Liquidum 4.00 Phytosqualane 2.00 Cera Alba 2.50 Hydrogenated Castor Oil 1.50 PROLIX XI 1.50 Bisabolol 1.00 Water up to 100 Glycerin 2.00 MgSO 4. 7H 2 O 0.70 Panthenol 1.00 Perfume Preservatives LIPSTICK BONDERM 9 OLIVE Candelilla Wax 7.50 Carnauba Wax 6.00 Ozokerite 4.50 Octyl Dodecanol Lanolin Oil 6.00 Octyldodecyl Lactate 5.00 Isostearyl Neopenthanoate 4.00 Castor Oil up to 100 Tocopheryl Acetate 1.00 Ca Al Borosilicate 2.50 C10-30 Chol Lan Esters 6.00 CI CI D&C Red 27 Lake 3.00 Titanium Dioxide 2.50

9 CREAMY FOUNDATION BONDERM 9 OLIVE 7.50 Octyldodecyl Lactate 5.00 Phytosqualane 3.00 C12-15 Alkyl Benzoate 7.00 Hydrogenated Polydecene 5.00 Olea Europaea Unsaponifiables 1.00 Water up to 100 Glycerin 3.50 CI CI Talc 2.00 Kaolin 2.00 MgSO4. 7H2O 0.50 Perfume Preservatives TALC IN CREAM BONDERM 9 OLIVE 7.50 Paraffinum Liquidum Octyldodecyl Lactate Talc Perfume Preservatives BODY MOISTURIZING FLUID EMULSION BONDERM 9 OLIVE 6.00 Avocado Oil 3.50 Shea Butter 9.00 Caprylic/Capric Triglyceride 1.50 Paraffinum Liquidum 2.00 Isopropyl Myristate 2.00 Bees Wax 0.50 Water up to 100 Sorbitol 70% 2.00 MgSO4. 7H2O 0.50 Perfume Preservatives

10 BONDERM 9 OLIVE MATERIAL SAFETY DATA SHEET

11 Material Safety Data Sheet Safety material sheet in compliance with Directive 91/155/CE and updates. Revision date: 18/12/ Version N PRODUCT AND COMPANY IDENTIFICATION Product name BONDERM 9 OLIVE Use Raw material for cosmetics Producer / Distributor BONDERALIA Tel: Fax: info@bonderaliaitalia.191.it Emergency calls COMPOSITION / INFORMATION ON INGREDIENTS Subject to directive 67/548/EEC of 27 th June 1967 and any amendments. Chemical Nature of the product Molecular weight Mixture of esters and anionic surfactants CAS Number EINECS Number INCI Name (USA) INCI Name (EEC) Italian law n / SORBITAN OLIVATE No limits on use Components CAS N Weight % Hazard Symbol Hazard sentence (R) / / / / / 3.HAZARD IDENTIFICATION This mixture has not been evaluated as a whole. Information provided on the health effects of this product is based on individual components. All ingredients are bound and potential for hazardous exposure as shipped is minimal. However, some vapours may be released upon heating and the end-user (fabricator) must take the necessary precautions (mechanical ventilation, respiratory protection, etc) to protect employees from exposure. Routes of exposure Health risks Environment risks Other risks Inhalation, Ingestion, Skin/Eye contact. Experience shows no acute irritancy or toxic effects. Belonging to directive 67/548/EEC and any amendments the product is not classified in hazard categories. Handle the product with good working practice avoiding dispersion into the environment. Belonging to directive 67/548/EEC and any amendments the product is not classified in hazard categories. Handle the product with good working practice avoiding dispersion into the environment. None known.

12 4. FIRST AID MEASURES Inhalation Contact with eyes Contact with skin Ingestion Notes for medical advice: Move to fresh air in case of accidental inhalation of fumes from overheating or combustion. When symptoms persist or in all cases of doubt seek medical advice. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If eye irritation persists or in all cases of doubt seek medical advice. Wash off with soap and plenty of water. If skin irritation persists or in all cases of doubt seek medical advice. The product as a low level of oral toxicity. Do not induce vomiting without medical advice. In case of gastric washing adopt a silicone anti-foam (Dimethicone) 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Special fire-fighting procedures Unusual fire/explosion hazards Carbon dioxide (CO2), Carbon monoxide (CO), water spray, dry powder. None known. Full-face self-contained breathing apparatus (SCBA) used in positive pressure mode should be worn to prevent inhalation of vapour/fumes. May emit irritant/toxic vapour/fumes under fire conditions. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Methods for cleaning up Wear appropriate personal protection during cleanup, such as gloves, boots and safety glasses with side shields. Should not be released into the environment. The product should not be allowed to enter drains, water courses or the soil. Clean up promptly by sweeping or vacuum. Package all material in plastic, cardboard or metal containers for disposal. Refer to section 13 of this MSDS for proper disposal methods. 7. HANDLING AND STORAGE Handling Storage Type of container Take measures to prevent the build up of electrostatic charge. Heat only in areas with appropriate exhaust ventilation. Avoid contact with the product. Handle in accordance with good industrial and hygiene practice. Keep containers dry and tightly closed to avoid moisture absorption and contamination. Keep in a dry, cool place. Compatible with: Steel, inox, Kraft, HDPE/LDPE. Avoid temperatures > 70 C

13 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Respiratory protection Hand protection Eye/face protection Skin and body protection Exposure limit(s) General hygiene considerations Engineering measures Facial mask Protective PVC gloves Safety glasses with side-shields Long sleeved clothing and safety shoes TLV not established Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Heat only in areas with appropriate exhaust ventilation. Provide appropriate exhaust ventilation at machinery. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Solid Appearance Flakes Colour From white to yellowish Odour Characteristic Melting point/range > 200 C Boiling point > 250 C Water solubility Dispersible Evaporation rate Specific gravity Bulk density Vapour pressure Vapour density ph 1% in water STABILITY AND REACTIVITY Stability Hazardous Polymerization Conditions to avoid Incompatible materials Hazardous decomposition products None in particular None in particular May emit irritant/toxic vapour/fumes under fire conditions. 11. TOXICOLOGICAL INFORMATION The information has been deduced from bibliographic literature and scientific lectures. Acute toxicity (LD50 rat) Eye irritation (rabbit) Skin irritation (rabbit 4 hours) Sensitisation Inhalation > 2000 mg/kg Not irritant Not irritant Not sensitizing Inhalation is possible only under aerosol conditions, and vapour/fumes might be irritant/toxic.

14 12. ECOLOGICAL INFORMATION Derived from products of analogous composition. Persistence & Biodegradability COD TOXIC EFFECTS Acute toxicity on Daphnia Fish toxicity AOX Bioaccumulation potential Heavy metals Additional advice Readily biodegradable. The product can be considered easily biodegradable accordingly to EEC Directives. The product has a biodegradability accordingly to OECD methods such as to be employed into detergent products as conformed by EEC Directive N 648/2004. EC50 (48h) 1 10 mg/l CL50 (96h) 1 10 mg/l Carassius Auratus The product does not contain organohalogenic compounds The product does not contain heavy metals in concentrations that could be relevant for disposal waters. The product is a surfactant agent, do not disperse into the environment. 13. DISPOSAL CONSIDERATIONS Product Contaminated packaging Where possible recycling is preferred to disposal or incineration. The generator of waste material has the responsibility for proper waste classification, transportation and disposal in accordance with applicable federal, state/provincial and local regulations. Recycling is preferred when possible. The generator of waste material has the responsibility for proper waste classification, transportation and disposal in accordance with applicable federal, state/provincial and local regulations. 14.TRANSPORT INFORMATION ROAD - RAIL Road/Rail (ADR/RID) Classification of the product N Hazard SEA IMDG Class AIR ICAO/IATA Class Not hazardous. Not regulated for transportation. Not hazardous. Not hazardous. 15. REGULATORY INFORMATION ( Directive EEC 67/548 and amendments) D. Lgs n 65 del 14/03/03 Classification / Symbol Hazard sentence Safety sentence Not classified Not required. BONDERM 9 OLIVE is a non hazardous substance and thus does not requires special labelling.

15 16. OTHER INFORMATION BIBLIOGRAPHY: CESIO Classification and Labelling of Anionic, Nonionic Surfactants (2000) CESIO Classification and Labelling of Surfactants as Dangerous for the Environment (2003) NIOSH Registry of TOxic Effects of Chemical Substances (1983) N. Irving Sax, R.J. Lewis Sr. Dangerous Properties of Industrial Materials Ed. Van Nonstrand, Reinhold 1989, 7 th edition. ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents 1995/1996 EINECS European Inventory of Existing Commercial Chemical Substances. CID Contributo alla compilazione delle schede di sicurezza dei tensioattivi. SAX Dangerous properties of industrial materials. SINTALEX Versione 7.0. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for the safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material when used in combination with any other materials and/or in any particular process or processing conditions. This Data Sheet replaces and substitutes any previous edition.