Silicones for Personal Care

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www.hrssilicone.com www.hrssilicone.cn Silicones for Personal Care HRS offers a wide range of solutions with unique consumer benefits for skin care, hair care, body care, sun care and color cosmetics.

contents Introduction Product Line Applications of Silicones Silicone Fluids Polymer-Fluid Blends Silicone s Silicone Copolyols Phenyl modified Fluids Silicone Resins Silicone Emulsions UV Absorber Unique Silicone Polymer EWG Green Score Products Silicones for Personal Care HRS Co., Ltd. was established in 1981 and developed silicone Elastomer for the first time in Korea. We have focused on silicone business for the last 37 years. Now we have a variety of products such as HCR, LSR, RTV, TSP(thermal conductive silicone rubber) and Silicones for Personal Care. HRS for Your Beauty

Applications of Silicones Silicone For Cosmetic Silicones for personal care Sun Care Skin Care Product Line CUSTOMIZE CUSTOMIZE Body Care Hair Care Elastomer Gel Series Resin Blends Series Gum Blends Series OIL Series EMULSIFYING AGENT Silicone For Cosmetic Polymer Series - Fluids - Powder Emulsion Seris UNIQU SILICONES Make Up Other CUSTOMIZE CUSTOMIZE HRS Silicone Technology 04 _ 05

Characteristics of silicone for cosmetic Silicone for Personal Care Volatile Silicone Fluids Dimethicone Fluid Phenyl modified Fluids Polymer-Fluid Blends(Gum Blends) Silicone s Dimethicone Copolyols Silicone Emulsions Silicone Resins Silicone Resin : Polymethylsilsesquioxane(PMSQ) Alkyldimethicones Vinyl Dimethicone Fluids Unique Silicone Polymers HRS for Your Beauty 01 Silicone is widely used in personal care for its advantages of water repellency, lubrication, low surface tension, safety, great usability and appliance, gloss, great moisturizing effect and nontoxic. 02 Silicone can be applied for Skin Care / Cream, Lotion, Make-up / BB Cream, Lip stick, Hair Care / Shampoo, Treatment, Sun Care / Sun Cream, Sun Gel, Body Care / Body Lotion, Body Cream and so on. 03 Selective application for product development from various dosage form of silicone. HRS Silicone Technology 06 _ 07

SILICONE OIL GRADE - Silicone oil used for cosmetic is normally transparent, odorless, physiologically inertness that is highly secure for human body - Usefully used to improve quality and performance of cosmetics due to its great spreadability, appliance, sticky less, water repellency, heteroplastic, inertness of other materials. So, it can be applied for skin care, make-up, foundation, hair care, sun care and body care and etc SILICONE ELASTOMER GEL/POWDER GRADE - Swelling low viscosity (volatile and non-volatile) oil and Cross Polymer together to make elastic silicone to bring cushioning for cosmetics - Bring higher viscosity, and reduce sticky effectively - Absorb face surface sebum to make smooth skin - Give Softness, Soft focus, Silky Touch, Matt characteristics SILICONE GUM() GRADE - is a heavy molecular weight silicone, based on dimethylsiloxane, which has hydroxyl group in the end - is used for wound healing, scar improvement, and also FDA approved its usage as over-thecounter drugs for skin protection component - Great spreading power due to low surface tension, great gloss lubrication and outstanding feeling - Gives soft sense of usage and appliance, and also prevents bubbles to grow in manufacturing - As skin emollient, it vitalizes skin and hair, and also keep the skin moisty from making protective film on skin SILICONE RESIN GRADE - Great skin adhesive power to keep the skin moisty for long time - Great skin adhesive power that is indelible from water, sweat or sebum - Can be applied for skin care, make up : waterproof, BB cream and etc NEW UV ABSORBER FOR COSMETIC SUNSCREENS - Composed benzotriazole with siloxane which has great compatibility with solvent - Low skin stimulation, great feeling and appliance and high water repellency - Block UVA and UVB at the same time, absorbs ultraviolet energy to convert into thermal energy SILICONE EMULSIONS GRADE - Silicone Emulsion is made from water, silicone oil, surfactant and other additives - Unique sense of usage - Silicone emulsion can be applied to antifoaming agent, release agent, water-repellenting agent, raw material for cosmetic, fiber disposal agent and so on HRS Silicone Technology 08 _ 09

HRS offers a wide range of solutions with unique consumer benefits for skin care, hair care, body care, sun care and color cosmetics. We will always engage on the development for better techniques and products. Silicone Fluids Volatile Silicone Fluids Dimethicone Fluids Product Name INCI Name Flash Point ( ) (Closed cup) Surface Tension (Mn/m) Specific Gravity at 25 (g/cm3) Product Name INCI Name HRC-C4 Cyclotetrasiloxane 2.40 55 17.80 0.950 HRC-D5 Dimethicone 5 HRC-D6A Dimethicone 6 HRC-C5 Cyclopentasiloxane 4.00 77 18.00 0.950 HRC-D10 Dimethicone 10 HRC-D20 Dimethicone 20 HRC-C6 Cyclohexasiloxane 6.80 93 18.80 0.960 HRC-D50 Dimethicone 50 HRC-CC45 Cyclotetrasiloxane (and) Cyclopentasiloxane 2.70 58 19.00 0.950 HRC-D100 Dimethicone 100 HRC-D200 Dimethicone 200 HRC-CC56 Cyclohexasiloxane 6.00 77 20.80 0.960 HRC-D300 Dimethicone 300 HRC-D350 Dimethicone 350 HRC-D0.65 Disiloxane 0.65 1 15.90 0.760 HRC-D500 Dimethicone 500 HRC-T1 Trisiloxane 1.00 30 17.40 0.816 HRC-D1,000 Dimethicone 1,000 HRC-D12,500 Dimethicone 12,500 HRC-D1.5 Dimethicone 1.50 57 18.00 0.851 Alkyldimethicones HRC-D2 Dimethicone 2.00 87 18.70 0.872 Refractive index at 25 HRC-CED45 Cetyl Dimethicone Clear to pale yellowish liquid 45 1.440 HRC-DT1.5 Trisiloxane 1.50 42 17.90 0.850 HRC-CAM03 Caprylyl Methicone Clear colorless liquid 3 1.413 HRS Silicone Technology 10 _ 11

We will always engage on the development for better techniques and products. Silicone Fluids Polymer-Fluid Blends Special Silicone Oil Gum Blends Product Name INCI Name Content(%) Gum HRC-PAD PCA Dimethicone Yellowish Clear liquid 700 ~ 900 HRC-C6DL Cyclohexasiloxane (and) 70,000 25 HRC-HD Hydrogen Dimethicone Clear colorless liquid 30 ~70 HRC-AD36 Amodimethicone Clear colorless liquid 30 ~40 HRC-V10DL Vinyl 100,000 25 HRC-LM Lauryl Methicone Clear colorless liquid 3 ~7 HRC-SM Stearyl Methicone Clear colorless liquid 7 ~11 HRC-CDL15 Cyclotetrasiloxane (and) 5,000 15 HRC-CDL75B 6,500 17 Vinyl Dimethicone Fluids Product Name INCI Name Molecular Weight (g/mol) Refractive index at 25 HRC-100 Vinyl Dimethicone 100 7,500 1.404 HRC-CDL60 6,000 15 HRC-200 Vinyl Dimethicone 200 14,500 1.404 HRC-CDL76 Cyclomethicone (and) 7,500 18 HRC-1,000 Vinyl Dimethicone 1,000 31,000 1.404 HRC-1,500 Vinyl Dimethicone 1,500 42,000 1.404 HRC-DDL69 7,500 16 HRC-3,000 Vinyl Dimethicone 3,000 50,000 1.404 HRC-10,000 Vinyl Dimethicone 10,000 70,000 1.404 HRC-20,000 Vinyl Dimethicone 20,000 81,000 1.404 HRC-65,000 Vinyl Dimethicone 65,000 104,000 1.404 HRC-165,000 Vinyl Dimethicone 165,000 132,000 1.404 Silicones for Personal Care HRS offers a wide range of solutions with unique consumer benefits for skin care, hair care, body care, sun care and color cosmetics. HRS Silicone Technology 12 _ 13

We will always engage on the development for better techniques and products. Silicone s Silicone Elastomer Blends Silicone Elastomer Blends Content(%) Gel Content(%) Gel HRC-SP5000 HRC-SP5058 (Heavy Type) HRC-SP1775 (Midium Type) HRC-SP6659 (Light Type) Caprylyl Methicone (and) 470,000~530,000 8 ~15 1,000,000~1,600,000 8 ~15 650,000~750,000 8 ~15 480,000~500,000 8 ~15 HRC-DSB65 HRC-WD45 Stearyl Methicone (and) Dimethicone/ Vinyl Dimethicone (and) Beeswax Aqua (and) Glycerin (and) Butylene (and) Glycol (and) Glyceryl Isostearate (and) Pentylene Glycol (and) Tocopheryl Acetate (and) Acetate (and) (and) Diglycerin (and) 1,2 Hexanediol * Water Dispersion White Paste Paste 8 ~15 Transparent Gel 36,000 ~ 42000 41 ~ 45 HRC-SP7669 (Heavy Type) 750,000~800,000 8 ~15 Silicone Copolyols HRC-SP4772 (Light Type) 460,000~500,000 8 ~15 Emulsifiers HLB HRC-SP3014 27,000~33,000 11 ~16 HRC-EF2008 HRC-EF3013 PEG/PPG-18/18 Dimethicone PEG-12 Dimethicone Clear to slightly hazy liquid Clear, Colourless Liquid 2,000 8 300 13 HRC-SP3014B 27,000~33,000 11 ~16 HRC-EF1205 HRC-EF6045 Cetyl PEG/PPG-10/1 Dimethicone PEG-10 Dimethicone to slightly yellow viscous liquid Clear, Colourless Liquid 1,250 5 600 4.5 HRC-SP3011 27,000~33,000 11 ~16 HRC-EF3002 PEG/PPG-18/18 Dimethicone Translucent to white liquid 30. 2 HRC-SP5512 52,000~58,000 9 ~15 Phenyl modified Fluids HRC-SP1006 8,000~12,000 9 ~15 Refractive index at 25 HRC-PTM20 Phenyl Trimethicone Colourless liquid 22.50 1.46 HRS Silicone Technology 14 _ 15

We will always engage on the development for better techniques and products. Silicone Resins Resin Powder Content(%) resin Particle Size (μm) HRC-TMS Trimethylsiloxysilicate White to off-white flakes 100 10 Silicone Emulsions HRC-ES2060 (and) TEAdodecylbenzenesulfonate Content(%) resin Color White to off-white 200 30 HRC-ES0535 Amodimethicone (and) Trideceth-12 (and) Cetrimonium chloride Milky white water/thin liquid 5 35 Resin Treatment Particle Size (μm) HRC-ES3020 Amodimethicone (and) Trideceth-7 (and) Trideceth-5 (and) Propylene Glycol (and) Trideceth-12 Clear to slightly hazy 30 20 HRC-PMS-2 Polymethylsilsesquioxane White Fine Powder 2 HRC-EF2020 Silicone Quaternium-17 (and) Trideceth-7 (and) Trideceth-5 Clear, pale liquid 20 20 HRC-PMS-5 Polymethylsilsesquioxane White Fine Powde 5 HRC-EF5050 Laureth-4 (and) Laureth-23 (and) Salicylic Acid Milky white 5,000 50 Resin Blends Vinyl to slightly HRC-TMS8035 Trimethylsiloxysilicate yellowish Content(%) resin 600 35 Silicones for Personal Care HRS offers a wide range of solutions with unique consumer benefits for skin care, hair care, body care, sun care and color cosmetics. HRC-TMS2050 Trimethylsiloxysilicate Slightly colored, clear to slightly hazy liquid 200 50 HRC-TMS1050 Isododecane (and) Trimethylsiloxysilicate Clear to slightly hazy liquid 10 50 HRC-TMS7030 Trimethylsiloxysilicate Colourless to pale yellow viscous liquid 700 30 HRS Silicone Technology 16 _ 17

We will always engage on the development for better techniques and products. uv absorber Unique Silicone Polymer uv absorber Features & Benefits Product Name INCI Name cp at 25 Hardness (time) Characteristics Appearance - Excellent Compatibility with solvent. HRC-SUV Benzotriazole Liquid - Excellent UV absorber hrc-suv & benzotriazole solubility contrast Benzotriazole HRC-SUV 1/9 5/5 1/9 5/5 HRC-LS-2830/1 A Vinyl Silica 30,000 HRC-LS-2830/1 B Vinyl Silica (and) Hydrogen Dimethicone 15,000 HRC-LS-2850/1 A Vinyl Silica 30,000 HRC-LS-2850/1 B Vinyl Silica (and) Hydrogen Dimethicone 30,000 5min 1:1 mixed 3min 1:1 mixed - High gloss - Improves spread - Mattifying effect This 2-part blend crosslinks to create a transparent gel. Can be used in colour cosmetics and woundcare applications.has the ability to thicken other silicone oils.recommended usage level of 1:1 weight ratio mixture 1.0~ 100%., Translucence paste Cyclopentasiloxane I I S S HRC-DM-3045/1 A Vinyl Silica (and) Quartz 30,000 - High gloss - Improves spread - Mattifying effect Dimethicone-6cst I I D S Dimethicone-50cst I I D I Alkyl Benzoate I I S S Olive oil I I I I HRC-DM-3045/1 B Vinyl Silica (and) Hydrogen Quartz 26,000 3min 1:1 mixed This 2-part blend crosslinks to create a white gel. Can be used in colour cosmetics and wound care applications.has the ability to thicken other silicone oils.recommended usage level of 1:1 weight ratio mixture 1.0~ 100%. White Paste Mineral oil I I S S Jojoba oil I I S S Unique Silicone Polymers Glycerin I I I I Product Name INCI Name Application Phenyl trimethicone I I S S Vaseline I I S S HRC-GS100A Vinyl Trimethylsiloxysilicate HRC-GS100B Vinyl Trimethylsiloxysilicate (and) Hydrogen Dimethicone Silicone gel patch Stearic acid I I I I HRC-GS101A Vinyl Trimethylsiloxysilicate LIFTING MASK Ethanol I I S S ( Insoluble Dispersible Soluble ) HRC-GS101B Vinyl Trimethylsiloxysilicate (and) Hydrogen Dimethicone Silicone gel HRS Silicone Technology 18 _ 19

We will always engage on the development for better techniques and products. EWG Green Score Products Groups Product Name INCI Name EWG Score Groups Product Name INCI Name EWG Score HRC-C6 Cyclohexasiloxane 2 HRC-PAD PCA Dimethicone 1 Volatile Silicone Fluids HRC-D0.65 Disiloxane 2 HRC-T1 Trisiloxane 2 HRC-HD Hydrogen Dimethicone 1 Phenyl Modified Fluid HRC-PTM20 Phenyl Trimethicone 1 HRC-C6DL Cyclohexasiloxane (and) 2 Gum Blends HRC-V10DL Vinyl 1 Silicone Oil HRC-AD36 Amodimethicone 1 HRC-LM Lauryl Methicone 1 Silicone Resins HRC-TMS Trimethylsiloxysilicate (10 µm) 1 HRC-TMS8035 Vinyl Trimethylsiloxysilicate 1 HRC-SM Stearyl Methicone 1 HRC-PMS-2 Polymethylsilsesquioxane (particle size 2um) 1 Resin Treatment HRC-PMS-5 Polymethylsilsesquioxane (particle size 5um) 1 HRC-SP5000 Caprylyl Methicone (and) Dimethicone/ Vinyl Dimethicone 1 HRC-CED45 Cetyl Dimethicone 1 Alkyl Dimethicones HRC-CAM03 Caprylyl Methicone 1 HRC-100 Vinyl Dimethicone 1 Elastomer Silicone Gel HRC-SP6000 Luaryl Methicone (and) Dimethicone/ Vinyl Dimethicone 1 HRC-200 Vinyl Dimethicone 1 HRC-1,000 Vinyl Dimethicone 1 HRC-CSB16 Caprylyl Methicone (and) Stearyl Methicone (and) Dimethicone/ Vinyl Dimethicone (and) Beeswax 1 HRC-1,500 Vinyl Dimethicone 1 Vinyl Dimethicone Fluids HRC-3,000 Vinyl Dimethicone 1 HRC-10,000 Vinyl Dimethicone 1 HRC-20,000 Vinyl Dimethicone 1 HRC-65,000 Vinyl Dimethicone 1 HRC-165,000 Vinyl Dimethicone 1 HRC-LS-2830/1 A Vinyl Silica 2 Silicones for Personal Care HRS offers a wide range of solutions with unique consumer benefits for skin care, hair care, body care, sun care and color cosmetics. Unique Silicone Polymers HRC-LS-2830/1 B Vinyl Silica (and) Hydrogen Dimethicone 2 HRC-LS-2850/1 A Vinyl Silica 2 HRC-LS-2850/1 B yl Silica (and) Hydrogen Dimethicone 2 HRS Silicone Technology 20 _ 21

EMULSION Silicone for Personal Care Silicone Emulsion is insoluble silicones which silicone oil is evenly dispersed in water without using any organic solvent. It is composed of surfactant, oil, silicone oil and other additives. The market demand for silicone emulsion is increasing due to its characteristics of Eco-Friendly products. Silicone has low surface tension, excellent water repellency, colorless, tasteless and odorless. It's very safe and widely used to make skin/body care products, sun care product, shampoo, hair care products such as treatment and color cosmetic products. HRS Silicone Technology 22 _ 23

everything for your life Seoul Office #1605, Miwon Bldg.,70, Gukjegeumyung-ro, Yeongdeungpo-gu, Seoul, KOREA 07333 TEL 82-2-780-6156~8 FAX 82-2-785-7643 Pyongtaek Plant 7, Chupalsandan 2-gil, Paengseong-eup, Pyeongtaek-si, Gyeonggi-do, KOREA 17998 TEL 82-31-655-8822 FAX 82-31-691-5901 Asan Plant 103-15, Sinbong-gil, Yeongin-myeon, Asan-si, Chungcheongnam-do, KOREA 31401 TEL 82-41-543-4003 FAX 82-41-543-4006 China Plant Plant 1, Science & Technology Park No.777 Kangyuan Road, Suzhou Xiangcheng Economic Development Zone. TEL 86-512-6939-0288 FAX 86-512-6618-9388 Date of Issue: November, 2016 Published by HRS Co., Ltd.