MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Product name CAS # Product use Manufacturer Rid O Rust Rust Preventer (2X Concentrated) Mixture Rust Stain Preventer Pro Products LLC 721 Engle Road Fort Wayne, IN 4684-5875 US Phone 26-483-2519 Emergency Phone: 1-8-424-93 (CHEMTREC) Severe Serious Moderate Slight Minimal LEGEND 4 3 2 1 HEALTH FLAMMABILITY PHYSICAL HAZARD PERSONAL PROTECTION / 1 X 1 Emergency overview Potential short term health effects Routes of exposure Eyes Skin Ingestion Target organs Chronic effects Signs and symptoms OSHA regulatory status 2. Hazards Identification CAUTION CAUSES EYE IRRITATION. MAY CAUSE SKIN IRRITATION. Corrosive to metals. Eye, Skin contact,, Ingestion. Causes irritation. May cause irritation. Potential environmental effects See section 12. May cause respiratory tract irritation. May cause stomach distress, nausea or vomiting. Eyes. Skin. Respiratory system. Prolonged or repeated exposure can cause drying, defatting and dermatitis. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 191.12. 3. Composition/Information on Ingredients Components CAS # Percent Citric acid 1-Hydroxyethylidene-1, 1-diphosphonic acid 4. First Aid Measures 77-92-9 15-4 289-21-4 1-3 First aid procedures Eye contact Skin contact Ingestion Immediately flush with cool water. Remove contact lenses, if applicable, and continue flushing for 15 minutes. Obtain medical attention immediately. Flush with cool water. Wash with soap and water. Obtain medical attention if irritation persists. If symptoms develop move victim to fresh air. If symptoms persist, obtain medical attention. Do not induce vomiting. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Never give anything by mouth if victim is unconscious, or is convulsing. Obtain medical attention. #2456 Page: 1 of 6
Notes to physician General advice Symptoms may be delayed. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with eyes and skin. Keep out of reach of children. 5. Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment and precautions for firefighters Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Not flammable by WHMIS/OSHA criteria. Dry chemical, CO2, water spray or regular foam. Firefighters should wear full protective clothing including self contained breathing apparatus. May include and are not limited to: Oxides of carbon. Oxides of nitrogen. Oxides of phosphorus. 6. Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Do not discharge into lakes, streams, ponds or public waters. Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confined areas. Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Never return spills to original containers for re-use. 7. Handling and Storage Handling Storage Use good industrial hygiene practices in handling this material. Do not get in eyes, on skin or on clothing. Use only with adequate ventilation. Avoid breathing vapors or mists of this product. Keep container tightly closed. Wash thoroughly after handling. Store in a closed container away from incompatible materials. Keep out of the reach of children. Exposure limits Engineering controls Personal protective equipment Eye / face protection Hand protection 8. Exposure Controls/Personal Protection Chemicals listed in section 3 that are not listed here do not have established limit values for ACGIH or OSHA PEL. Use only under good ventilation conditions or with respiratory protection. Wear safety glasses with side shields. Rubber gloves. Confirm with a reputable supplier first. Skin and body protection As required by employer code. Respiratory protection General hygiene considerations Where exposure guideline levels may be exceeded, use an approved NIOSH respirator. Use good industrial hygiene practices in handling this material. When using do not eat or drink. Wash hands before breaks and immediately after handling the product. #2456 Page: 2 of 6
Appearance Color Form Odor Odor threshold Physical state Clear Blue Liquid ph < 2 Freezing point Boiling point Pour point Evaporation rate Flash point Auto-ignition temperature Flammability limits in air, upper, % by volume Flammability limits in air, lower, % by volume Vapor pressure Vapor density Liquid. Specific gravity 1.16 Partition coefficient (n-octanol/water) Solubility (water) Relative density Viscosity VOC Percent volatile 9.66 lb/gal 9. Physical and Chemical Properties 1. Stability and Reactivity Reactivity Possibility of hazardous reactions Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Reacts vigorously with alkaline material. This product may react with reducing agents. Hazardous polymerization does not occur. Stable under recommended storage conditions. Do not mix with other chemicals. Caustics. Reducing agents. Oxidizers. May include and are not limited to: Oxides of carbon. Oxides of nitrogen. Oxides of phosphorus. 11. Toxicological Information Toxicological data Components Species 1-Hydroxyethylidene-1, 1-diphosphonic acid (CAS 289-21-4) Dermal LD5 Rabbit Oral LD5 Rat Test Results >= 8 mg/kg 18 mg/kg #2456 Page: 3 of 6
Components Citric acid (CAS 77-92-9) Dermal LD5 LC5 Oral LD5 Species Mouse Rat Test Results 54 mg/kg 3 mg/kg Effects of acute exposure Eye contact Skin contact Ingestion Sensitization Chronic effects Carcinogenicity Mutagenicity Reproductive effects Teratogenicity Name of Toxicologically Synergistic Products Causes irritation. May cause irritation. May cause respiratory tract irritation. May cause stomach distress, nausea or vomiting. Not classified or listed by IARC, NTP, OSHA and ACGIH. 12. Ecological Information Ecotoxicity See below Ecotoxicological data Components Species 1-Hydroxyethylidene-1, 1-diphosphonic acid (CAS 289-21-4) Crustacea EC5 Daphnia Citric acid (CAS 77-92-9) Crustacea EC5 Daphnia magna Aquatic Fish LC5 Bluegill (Lepomis macrochirus) Test Results 527 mg/l, 48 Hours 12 mg/l, 72 hr 1516 mg/l, 96 hr Persistence and degradability Bioaccumulation / Accumulation Mobility in environmental media Environmental effects Aquatic toxicity Partition coefficient Chemical fate information Disposal instructions Waste from residues / unused products 13. Disposal Considerations Dispose in accordance with all applicable regulations. #2456 Page: 4 of 6
Contaminated packaging 14. Transport Information U.S. Department of Transportation (DOT) Basic shipping requirements: UN number UN3265 Proper shipping name Corrosive liquid, acidic, organic, n.o.s. (1,2,3-propanetricarboxylic acid, 2-hydroxy-) Hazard class 8 Packing group III Special provisions IB3, T7, TP1, TP28 Packaging exceptions 154 Packaging non bulk 23 Packaging bulk 241 ERG code 153 Transportation of Dangerous Goods (TDG- Canada) Basic shipping requirements: UN number UN3265 Proper shipping name CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (1,2,3-propanetricarboxylic acid, 2-hydroxy-) Hazard class 8 Packing group III Special provisions 16 DOT TDG Canadian federal regulations Canada WHMIS Ingredient Disclosure: Threshold limits WHMIS status 15. Regulatory Information This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Citric acid (CAS 77-92-9) 1 % WHMIS classification WHMIS labeling Controlled Class D - Division 2B, Class E - Corrosive Material Occupational Safety and Health Administration (OSHA) 29 CFR 191.12 hazardous chemical Yes #2456 Page: 5 of 6
US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 191.12. TSCA Section 12(b) Export Notification (4 CFR 77, Subpt. D) CERCLA Hazardous Substance List (4 CFR 32.4) Not listed. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (4 CFR 68.13) Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List CERCLA (Superfund) reportable quantity None Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories State regulations Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance Not listed. US - Texas Effects Screening Levels: Listed substance 1-Hydroxyethylidene-1, 1-diphosphonic acid (CAS 289-21-4) Citric acid (CAS 77-92-9) US. Massachusetts RTK - Substance List US. Pennsylvania RTK - Hazardous Substances US. Rhode Island RTK Inventory status Listed. Listed. Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada United States & Puerto Rico Non-Domestic Substances List (NDSL) Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) Disclaimer Issue date Effective date Expiry date 16. Other Information The data contained in this material safety data sheet was obtained from sources that were technically accurate, reliable, and state of the art when this document was prepared. If data was unavailable to complete certain sections, the absence of that data is identified in this document. Because the supplier cannot know the exact circumstances during actual use of this product, other hazards, exposure scenarios, disposal considerations, and regulations may apply and it is the responsibility of the user to read and understand the product label and this document before use. Do not use the product for purposes other than those stated in Section 1. 5-August-214 31-July-214 31-July-217 Prepared by Dell Tech Laboratories Ltd. Phone: (519) 858-521 Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document. This MSDS conforms to the ANSI Z4.1/Z129.1-21 Standard. Redbook revision # 1, 7/25/14 No Yes #2456 Page: 6 of 6