MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Product name CAS # Product Use Distributed by AMOPE PEDI PERFECT Daily Moisturizer Mixture This MSDS is designed for workplace employees, emergency personnel and for other conditions and situations where there is a greater potential for large-scale or prolonged exposure, in accordance with requirements of the Canadian Workplace Hazardous Materials Information System (WHMIS). This MSDS is not applicable for consumer use of our products. For consumer use, all precautionary and first aid language is provided on the product label in accordance with the applicable government regulation. Skin Cream Reckitt Benckiser (Canada) Inc. 1680 Tech Avenue Unit #2 Mississauga, ON L4W 5S9 In Case of Emergency: 1-800-338-6167 Transportation Emergencies: 24 Hour Number: North America: CHEMTREC: 1-800-424-9300 Outside North America: 1-703-527-3887 LEGEND Severe 4 Serious 3 Moderate 2 Slight 1 Minimal 0 Emergency overview HEALTH / 1 FLAMMABILITY 0 PHYSICAL HAZARD 0 PERSONAL PROTECTION X KEEP OUT OF REACH OF CHILDREN. 0 1 0 2. Hazards Identification Potential short term health effects Routes of exposure Eye, Skin contact,, Ingestion. Eyes Causes irritation. Skin The finished product is not expected to cause irritation. Not expected to be a skin sensitizer. No risks anticipated in normal use. Ingestion Ingestion may cause gastrointestinal irritation. Target organs Eyes. Skin. Respiratory system. Reproductive System. Chronic effects Signs and symptoms Symptoms may include redness, oedema, drying, defatting and cracking of the skin. Potential environmental effects See section 12. 3. Composition/Information on Ingredients Components CAS # Percent Glycerin 56-81-5 10-30 Mineral Oil 8042-47-5 5-10 Sodium Gluconate 527-07-1 3-7 Dimethicone 63148-62-9 1-5 Dimethylimidazolidinone Rice Starch 172275-79-5 1-5 #24981 Page: 1 of 7 Issue date 16-July-2014
Components CAS # Percent Niacinamide Phenoxyethanol 98-92-0 1-5 122-99-6 0.1-1 4. First Aid Measures First aid procedures Eye contact Skin contact Ingestion Notes to physician General advice Immediately rinse eye for several minutes with plenty of lukewarm water whilst separating the eyelids. If irritation persists, seek medical attention. Cosmetic product designed to be in contact with the skin. In case of accidental and excess application of the product, rinse with water. Not an anticipated route of exposure. Move victim to fresh air. If symptoms persist, obtain medical attention. Do not induce vomiting. Immediately rinse the mouth with water. Drink one pint (500mL) of water unless there is evidence of burns or difficulty swallowing. Seek medical advice immediately. Treat patient symptomatically. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with eyes. Keep out of reach of children. 5. Fire Fighting Measures Flammable properties Not flammable by WHMIS criteria. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighters Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Water spray. Foam. Carbon dioxide. Dry chemical. Firefighters should wear full protective clothing including self contained breathing apparatus. May include and are not limited to: Oxides of carbon. Oxides of nitrogen. Oxides of sulfur. 6. Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up Keep unnecessary personnel away. Do not touch or walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep people away from and upwind of spill/leak. Floors may become slippery. Do not discharge into lakes, streams, ponds or public waters. Advise authorities if product has penetrated drains, sewers or water pipes. Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confined areas. Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. #24981 Page: 2 of 7 Issue date 16-July-2014
7. Handling and Storage Handling Storage Ensure adequate ventilation. Avoid contact with eyes. Use good industrial hygiene practices in handling this material. Avoid spillage on carpets, clothes and flooring. Use according to package label instructions. Keep out of reach of children. Store in a closed container away from incompatible materials. Do not store contents under direct sunlight. Keep from freezing. Allowances for excursions above 30 C: >50 C - Not permitted. 40 C - Not more than 8 weeks. Allowances for excursions below 0 C: Do not store below -20 C. 8. Exposure Controls/Personal Protection Occupational exposure limits US. ACGIH Threshold Limit Values Components Type Value Form Mineral Oil (CAS 8042-47-5) Exposure limits Engineering controls Personal protective equipment Eye / face protection Hand protection Skin and body protection Respiratory protection General hygiene considerations TWA 5 mg/m3 Inhalable fraction. Chemicals listed in section 3 that are not listed here do not have established limit values for ACGIH or OSHA PEL. General ventilation normally adequate. Consult the product label for special protection or precautions that have been identified for using this product under directed consumer use conditions. The following recommendations are given for workplace employees, emergency personnel and for other conditions and situations where there is a greater potential for large-scale or prolonged exposure. Follow standard industrial hygiene practices. Not required Not normally required. Appearance Lotion Colour White. Form Cream Odour Characteristic Odour threshold Physical state Liquid. ph 4.70-5.80 Freezing point Boiling point Pour point Evaporation rate Flash point Auto-ignition temperature Flammability Limits in Air, Upper, % by Volume Where exposure guideline levels may be exceeded, use an approved NIOSH respirator. Handle in accordance with good industrial hygiene and safety practices. When using do not eat or drink. Wash hands before breaks and immediately after handling the product. 9. Physical and Chemical Properties #24981 Page: 3 of 7 Issue date 16-July-2014
Flammability Limits in Air, Lower, % by Volume Heat of combustion Vapour pressure Vapour density Specific gravity Partition coefficient (n-octanol/water) Solubility (Water) Relative density Viscosity VOC Percent volatile Reactivity Possibility of hazardous reactions Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Insoluble 0.950-1.050 g/cm 10. Stability and Reactivity This product may react with oxidizing agents. Hazardous polymerisation does not occur. Stable under recommended storage conditions. Do not mix with other chemicals. Temperatures below 5 C and >40 C. Keep from freezing. Oxidizing agents. May include and are not limited to: Oxides of carbon. Oxides of nitrogen. Oxides of sulfur. 11. Toxicological Information Toxicological data Components Dimethicone (CAS 63148-62-9) Species Rabbit Dimethylimidazolidinone Rice Starch (CAS 172275-79-5) Glycerin (CAS 56-81-5) Rabbit Mouse Test results > 2000 mg/kg > 17000 mg/kg > 10000 mg/kg 23000 mg/kg > 143 mg/m³, 4 Hours 23000 mg/kg #24981 Page: 4 of 7 Issue date 16-July-2014
Components Species Test results > 12600 mg/kg Mineral Oil (CAS 8042-47-5) Niacinamide (CAS 98-92-0) Rabbit 27200 mg/kg > 2000 mg/kg 5000 mg/kg > 2.2 mg/l, 4 Hours > 2000 mg/kg 2000 mg/kg Mouse 2500 mg/kg Phenoxyethanol (CAS 122-99-6) Sodium Gluconate (CAS 527-07-1) Mouse 3500 mg/kg 14422 mg/kg 14300 mg/kg 16500 mg/kg 2563-4013 mg/kg, females 1386-2937 mg/kg, males 1260 mg/kg > 2000 mg/kg Effects of acute exposure Eye contact Skin contact Ingestion Sensitisation Chronic effects Causes irritation. The finished product is not expected to cause irritation. Not expected to be a skin sensitizer. No risks anticipated in normal use. Ingestion may cause gastrointestinal irritation. #24981 Page: 5 of 7 Issue date 16-July-2014
Carcinogenicity Mutagenicity Reproductive effects Teratogenicity Name of Toxicologically Synergistic Products The finished pr oduct is not expected to have chronic health effects. 12. Ecological Information Ecotoxicity See below Ecotoxicological data Components Dimethicone (CAS 63148-62-9) Species Test results Aquatic Fish Channel catfish (Ictalurus punctatus) 2.36-4.15 mg/l, 96 hours Glycerin (CAS 56-81-5) Aquatic Fish Rainbow trout,donaldson trout (Oncorhynchus mykiss) 51000-57000 mg/l, 96 hours Phenoxyethanol (CAS 122-99-6) Algae IC50 Algae 500 mg/l, 72 Hours Crustacea EC50 Daphnia 500 mg/l, 48 Hours Aquatic Fish Fathead minnow (Pimephales promelas) 337-352 mg/l, 96 hours Persistence and degradability Bioaccumulation/accumulation Mobility in environmental media Environmental effects Aquatic toxicity Partition coefficient Glycerin -1.76 Niacinamide -0.37 Phenoxyethanol 1.16 Chemical fate information 13. Disposal Considerations Disposal instructions Waste from residues / unused products Contaminated packaging Dispose in accordance with all applicable regulations. Dispose of empty packaging with normal household trash. U.S. Department of Transportation (DOT) Transportation of Dangerous Goods (TDG - Canada) IATA/ICAO (Air) IMDG (Marine Transport) 14. Transport Information #24981 Page: 6 of 7 Issue date 16-July-2014
15. Regulatory Information Canadian federal regulations This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. All components of this product are either on the Domestic Substances List (DSL), the Non-Domestic Substances List (NDSL) or exempt. Canada NPRI VOCs with Additional Reporting Requirements: Mass reporting threshold/identification Number Mineral Oil (CAS 8042-47-5) Canada WHMIS Ingredient Disclosure: Threshold limits Mineral Oil (CAS 8042-47-5) 1 % Phenoxyethanol (CAS 122-99-6) 1 % WHMIS Classification Inventory status 1 TONNES Exempt - Notified cosmetic under the Food & Drugs Act Country(s) or region Inventory Name On Inventory (Yes/No)* Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) No *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) 16. Other Information Disclaimer This product should only be used as directed on the label and for the purpose intended. To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Further information AMOPE PEDI PERFECT Daily Moisturizer 250mL 0243005v5.0 Issue date 16-July-2014 Effective date 15-July-2014 Expiry Date 15-July-2017 Prepared by Dell Tech Laboratories Ltd. Phone: (519) 858-5021 Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document. This MSDS conforms to the ANSI Z400.1/Z129.1-2010 Standard. #24981 Page: 7 of 7 Issue date 16-July-2014