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Transcription:

MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Product Name CAS # Product Use Distributed by AIR WICK Stick Ups Air Freshener All Scents Mixture This MSDS is designed for workplace employees, emergency personnel and for other conditions and situations where there is a greater potential for large-scale or prolonged exposure, in accordance with requirements of the Canadian Workplace Hazardous Materials Information System (WHMIS). This MSDS is not applicable for consumer use of our products. For consumer use, all precautionary and first aid language is provided on the product label in accordance with the applicable government regulation. Air freshener Reckitt Benckiser (Canada) Inc. 1680 Tech Avenue Unit #2 Mississauga, ON L4W 5S9 In Case of Emergency: 1-800-338-6167 Transportation Emergencies: 24 Hour Number: North America: CHEMTREC: 1-800-424-9300 Outside North America: 1-703-527-3887 LEGEND Severe 4 Serious 3 Moderate 2 Slight 1 Minimal 0 HEALTH / 0 FLAMMABILITY 0 PHYSICAL HAZARD 0 PERSONAL PROTECTION A 0 0 0 2. Hazards Identification Emergency Overview Prolonged or frequent skin contact may cause an allergic reaction. Avoid contact with eyes, skin and clothing. Do not ingest. Intended for adult use only. Read precautions on back. Keep out of reach of children. Potential short term health effects Routes of exposure Eye, Skin contact, Inhalation, Ingestion. Eyes Avoid contact with eyes. Skin Prolonged or frequent skin contact may cause an allergic reaction. Inhalation Not toxic by inhalation. Ingestion Not orally toxic. Target organs Eyes. Chronic effects The finished product is not expected to have chronic health effects. Signs and symptoms May cause irritation. Potential environmental effects This product has not been tested. 3. Composition/Information on Ingredients Components CAS # Percent Proprietary Fragrance Oil Proprietary 5-10 #22024 Page: 1 of 6 Issue date 22-September-2013

4. First Aid Measures First aid procedures Eye contact Skin contact Inhalation Ingestion Notes to physician General advice If in eyes, IMMEDIATELY rinse with plenty of water. Remove contact lenses and continue to rinse eyes for at least 15 minutes. Obtain medical attention immediately. After contact with skin, wash immediately with plenty of water. If irritation persists, get medical attention. Wash hands after handling. Remove to fresh air. If symptoms develop move victim to fresh air. If symptoms persist, obtain medical attention. If swallowed, DO NOT induce vomiting. Call a physician or Poison Control Centre IMMEDIATELY. Rinse mouth with water. NEVER give an unconscious person anything to ingest. Symptoms may be delayed. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with eyes and skin. Keep out of reach of children. 5. Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighers Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Not flammable by WHMIS criteria. Water spray. Foam. Dry chemical. Carbon dioxide. Firefighters should wear full protective clothing including self contained breathing apparatus. May include and are not limited to: Oxides of carbon. 6. Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up Keep unnecessary personnel away. Do not touch or walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Do not discharge into lakes, streams, ponds or public waters. Advise authorities if product has penetrated drains, sewers or water pipes. Prevent entry into waterways, sewers, basements or confined areas. Stop leak if you can do so without risk. Pick up and discard. 7. Handling and Storage Handling Storage Ensure adequate ventilation. Avoid contact with eyes, skin and clothing. Use good industrial hygiene practices in handling this material. When using do not eat or drink. Wash hands after handling. Use only as directed. Do not ingest. Keep out of reach of children. Keep away from heat, open flames or other sources of ignition. Avoid storage under direct sunlight. Store in a cool dry place inaccessible to children and pets. #22024 Page: 2 of 6 Issue date 22-September-2013

8. Exposure Controls/Personal Protection Exposure limit values Engineering controls Personal protective equipment Eye / face protection Hand protection Skin and body protection Respiratory protection General hygiene considerations There are no established ACGIH exposure limits for the hazardous chemicals listed in section 3 of the MSDS. General ventilation normally adequate. Consult the product label for special protection or precautions that have been identified for using this product under directed consumer use conditions. The following recommendations are given for workplace employees, emergency personnel and for other conditions and situations where there is a greater potential for large-scale or prolonged exposure. Avoid contact with eyes. No special requirements under normal use conditions. No special requirements under normal use conditions. Emergency responders should wear impermeable gloves. As required by employer code. Usual safety precautions while handling the product will provide adequate protection against injury or irritation. Not normally required under normal use conditions. Handle in accordance with good industrial hygiene and safety practice. When using do not eat or drink. Wash hands before breaks and immediately after handling the product. 9. Physical and Chemical Properties Appearance Colour Form Odour Odour threshold Physical state ph Freezing point Boiling point Pour point Evaporation Rate Flash point Auto-ignition temperature Flammability Limits in Air, Upper, % by Volume Flammability Limits in Air, Lower, % by Volume Vapour pressure Vapour density Specific gravity Partition coefficient (n-octanol/water) Solubility (Water) Relative density Viscosity VOC Percent volatile Plastic cage containing a fragranced carragheenan gel Variable Gel Various Liquid. Insoluble 10. Stability and Reactivity Reactivity Possibility of hazardous reactions This product may react with strong oxidizing agents. Hazardous polymerization does not occur. #22024 Page: 3 of 6 Issue date 22-September-2013

Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Stable under recommended storage conditions. Do not mix with other chemicals. Keep from freezing and extreme heat. Keep away from moisture. Acids. Caustics. May include and are not limited to: Oxides of carbon. 11. Toxicological Information Toxicological data Components Species Proprietary Fragrance Oil (CAS Proprietary) LC50 LD50 Test results Effects of acute exposure Eye contact Skin contact Inhalation Ingestion Sensitisation Chronic effects Carcinogenicity Mutagenicity Reproductive effects Teratogenicity Name of Toxicologically Synergistic Products Avoid contact with eyes. Prolonged or frequent skin contact may cause an allergic reaction. Not toxic by inhalation. Not orally toxic. The finished product is not expected to have c hronic health effects. The finished product is not expected to have chr onic health effects. The finishe d pro duct is not e xpected to have c hronic health effects. The finishe d prod uct is n ot expecte d to have chr onic health effects. The finished product is not e xpected to hav e chronic health effects. The finished product is not expected to have chronic health effects. 12. Ecological Information Ecotoxicity Not ava ilable. Persistence and de gradability Not ava ilable. Bioaccumulation/accumulation Mobility in environmental media Environmental effects Aquatic toxicity Partition coefficient Chemical fate information 13. Disposal Considerations Disposal instructions Waste from residues / unused products Contaminated packaging UN/ID N.o. Dispose in accordance with all applicable regulations. Used gadget may be disposed of with normal household trash. 14. Transport Information U.S. Department of Transportation (DOT): Classification: Not regulated Proper shipping name U.S. DOT Hazard Class #22024 Page: 4 of 6 Issue date 22-September-2013

. Subsidiary Risk Packing group DOT RQ (lbs) ERG NO Transportation of Dangerous Goods (TDG - Canada): Classification: Not regulated Proper shipping name Status Packing group IMDG (Marine Transport): Classification: Not regulated Proper shipping name Class Subsidiary Risk Packing group IMDG Page Marine pollutant EMS MFAG Maximum Quantity IATA/ICAO (Air): Classification: Not regulated Proper shipping name Class Subsidiary Risk: Packing group Maximum Quantity 15. Regulatory Information Canadian federal regulations This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Product Registration: Product is compliant with CCCR regulatory guidelines; a specific registration is not required for this product. WHMIS Classification Exempt - Consumer product Inventory Status Country(s) or region Inventory Name On Inventory (Yes/No)* Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) Yes *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) 16. Other Information #22024 Page: 5 of 6 Issue date 22-September-2013

. Disclaimer This product should only be used as directed on the label and for the purpose intended. To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Further information AIR WICK Stick Ups Air Freshener Fresh Waters 153182v4.0 AIR WICK Stick Ups Air Freshener Lavender & Chamomile 105274v5.0 AIR WICK Stick Ups Air Freshener Sparkling Citrus 155991v4.0 Issue date 22-September-2013 Effective date 15-September-2013 Expiry Date 15-September-2016 Prepared by Reckitt Benckiser Regulatory Department Phone: 800-333-3899 Other Information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document. This MSDS conforms to the ANSI Z400.1/Z129.1-2010 Standard. #22024 Page: 6 of 6 Issue date 22-September-2013