MATERIAL SAFETY DATA SHEET 1 Product and Company Identification Product name CAS # Product use Manufacturer Pool Magic Plus Phosfree Mixture Water cleaning compound and Phosphate remover Natural Chemistry LP 4 Richards Ave Norwalk, CT 6854 US Phone: (8) 753-1233 Emergency Phone: CHEMTREC (8) 424-93 Emergency overview Potential short term health effects Routes of exposure Eyes Skin Target organs Chronic effects Signs and symptoms OSHA regulatory status 2 Hazards Identification CAUTION MAY CAUSE EYE IRRITATION MAY CAUSE SKIN IRRITATION Eye, Skin contact,, May cause irritation May cause irritation May cause respiratory tract irritation May cause stomach distress, nausea or vomiting Eyes Skin Potential environmental effects See section 12 Prolonged or repeated exposure can cause drying, defatting and dermatitis Symptoms may include redness, edema, drying, defatting and cracking of the skin Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 19112 3 Composition/Information on Ingredients Components CAS # Percent Lanthanum chloride 199-58-8 3-7 4 First Aid Measures First aid procedures Eye contact Skin contact Notes to physician General advice Flush with cool water Remove contact lenses, if applicable, and continue flushing Obtain medical attention if irritation persists Flush with cool water Wash with soap and water Obtain medical attention if irritation persists If symptoms develop move victim to fresh air If symptoms persist, obtain medical attention Do not induce vomiting Never give anything by mouth if victim is unconscious, or is convulsing Obtain medical attention Symptoms may be delayed If you feel unwell, seek medical advice (show the label where possible) Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves Show this safety data sheet to the doctor in attendance Avoid contact with eyes and skin Keep out of reach of children 5 Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Not flammable by WHMIS/OSHA criteria Dry chemical, CO2, water spray or regular foam #17836 Page: 1 of 5 3-April-214
Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment and precautions for firefighters Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Firefighters should wear full protective clothing including self contained breathing apparatus May include and are not limited to: Oxides of sulfur Hydrogen chloride 6 Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up Keep unnecessary personnel away Keep people away from and upwind of spill/leak Do not touch damaged containers or spilled material unless wearing appropriate protective clothing Do not discharge into lakes, streams, ponds or public waters Stop leak if you can do so without risk Prevent entry into waterways, sewers, basements or confined areas Before attempting clean up, refer to hazard data given above Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers Prevent large spills from entering sewers or waterways Contact emergency services and supplier for advice Never return spills to original containers for re-use 7 Handling and Storage Handling Storage Use good industrial hygiene practices in handling this material Avoid contact with eyes and skin Wash thoroughly after handling Keep out of reach of children Store in a closed container away from incompatible materials 8 Exposure Controls/Personal Protection Exposure limits Engineering controls Personal protective equipment Eye / face protection Hand protection Skin and body protection Respiratory protection General hygiene considerations Chemicals listed in section 3 that are not listed here do not have established limit values for ACGIH or OSHA PEL General ventilation normally adequate Wear safety glasses with side shields Rubber gloves Confirm with a reputable supplier first As required by employer code Where exposure guideline levels may be exceeded, use an approved NIOSH respirator Handle in accordance with good industrial hygiene and safety practice When using do not eat or drink Wash hands before breaks and immediately after handling the product Appearance Cloudy Color Amber Form Liquid Odor Slight Odor threshold Physical state Liquid ph 21-23 Freezing point Boiling point Pour point 9 Physical and Chemical Properties #17836 Page: 2 of 5 3-April-214
Evaporation rate Flash point Auto-ignition temperature Flammability limits in air, upper, % by volume Flammability limits in air, lower, % by volume Vapor pressure Vapor density Specific gravity 12-15 Partition coefficient (n-octanol/water) Solubility (water) Relative density Viscosity VOC Percent volatile Complete 86-88 lb/gal 1 Stability and Reactivity Reactivity Possibility of hazardous reactions Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products This product may react with strong alkalies Hazardous polymerization does not occur Stable under recommended storage conditions Do not mix with other chemicals Caustics May include and are not limited to: Oxides of sulfur Hydrogen chloride 11 Toxicological Information Toxicological data Components Species Lanthanum chloride (CAS 199-58-8) Acute Dermal LD5 LC5 Oral LD5 Rat Test Results 237 mg/kg Effects of acute exposure Eye contact Skin contact Sensitization Chronic effects Carcinogenicity Mutagenicity Reproductive effects Teratogenicity Name of Toxicologically Synergistic Products May cause irritation May cause irritation May cause respiratory tract irritation May cause stomach distress, nausea or vomiting Non-hazardous by WHMIS/OSHA criteria Non-hazardous by WHMIS/OSHA criteria Non-hazardous by WHMIS/OSHA criteria Non-hazardous by WHMIS/OSHA criteria Non-hazardous by WHMIS/OSHA criteria Non-hazardous by WHMIS/OSHA criteria #17836 Page: 3 of 5 3-April-214
Ecotoxicity See below Ecotoxicological data Components Lanthanum chloride (CAS 199-58-8) Aquatic Crustacea EC5 12 Ecological Information Species Water flea (Daphnia carinata) Test Results 43 mg/l, 48 hours Persistence and degradability Bioaccumulation / Accumulation Mobility in environmental media Environmental effects Aquatic toxicity Chemical fate information Disposal instructions Waste from residues / unused products Contaminated packaging 13 Disposal Considerations Dispose in accordance with all applicable regulations 14 Transport Information US Department of Transportation (DOT) Not regulated as dangerous goods Transportation of Dangerous Goods (TDG - Canada) Not regulated as dangerous goods 15 Regulatory Information Canadian federal regulations WHMIS status WHMIS classification WHMIS labeling This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations Controlled Class D - Division 2B Occupational Safety and Health Administration (OSHA) 29 CFR 19112 hazardous chemical US federal regulations Yes This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 19112 All components are on the US EPA TSCA Inventory List TSCA Section 12(b) Export Notification (4 CFR 77, Subpt D) Not regulated CERCLA Hazardous Substance List (4 CFR 324) Not listed Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (4 CFR 6813) Not regulated Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated #17836 Page: 4 of 5 3-April-214
CERCLA (Superfund) reportable quantity None Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Clean Water Act (CWA) State regulations Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Hazardous substance This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance Not listed US - Texas Effects Screening Levels: Listed substance Lanthanum chloride (CAS 199-58-8) US Massachusetts RTK - Substance List Not regulated US Pennsylvania RTK - Hazardous Substances Not regulated US Rhode Island RTK Not regulated Inventory status Listed Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) 16 Other Information No Yes Severe Serious Moderate Slight Minimal LEGEND 4 3 2 1 HEALTH FLAMMABILITY PHYSICAL HAZARD PERSONAL PROTECTION / 1 X 1 Disclaimer Effective date Expiry date Information contained herein was obtained from sources considered technically accurate and reliable While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document 3-April-214 15-November-213 15-November-216 Prepared by Dell Tech Laboratories, Ltd Phone: (519) 858-521 Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document This MSDS conforms to the ANSI Z41/Z1291-21 Standard #17836 Page: 5 of 5 3-April-214
MATERIAL SAFETY DATA SHEET Product Name CAS # Product Use Manufacturer 1 Product and Company Identification Metal Free - Canada Mixture Deactivates iron, copper, and other trace metals Prevents stains and water discoloration Natural Chemistry, LLC 4 Richards Ave Norwalk, CT 6854 US Phone: (8) 753-1233 Emergency Phone: CHEMTREC (8) 424-93 2 Hazards Identification Emergency Overview Potential short term health effects Routes of exposure Eyes Skin Target organs Chronic effects CAUTION MAY CAUSE EYE IRRITATION MAY CAUSE SKIN IRRITATION Eye, Skin contact,, May cause irritation May cause irritation May cause respiratory tract irritation May cause stomach distress, nausea or vomiting Eyes Skin Prolonged or repeated exposure can cause drying, defatting and dermatitis Signs and symptoms Symptoms may include redness, oedema, drying, defatting and cracking of the skin Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting Potential environmental effects See section 12 3 Composition/Information on Ingredients Ingredient(s) Citric acid CAS # 77-92-9 Percent 5-15 First aid procedures Eye contact Skin contact Notes to physician General advice Flammable properties Extinguishing media Suitable extinguishing media 4 First Aid Measures Flush with cool water Remove contact lenses, if applicable, and continue flushing Obtain medical attention if irritation persists Flush with cool water Wash with soap and water Obtain medical attention if irritation persists If symptoms develop move victim to fresh air If symptoms persist, obtain medical attention Do not induce vomiting Never give anything by mouth if victim is unconscious, or is convulsing Obtain medical attention Symptoms may be delayed If you feel unwell, seek medical advice (show the label where possible) Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves Show this safety data sheet to the doctor in attendance Avoid contact with eyes and skin Keep out of reach of children 5 Fire-fighting Measures Not flammable by WHMIS criteria Dry chemical Carbon dioxide Water spray Foam #17282 Page 1 of 5 7-Feb-213
Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighers Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Firefighters should wear full protective clothing including self contained breathing apparatus May include and are not limited to: Oxides of carbon Oxides of nitrogen 6 Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up Handling Storage Exposure limit values Ingredient(s) Keep unnecessary personnel away Do not touch or walk through spilled material Do not touch damaged containers or spilled material unless wearing appropriate protective clothing Keep people away from and upwind of spill/leak Do not discharge into lakes, streams, ponds or public waters Stop leak if you can do so without risk Prevent entry into waterways, sewers, basements or confined areas Before attempting clean up, refer to hazard data given above Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers Prevent large spills from entering sewers or waterways Contact emergency services and supplier for advice Never return spills in original containers for re-use 7 Handling and Storage Use good industrial hygiene practices in handling this material Avoid contact with eyes and skin Wash thoroughly after handling Keep out of reach of children Store in a closed container away from incompatible materials 8 Exposure Controls / Personal Protection Exposure limit values Citric acid Engineering controls Personal protective equipment Eye/Face protection Hand protection Skin and body protection Respiratory protection ACGIH-TLV TWA: 1 mg/m3 General ventilation normally adequate Wear safety glasses with side shields Rubber gloves Confirm with a reputable supplier first As required by employer code Where exposure guideline levels may be exceeded, use an approved NIOSH respirator General hygiene considerations Handle in accordance with good industrial hygiene and safety practice When using do not eat or drink Wash hands before breaks and immediately after handling the product Appearance Colour Form Odour Odour threshold Physical state 9 Physical and Chemical Properties Clear Colourless Liquid Mild Liquid ph 625-635 Freezing point #17282 Page 2 of 5 7-Feb-213
Boiling point Pour point Evaporation Rate Flash point Auto-ignition temperature Flammability limits in air, lower, % by volume None Not applicable Not applicable Flammability Limits in Air, Upper, % Not applicable by Volume Vapour pressure Vapour density Specific gravity 19-111 Relative density 914-918 Octanol/water coefficient 1 Stability and Reactivity Reactivity Possibility of hazardous reactions Chemical stability Conditions to avoid Incompatible materials None known Hazardous polymerisation does not occur Stable under recommended storage conditions Do not mix with other chemicals Caustics Oxidizers Reducing agents Hazardous decomposition products May include and are not limited to: Oxides of carbon Oxides of nitrogen 11 Toxicological Information Component analysis - LC5 Ingredient(s) Citric acid Component analysis - Oral LD5 Ingredient(s) Citric acid Effects of acute exposure Eye Skin Sensitisation Chronic effects Carcinogenicity Mutagenicity Reproductive effects Teratogenicity Name of Toxicologically Synergistic Products LC5 LD5 54 mg/kg mouse; 3 mg/kg rat May cause irritation May cause irritation May cause respiratory tract irritation May cause stomach distress, nausea or vomiting Non-hazardous by WHMIS criteria Non-hazardous by WHMIS criteria Non-hazardous by WHMIS criteria Non-hazardous by WHMIS criteria Non-hazardous by WHMIS criteria Non-hazardous by WHMIS criteria 12 Ecological Information Ecotoxicity Components of this product have been identified as having potential environmental concerns Ecotoxicity - Freshwater Fish - Acute Toxicity Data Citric acid 77-92-9 96 Hr LC5 Lepomis macrochirus: 1516 mg/l [static] Ecotoxicity - Water Flea - Acute Toxicity Data Citric acid 77-92-9 72 Hr EC5 Daphnia magna: 12 mg/l Persistence and degradability #17282 Page 3 of 5 7-Feb-213
Bioaccumulation/accumulation Mobility in environmental media Environmental effects Aquatic toxicity Partition coefficient Chemical fate information Other adverse effects Disposal instructions Waste from residues / unused products Contaminated packaging 13 Disposal Considerations Review federal, provincial, and local government requirements prior to disposal 14 Transport Information US Department of Transportation (DOT) Not regulated as dangerous goods Transportation of Dangerous Goods (TDG - Canada) Not regulated as dangerous goods 15 Regulatory Information Canadian federal regulations This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations Canada - WHMIS - Ingredient Disclosure List Citric acid 77-92-9 1 % WHMIS classification Class D - Division 2B WHMIS status WHMIS labeling Controlled Inventory Status Country(s) or region Canada Canada Inventory Name Domestic Substances List (DSL) Non-Domestic Substances List (NDSL) On Inventory (Yes/No)* Yes No A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) 16 Other Information LEGEND HMIS/NFPA Severe Serious Moderate Slight Minimal 4 3 2 1 Health / Flammability Physical Hazard Personal Protection 1 X 1 #17282 Page 4 of 5 7-Feb-213
Disclaimer Effective Date Expiry Date Information contained herein was obtained from sources considered technically accurate and reliable While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document 7-Feb-213 15-Feb-213 15-Feb-216 Prepared by Dell Tech Laboratories Ltd (519) 858-521 Other Information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document This MSDS conforms to the ANSI Z41/Z1291-21 Standard #17282 Page 5 of 5 7-Feb-213