MATERIAL SAFETY DATA SHEET 1 Product and Company Identification Product Name Clearasil ULTRA Acne+Marks Spot Lotion UPC CODES Refer to Section 16 CAS # Product use Spac Distributed by LEGEND HMIS/NFPA Severe Serious 4 3 Moderate 2 Slight 1 Minimal 0 Mixture Topical Skin Preparation Reckitt Benckiser Morris Corporate Center IV 399 Interpace Parkway PO Box 225 Parsippany, NJ 07054-0225 In Case of Emergency: 1-800-228-4722 Transportation Emergencies: 24 Hour Number: North America: CHEMTREC: 1-800-424-9300 Outside North America: 1-703-527-3887 Health / 1 Flammability 0 Physical Hazard 0 Personal Protection 0 1 0 Emergency overview Potential short term health effects Routes of exposure Eyes Skin Inhalation Ingestion Target organs Chronic effects Signs and symptoms 2 Hazards Identification This product is regulated by the US FDA as an over-the-counter drug WARNINGS: FOR EXTERNAL USE ONLY WHEN USING THIS PRODUCT AVOID CONTACT WITH EYES, LIPS AND MOUTH If contact occurs, rinse thoroughly with water Use with other topical acne medications, at the same time or immediately following use of this product, may increase dryness or irritation of the skin If this occurs, only one acne medication should be used unless directed by your doctor Limit use to the face and neck Wash hands after use Sun Alert: Because this product may make your skin more sensitive to the sun, be certain you have adequate sunscreeen protection while using this product and for a week after you discontinue use Stop use and ask a doctor if skin or eye irritation develops In case of accidental ingestion, get medical help or contact a Poison Control Center immediately KEEP OUT OF REACH OF CHILDREN Eye, Skin contact, Inhalation, Ingestion Avoid contact with eyes May cause eye irritation upon direct contact with the eyes Prolonged exposure may cause skin irritation Not expected to be a skin sensitizer There are no hazards associated with this product in normal use Ingestion may cause gastrointestinal irritation Eyes Skin The finished product is not expected to have chronic health effects Symptoms may include redness, edema, drying, defatting and cracking of the skin 3 Composition / Information on Ingredients Ingredient(s) CAS # Percent Salicylic acid 69-72-7 1-25 #20281 Page 1 of 6 Issue date 13-Aug-2010
First aid procedures Eye contact Skin contact Inhalation Ingestion Notes to physician General advice 4 First Aid Measures If product gets into the eyes, rinse thoroughly with water Stop use and ask a doctor if eye irritation develops Stop use and ask a doctor if skin irritation develops Remove to fresh air In case of accidental ingestion, get medical help or contact a Poison Control Center immediately Treat patient symptomatically If you feel unwell, seek medical advice (show the label where possible) Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves Show this safety data sheet to the doctor in attendance Avoid contact with eyes Keep out of reach of children 5 Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighters Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Personal precautions Methods for containment Methods for cleaning up Not flammable by OSHA criteria Water spray Foam Dry chemical Sand Firefighters should wear full protective clothing including self contained breathing apparatus May include and are not limited to: Oxides of carbon 6 Accidental Release Measures Do not touch or walk through spilled material Do not touch damaged containers or spilled material unless wearing appropriate protective clothing Stop leak if you can do so without risk Prevent entry into waterways, sewers, basements or confined areas Before attempting clean up, refer to hazard data given above Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers Prevent large spills from entering sewers or waterways Contact emergency services and supplier for advice Never return spills in original containers for re-use Handling Storage 7 Handling and Storage For external use only Avoid contact with eyes, lips and mouth When using do not eat or drink Keep out of reach of children Keep in cool, dry, ventilated storage Keep in original container Keep from freezing Allowances for excursions above 30 C: 60 C - Not more than 5 days 50 C - Not more than 5 days 40 C - Not more than 8 weeks Allowances for excursions below 0 C: Do not store below -20 C #20281 Page 2 of 6 Issue date 13-Aug-2010
Exposure limits Ingredient(s) 8 Exposure Controls / Personal Protection Exposure Limits Salicylic acid Engineering controls Personal protective equipment Eye / face protection Hand protection Skin and body protection Respiratory protection Not normally required ACGIH-TLV Not established OSHA-PEL Not established Not normally required under normal use conditions When handling in large quantities or responding to emergency situations, the use of appropriate eye protection is recommended Not required When handling in large quantities or responding to emergency situations, the use of appropriate eye protection is recommended No special requirements under normal use conditions Not normally required under normal use conditions General hygiene considerations Avoid contact with eyes Handle in accordance with good industrial hygiene and safety practice When using do not eat or drink Appearance gel Color white Form Liquid Odor perfumed Odor threshold Physical state Liquid ph 52-57 Freezing point Boiling point Pour point Evaporation rate Flash point Auto-ignition temperature Flammability limits in air, lower, % by volume Flammability limits in air, upper, % by volume Vapor pressure Vapor density Specific gravity 0965 Octanol/water coefficient Solubility (H2O) VOC (Weight %) Percent volatile 9 Physical and Chemical Properties Soluble 10 Stability and Reactivity Chemical stability Stable under recommended storage conditions Conditions to avoid Do not mix with other chemicals Incompatible materials Acids Oxidizers Hazardous decomposition products May include and are not limited to: Oxides of carbon Possibility of hazardous reactions Hazardous polymerization does not occur #20281 Page 3 of 6 Issue date 13-Aug-2010
Component analysis - LC50 Ingredient(s) Salicylic acid Component analysis - Oral LD50 Ingredient(s) 11 Toxicological Information LC50 LD50 Salicylic acid Effects of acute exposure Eye Skin Inhalation Ingestion Sensitization Chronic effects Carcinogenicity Mutagenicity Reproductive effects Teratogenicity Synergistic Materials Ecotoxicity 891 mg/kg rat; 400 mg/kg cat; 480 mg/kg mouse Avoid contact with eyes May cause eye irritation upon direct contact with the eyes Prolonged exposure may cause skin irritation Not expected to be a skin sensitizer There are no hazards associated with this product in normal use Ingestion may cause gastrointestinal irritation The finished product is not expected to have chronic health effects The finished product is not expected to have chronic health effects The finished product is not expected to have chronic health effects The finished product is not expected to have chronic health effects The finished product is not expected to have chronic health effects The finished product is not expected to have chronic health effects 12 Ecological Information Components of this product have been identified as having potential environmental concerns Ecotoxicity - Freshwater Fish Species Data Salicylic acid 69-72-7 48 Hr LC50 Leuciscus idus: 90 mg/l [static] Ecotoxicity - Water Flea Data Salicylic acid 69-72-7 24 Hr EC50 Daphnia magna: 105 mg/l; 48 Hr EC50 Daphnia magna: 870 mg/l [Static] Environmental effects Aquatic toxicity Persistence / degradability Bioaccumulation / accumulation Partition coefficient Mobility in environmental media Chemical fate information Waste codes Disposal instructions Waste from residues / unused products Contaminated packaging 13 Disposal Considerations Review federal, provincial, and local government requirements prior to disposal #20281 Page 4 of 6 Issue date 13-Aug-2010
14 Transport Information UN/ID No US Department of Transportation (DOT): Classification: Not regulated Proper shipping name US DOT Hazard Class Subsidiary Risk Packing group DOT RQ (lbs) ERG NO Transportation of Dangerous Goods (TDG - Canada): Classification: Not regulated Proper shipping name Status Packing group IMDG (Marine Transport): Classification: Not regulated Proper shipping name Class Subsidiary Risk Packing group IMDG Page Marine pollutant EMS MFAG Maximum Quantity IATA/ICAO (Air): Classification: Not regulated Proper shipping name Class Subsidiary Risk: Packing group Maximum Quantity #20281 Page 5 of 6 Issue date 13-Aug-2010
US Federal regulations 15 Regulatory Information This acne product is in compliance with Title 21 of the Code of Federal Regulations, Part 207 and meets the regulatory requirements outlined in the OTC Monograph under 21 CFR Part 333 Product Registration: Not Registered Occupational Safety and Health Administration (OSHA) 29 CFR 19101200 hazardous Yes chemical Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Section 302 extremely hazardous substance Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No No Section 311 hazardous chemical Yes Clean Air Act (CAA) Clean Water Act (CWA) State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm Inventory status Country(s) or region Inventory name On inventory (yes/no)* United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) Disclaimer 16 Other Information This product should only be used as directed on the label and for the purpose intended To the best of our knowledge, the information contained herein is accurate However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein Final determination of suitability of any material is the sole responsibility of the user All materials may present unknown hazards and should be used with caution Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist Further information 39977-00506 - 1 fl oz - Clearasil ULTRA Acne+Marks Spot Lotion- 0254303 Issue date 13-Aug-2010 Effective date 01-Jul-2010 Prepared by Reckitt Benckiser Regulatory Department 800-333-3899 Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document #20281 Page 6 of 6 Issue date 13-Aug-2010