Page 1 of 12 The following sample(s) was/were submitted and identified by/on behalf of the applicant as Sample Description CTS Reference No. Sample Receiving Date Testing Period Sample Submitted By KM+ ADVANCED FUEL ADDITIVE CTS/SA/14/0214/BIOSURGE 2014/01/27 2014/01/27 TO 2014/02/07 ============================================================================================ Test Requested 151 Substances of Very High Concern screening. SVHC candidate list based on the publication by European Chemicals Agency (ECHA) on 2013 December 16, regarding Regulation (EC) No 1907/2006 concerning the REACH. Test Method Test Result(s) Summary Please refer to next page(s). Please refer to next page(s). According to the interpretation of ECHA and the majority of EU member states on the definition of an article as well as the specified scope and analytical technique, concentrations of all SVHC are <0.1% in the submitted sample(s).
Page 2 of 12 Test Sample TRANSPARENT KM+ ADVANCED FUEL ADDITIVE Test Method Remark 1. The chemical analysis of 151 SVHC is performed by means of currently available analytical techniques against the list published by ECHA on 2013 December 16. Refer to http//echa.europa.eu/web/guest/candidatelisttable 2. In accordance with Regulation (EC) No 1907/2006, any producer or importer of articles shall notify ECHA, in accordance with paragraph 2 of Article 7, if a substance meets the criteria in Article 57 and is identified in accordance with Article 59(1) of the Regulation, if (a) the substance is present in those articles in quantities totaling over one tonne per producer or importer per year; and (b) the substance is present in those articles above a concentration of 0.1% weight by weight (w/w). 3. Article 33 of Regulation (EC) No 1907/2006 requires supplier of an article containing a substance meeting the criteria in Article 57 and identified in accordance with Article 59(1) in a concentration above 0.1% weight by weight (w/w) shall provide the recipient of the article with sufficient information, available to the supplier, to allow safe use of the article including, as a minimum, the name of that substance. 4. If a SVHC is found over the reporting limit, client is suggested to identify the component which contains the SVHC and the exact concentration of the SVHC by requesting further quantitative analysis from the laboratory. Test Result(s) Anthracene (CAS No. 120127) 4,4' Diaminodiphenylmethane (CAS No. 101779) BBP (Benzyl butyl phthalate) (CAS No. 85687) Bis (2ethyl(hexyl)phthalate) (DEHP) (CAS No. 117817) 5tertbutyl2,4,6trinitro mxylene (Musk Xylene) (CAS No. 81152) DBP (Dibutyl phthalate) (CAS No. 84742) Hexabromocyclododecane (HBCDD) andpbt all major diastereoi identified (α HBCDD, β HBCDD, γ HBCDD) (CAS No. 25637994 and 3194556 (134237517, 134237506, 134237528)) Alkanes, C1013, chloro (Short Chain Chlorinated Paraffins) (CAS No. 85535848) Cobalt dichloride (CAS No. 7646799) SGS InHouse methodrstseesvhc007. Analyzed by ICPAES, UVVIS, GC/MS, LC/MS, GC/FPD, LC/MS/DAD. Bis(tributyltin)oxide (TBTO)*** (CAS No. PBT 56359) 0.005 Classification PBT vpvb PBT ;
Page 3 of 12 Diarsenic pentaoxide*** (CAS No. 1303282) Diarsenic trioxide*** (CAS No. 1327533) Triethyl arsenate*** (CAS No. 15606958) Lead hydrogen arsenate*** (CAS No. 7784409) ( 1) Sodium chromate*** (CAS No. 7775113) Ammonium dichromate*** (CAS No. 7789095) Potassium dichromate*** (CAS No. 7778509) Potassium chromate*** (CAS No. 7789006) Sodium dichromate*** (CAS No. 10588019, 7789120(*)) Chromium trioxide*** (CAS No. 1333820) Acids generated from chromium trioxide and their oligomers Chromic acid*** (CAS No. 7738945) Acids generated from chromium trioxide and their oligomers Dichromic acid*** (CAS No. 13530682) Acids generated from chromium trioxide and their oligomers Oligomers of chromic acid and dichromic acid (*1) Strontium chromate*** (CAS No. 7789062) Anthracene oil (CAS No. 90640805) (**) Anthracene oil, anthracene paste, distn. Lights (CAS No. 91995174) (**) Anthracene oil, anthracene paste, anthracene fraction (CAS No. 91995152) (**) Anthracene oil, anthracenelow (CAS No. 90640827) (**) Anthracene oil, anthracene paste (CAS No. 90640816) (**) Pitch, coal tar, hightemp. (CAS No. 65996932) (**) DIBP (Diisobutyl phthalate) (CAS No. 84695) 2,4Dinitrotoluene (CAS No. 121142) Tris(2chloroethyl) phosphate (TCEP) (CAS No. 115968) Lead chromate molybdate sulphate red (C.I. Pigment Red 104) (CAS No. 12656858) Lead chromate (CAS No. 0.01 7758976) ; 0.01 Classification ; ; MC2; ; MC2; ; MC2; ; MC2 ; MC2; ; MC2 PBT; vpvb; PBT; vpvb; ; MC2 PBT; vpvb; ; MC2 PBT; vpvb; ; MC2 PBT; vpvb; ; MC2 PBT; vpvb; ;
Page 4 of 12 Lead sulfochromate yellow (C.I. Pigment Yellow 34) (CAS No. 1344 372) Acrylamide (CAS No. 79061) Boric acid*** (CAS No. 10043353; 11113501) Disodium tetraborate, anhydrous*** (CAS No. 1303964, 1330434, 12179043) Tetraboron disodium heptaoxide, hydrate (CAS No. 12267731) (*2) Trichloroethylene (CAS No. 79016) Cobalt(II) sulphate*** (CAS No. 10124433) Cobalt(II) dinitrate*** (CAS No. 10141056) Cobalt(II) carbonate*** (CAS No. 513791) Cobalt(II) diacetate*** (CAS No. 71487) 2Methoxyethanol (CAS No. 109864) 2Ethoxyethanol (CAS No. 110805) 2ethoxyethyl acetate (CAS No. 111159) 1,2Benzenedicarboxylic acid, dic711branched and linear alkyl esters (CAS No. 68515424) Hydrazine (CAS No. 7803578; 302012) 1methyl2pyrrolidone (CAS No. 872504) 1,2,3trichloropropane (CAS No. 96184) 1,2Benzenedicarboxylic acid, dic68branched alkyl esters, C7rich (CAS No. 71888896) Arsenic acid*** (CAS No. 7778394) Calcium arsenate*** (CAS No. 7778441) Trilead diarsenate*** (CAS No. 3687318) ( 1) Lead diazide, Lead azide*** (CAS No. 13424469) Lead styphnate*** (CAS No. 15245440) Lead dipicrate*** (CAS No. 6477641) Dichromium tris (chromate)*** (CAS No. 24613896) Potassium hydroxyoctaoxodizincatedi chromate*** (CAS No. 11103 869) 0.01 Classification ; ; MC2 ; ; ; ; ; ;
Page 5 of 12 2Methoxyaniline; oanisidine (CAS No. 90040) 1,2Dichloroethane (CAS No. 107062) Phenolphthalein (CAS No. 77098) Aluminosilicate, Refractory Ceramic Fibres oxides of aluminium and silicon are the main components present (in the fibres) within variable concentration ranges Zirconia Aluminosilicate, Refractory Ceramic Fibres oxides of aluminium, silicon and zirconium are the main components present (in the fibres) within variable concentration ranges 1,2dimethoxyethane; ethylene glycol dimethyl ether (EGDME) (CAS No. 110714) Formamide (CAS No. 75127) Pentazinc chromate octahydroxide*** (CAS No. 49663845) Formaldehyde, oligomeric reaction products with aniline (technical MDA) (CAS No. 25214704) Bis(2methoxyethyl) phthalate (CAS No. 117828) 4(1,1,3,3tetramethylbutyl) phenol, (4tertOctylphenol) (CAS No. 140 669) Bis(2methoxyethyl) ether (CAS No. 111966) N,Ndimethylacetamide (DMAC) (CAS No. 127195) 2,2'dichloro 4,4'methylenedianiline (MOCA) (CAS No. 101144) 1,2bis (2methoxyethoxy) ethane (TEGDME; triglyme) (CAS No. 112 492) Lead(II) bis(methanesulfonate)*** (CAS No. 17570762) TGIC (1,3,5tris(oxiranylmethyl) 1,3,5triazine2,4,6 (1H,3H,5H)trione) (CAS No. 2451629) βtgic (1,3,5tris [(2S and 2R)2,3epoxypropyl] 1,3,5triazine2,4,6 (1H,3H,5H)trione) (CAS No. 59653746) ( 3) 4,4'bis (dimethylamino) benzophenone (Michler's ketone) (CAS No. 90948) N,N,N',N'tetramethyl 4,4'methylenedianiline (Michler's base) (CAS No. 101611) Classification Equivalent concern MC2 MC2
Page 6 of 12 [4[4,4'bis(dimethylamino) benzhydrylidene] cyclohexa2,5dien1 ylidene] dimethylammonium chloride (C.I. Basic Violet 3) (CAS No. 548629) [with 0.1% of Michler's ketone or Michler's base] [4[[4anilino1naphthyl] [4(dimethylamino) phenyl] methylene] cyclohexa2,5dien1ylidene] dimethylammonium chloride (C.I. Basic Blue 26) (CAS No. 2580565) [with 0.1% of Michler's ketone or Michler's base] α,αbis[4(dimethylamino) phenyl]4 (phenylamino) naphthalene1 methanol (C.I. Solvent Blue 4) (CAS No. 6786830) [with 0.1% of Michler's ketone or Michler's base] Diboron trioxide*** (CAS No. 1303862) 4,4'bis (dimethylamino)4''(methylamino) trityl alcohol (CAS No. 561 411) [with 0.1% of Michler's ketone or Michler's base] Bis(pentabromophenyl) ether (DecaBDE) (CAS No. 1163195) Tricosafluorododecanoic acid (CAS No. 307551) Henicosafluoroundecanoic acid (CAS No. 2058948) Heptacosafluorotetradecanoic acid (CAS No. 376067) 4(1,1,3,3tetramethylbutyl) phenol, ethoxylated covering welldefined substances and UVCB substances, polymers and homologues 4Nonylphenol, branched and linear substances with a linear and/or branched alkyl chain with a carbon number of 9 covalently bound in position 4 to phenol, covering also UVCB and welldefined substances which include any of the individual isomers or a combination thereof Diazene1,2dicarboxamide (C,C'azodi(formamide)) (CAS No. 12377 3) Cyclohexane1,2dicarboxylic anhydride (HHPA), ciscyclohexane1,2 dicarboxylic anhydride, transcyclohexane1,2 dicarboxylic anhydride (Hexahydrophthalic anhydride HHPA) (CAS No. 85427, 13149003, 14166213) Hexahydromethylphathalic anhydride (CAS No. 25550510) Hexahydro4methylphathalic anhydride (CAS No. 19438609) Hexahydro1methylphathalic anhydride (CAS No. 48122141) Hexahydro3methylphathalic anhydride (CAS No. 57110299) Pentacosafluorotridecanoic acid (CAS No. PBT 72629948) Classification PBT PBT PBT PBT Equivalent concern Equivalent concern Equivalent concern Equivalent concern Equivalent concern
Page 7 of 12 Methoxy acetic acid (CAS No. 625456) 1,2Benzenedicarboxylic acid, dipentylester, branched and linear (CAS No. 84777060) Diisopentylphthalate (CAS No. 605505) Npentylisopentylphtalate (CAS No. 776297699) 1,2Diethoxyethane (CAS No. 629141) N,Ndimethylformamide; dimethyl formamide (CAS No. 68122) Dibutyltin dichloride (DBTC) (CAS No. 683181) Acetic acid, lead salt, basic*** (CAS No. 51404694) Trilead bis(carbonate) dihydroxide (basic lead carbonate)*** (CAS No. 1319466) Lead oxide sulfate*** (CAS No. 12036769) [Phthalato(2)] dioxotrilead*** (CAS No. 69011069) Dioxobis(stearato) trilead*** (CAS No. 12578120) Fatty acids, C1618, lead salts*** (CAS No. 91031628) Lead cyanamidate*** (CAS No. 20837869) Lead dinitrate*** (CAS No. 10099748) Lead oxide (lead monoxide)*** (CAS No. 1317368) Lead tetroxide (orange lead)*** (CAS No. 1314416) Pentalead tetraoxide sulphate*** (CAS No. 12065906) Silicic acid, lead salt*** (CAS No. 11120222) Sulfurous acid, lead salt, dibasic*** (CAS No. 62229087) Tetraethyllead*** (CAS No. 78002) Tetralead trioxide sulphate*** (CAS No. 12202174) Lead bis(tetrafluoroborate)*** (CAS No. 13814965) Lead titanium trioxide*** (CAS No. 12060003) Lead Titanium Zirconium Oxide*** (CAS No. 12626812) Pyrochlore, antimony lead yellow*** (CAS No. 8012008) Trilead dioxide phosphonate*** (CAS No. 12141207) Silicic acid, barium salt, leaddoped*** (CAS No. 68784758) Furan (CAS No. 110009) Substance Classification Name
Page 8 of 12 Propylene oxide; 1,2epoxypropane; methyloxirane (CAS No. 75569) ; MC2 Diethyl sulphate (CAS No. 64675) ; MC2 Dimethyl sulphate (CAS No. 77781) 3ethyl2methyl2(3methylbutyl)1,3oxazolidine (CAS No. 143860 042) Dinoseb (CAS No. 88857) 4,4'methylenediotoluidine (CAS No. 838880) 4,4'oxydianiline and its salts (CAS No. 101804) ; MC2 4Aminoazobenzene; 4Phenylazoaniline (CAS No. 60093) 4methylmphenylenediamine (2,4toluenediamine) (CAS No. 95807) 6methoxymtoluidine (pcresidine) (CAS No. 120718) Biphenyl4ylamine (CAS No. 92671) oaminoazotoluene (CAS No. 97563) otoluidine; 2Aminotoluene (CAS No. 95534) Nmethylacetamide (CAS No. 79163) 1bromopropane (CAS No. 106945) Pentadecafluorooctanoic acid (PFOA) (CAS No. 335671) TRC 1B & PBT Ammoniumpentadecafluorootanoate (APFO)*** (CAS No. 3825261) Cadmium (Cd) (CAS No. 7440439) 0.005 CC 1B & EQC Cadmium oxide*** (CAS No. 1306190) DPP (Dipentyl phthalate) (CAS No. 131180) 4Nonylphenol, branched and linear, ethoxylated [substances with a linear and/or branched alkyl chain with a carbon number of 9 covalently bound in position 4 to phenol, ethoxylated covering UVCB and welldefined substances, polymers and homologues, which include any of the individual isomers and/or combinations thereof] Dihexyl phthalate (CAS No. 84753) Disodium 3,3'[[1,1'biphenyl]4,4'diylbis(azo)]bis(4aminonaphthalene 1sulphonate) (C.I. Direct Red 28) (CAS No. 573580) Disodium 4amino3[[4'[(2,4diaminophenyl)azo][1,1'biphenyl]4 yl]azo] 5hydroxy6(phenylazo)naphthalene2,7disulphonate (C.I. Direct Black 38) (CAS No. 1937377) Substance Classification Name TRC 1B & PBT CC 1B & EQC TRC 1B EQC TRC 1B CC 1B CC 1B
Page 9 of 12 Imidazolidine2thione; 2imidazoline2thiol (CAS No. 96457) TRC 1B Trixylyl phosphate (CAS No. 25155231) TRC 1B Cadmium sulphide*** (CAS No. 1306236) Lead di(acetate)*** (CAS No. 301042) Classification CC 1B & EQC TRC 1A Note 1. mg/kg = ppm; 0.1wt% = 1000ppm 2. = not detected = below Reporting Limit 3. = Reporting Limit 4. " " = Not Regulated 5. (*) conc. of Sodium dichromate dihydrate (CAS No. 7789120) = conc. of sodium dichromate 1.1374 6. 7. 8. (**) The concentrations of abovementioned mixtures are evaluated per the gained composition rate between the selected marks and the mixtures. (*1) Oligomers of chromic acid and dichromic acid since the oligomers are made of the unknown amount of chromic acid or dichromic acid that results in no fixed molecular weight, therefore the monomer of chromic acid or dichromic acid is relevant and considered. (*2) Tetraboron disodium heptaoxide, hydrate Only anhydrous form of disodium tetraborate is relevant and considered according to ECHA explanation (Ref no. INC 000000032519). 9. F Parameter Conversion TablePlease refer to http//twap.sgs.com/sgsrsts/chn/downloadreach_tw.asp 10. ClassificationPlease refer to http//twap.sgs.com/sgsrsts/chn/downloadreach_tw.asp 11. *** The substance was calculated by the test results of Tributyl Tin, PFOA or element (Ex. Arsenic, Lead, Cr(VI), Boron, Cobalt, Barium, Cadmium respectively). The test result is given as Tributyl Tin (TBT) Arsenic (As) ( 2) Lead (Pb) Hexavalent Chromium Cr(VI) Boron (B) ( 2) Cobalt (Co) 0.005 0.005 0.005 0.005 0.005
Page 10 of 12 12. ( 1) Regarding the compound containing arsenic and lead, lead and arsenic are tested and respectively used for the calculation of the independent concentration of the compound containing arsenic and lead. The minimum value of the two independently calculated concentrations is used as the final concentration for the report. 13. ( 2) The extracted soluble Boron / Arsenic are detected by ICPAES. 14. ( 3) TGIC is a mixture and also contains βtgic. According to the ECHA's technical dossier the ratio of βtgic to TGIC is around 1 to 10. Therefore βtgic is issued based on the abovementioned ratio.
Page 11 of 12 Analytical flow chart of SVHC Name of the person who made measurement Jony Liu/Dorothy Chen/Ginny Huang Name of the person in charge of measurement Ray Chang Sampling Sample pretreated by acid digestion, solvent extraction Analysis was performed by ICPAES, UVVIS, GC/MS, LC/MS, GC/FPD, LC/MS/DAD Data
Page 12 of 12 #PIC * The tested sample / part is marked by an arrow if it's shown on the photo. * ** End of Report **