MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Product name HandsFresh Anti-Bac Foam Soap with Moisturizers - CAS # Product use Manufacturer information Supplier Emergency overview Potential short term health effects Routes of exposure Eyes Skin Ingestion Target organs Chronic effects Signs and symptoms OSHA regulatory status Mixture Antiseptic handwash NWL Netherlands Services BV Newell Rubbermaid Amperestraat 12 2181HB Hillegom, Netherlands Phone + 31 () 252 623 294 Kruger Products L.P. 2-19 Minnesota Court Mississauga, Ontario L5N 5R5 Canada Emergency Phone: 1-8-328-26 Fax: 95-812-691 Phone: 95-812-69 2. Hazards Identification WARNINGS: FOR EXTERNAL USE ONLY. WHEN USING THIS PRODUCT AVOID CONTACT WITH EYES. Eye, Skin contact,, Ingestion. May cause respiratory tract irritation. May cause stomach distress, nausea or vomiting. Eyes. Potential environmental effects See section 12. Prolonged or repeated exposure can cause drying, defatting and dermatitis. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 191.12. 3. Composition/Information on Ingredients Components CAS # Percent Triclosan 338-34-5.1-1 Composition comments Active ingredients are listed above. 4. First Aid Measures First aid procedures Eye contact Skin contact Ingestion Notes to physician General advice In case of eye contact, flush with water. Stop use and ask a doctor, if irritation develops or if condition persists for more than 72 hours. Flush with cool water. Wash with soap and water. Obtain medical attention if irritation persists. If symptoms develop move victim to fresh air. If symptoms persist, obtain medical attention. If swallowed, DO NOT induce vomiting. Get medical attention. Symptoms may be delayed. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Keep out of reach of children. #2526 Page: 1 of 6
5. Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment and precautions for firefighters Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Not flammable by WHMIS/OSHA criteria. Dry chemical. Carbon dioxide. Firefighters should wear full protective clothing including self contained breathing apparatus. May include and are not limited to: Oxides of carbon. Oxides of sulfur. Hydrogen chloride. 6. Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up Keep unnecessary personnel away. Do not touch or walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep people away from and upwind of spill/leak. Do not discharge into lakes, streams, ponds or public waters. Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confined areas. Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Never return spills to original containers for re-use. 7. Handling and Storage Handling Storage Use according to package label instructions. For external use only. DO NOT get in eyes. Do not ingest. Use good industrial hygiene practices in handling this material. Keep out of reach of children. Store in a cool, dry, well-ventilated place away from incompatible materials. 8. Exposure Controls/Personal Protection Exposure limits Engineering controls Personal protective equipment Eye / face protection Hand protection Skin and body protection Respiratory protection General hygiene considerations There are no established ACGIH or OSHA PEL exposure limits for the hazardous chemicals listed in section 3 of the MSDS. General ventilation normally adequate. Not normally required when used as directed. Not applicable. In case of skin irritation, discontinue use of product. Rinse hands thoroughly with potable water after washing. As required by employer code. Not normally required. Handle in accordance with good industrial hygiene and safety practice. 9. Physical and Chemical Properties Appearance Clear #2526 Page: 2 of 6
Color Form Odor Odor threshold Physical state Colorless aqueous solution Mild ph 7.6 Freezing point Boiling point Pour point Evaporation rate Flash point Auto-ignition temperature Flammability limits in air, upper, % by volume Flammability limits in air, lower, % by volume Vapor pressure Vapor density Liquid. 32 F ( C) > 212 F (> 1 C) None Not applicable Not applicable Not applicable Specific gravity 1.3 (Water = 1) Partition coefficient (n-octanol/water) Solubility (water) Relative density Viscosity VOC Percent volatile Reactivity Possibility of hazardous reactions Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Appreciable Slightly viscous 1. Stability and Reactivity This product may react with acids. This product may react with oxidizing agents. Hazardous polymerization does not occur. Stable under recommended storage conditions. Do not mix with other chemicals. Caustics. Acids. Oxidizers. May include and are not limited to: Hydrogen chloride. Oxides of carbon. Oxides of sulfur. 11. Toxicological Information Toxicological data Components Triclosan (CAS 338-34-5) Acute Dermal LD5 LC5 Oral LD5 Effects of acute exposure Eye contact Species Rabbit Rat Rat Mouse Rat Test Results 93 mg/kg 93 mg/kg > 14 mg/m3, 4 Hours 453 mg/kg 37 mg/kg #2526 Page: 3 of 6
Skin contact Ingestion Sensitization Chronic effects Carcinogenicity Mutagenicity Reproductive effects Teratogenicity Name of Toxicologically Synergistic Products May cause respiratory tract irritation. May cause stomach distress, nausea or vomiting. 12. Ecological Information Ecotoxicity Components of this product have been identified as having potential environmental concerns. Ecotoxicological data Components Triclosan (CAS 338-34-5) Aquatic Fish Persistence and degradability Bioaccumulation / Accumulation Mobility in environmental media Environmental effects Aquatic toxicity Triclosan - Bluegill, Lepomis macrochirus, 96 hour, LC5 37. ug/l Triclosan - Rainbow trout,donaldson trout, Oncorhynchus mykiss, 96 hour, LC5 288 ug/l Triclosan - Medaka, high-eyes, Oryzias latipes, 96 hour, LC5 451 ug/l Triclosan - Fathead minnow, Pimephales promelas, 96 hour, LC5 342.5 ug/l Triclosan - Water flea, Daphnia magna, 48 hour, EC5.39 mg/l LC5 Species Fathead minnow (Pimephales promelas) Partition coefficient Triclosan 4.76 Chemical fate information Disposal instructions Waste from residues / unused products Contaminated packaging 13. Disposal Considerations Dispose in accordance with all applicable regulations. U.S. Department of Transportation (DOT) Not regulated as dangerous goods. Transportation of Dangerous Goods (TDG - Canada) Not regulated as dangerous goods. Canadian federal regulations 14. Transport Information 15. Regulatory Information Test Results.3 -.5 mg/l, 96 hours This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. WHMIS classification Exempt - Registered product - (DIN 2245467) #2526 Page: 4 of 6
Occupational Safety and Health Administration (OSHA) 29 CFR 191.12 hazardous chemical US federal regulations Yes This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 191.12. TSCA Section 12(b) Export Notification (4 CFR 77, Subpt. D) CERCLA Hazardous Substance List (4 CFR 32.4) Not listed. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (4 CFR 68.13) Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List CERCLA (Superfund) reportable quantity None Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories State regulations Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance Not listed. US. Massachusetts RTK - Substance List US. Pennsylvania RTK - Hazardous Substances US. Rhode Island RTK Inventory status Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) 16. Other Information No No Severe Serious Moderate Slight Minimal LEGEND 4 3 2 1 HEALTH FLAMMABILITY PHYSICAL HAZARD PERSONAL PROTECTION / 1 X 1 Disclaimer Issue date Effective date Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. 29-August-213 31-August-213 #2526 Page: 5 of 6
Expiry date 31-August-216 Prepared by Dell Tech Laboratories, Ltd. Phone: (519) 858-521 Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document. This MSDS conforms to the ANSI Z4.1/Z129.1-21 Standard. #2526 Page: 6 of 6