MATERIAL SAFETY DATA SHEET Product Name CAS # 1 Product and Company Identification CLEARASIL DAILY CLEAR Daily Facial Scrub Mixture This MSDS is designed for workplace employees, emergency personnel and for other conditions and situations where there is a greater potential for large-scale or prolonged exposure, in accordance with requirements of the US Government's Occupational Safety and Health Administration (OSHA) This MSDS is not applicable for consumer use of our products For consumer use, all precautionary and first aid language is provided on the product label in accordance with the applicable government regulation Product Use Distributed by LEGEND HMIS/NFPA Severe Serious 4 3 Moderate 2 Slight 1 Minimal 0 Emergency overview Exfoliating scrub Reckitt Benckiser Morris Corporate Center IV 399 Interpace Parkway PO Box 225 Parsippany, NJ 07054-0225 In Case of Emergency: 1-800-338-6167 Transportation Emergencies: 24 Hour Number: North America: CHEMTREC: 1-800-424-9300 Outside North America: 1-703-527-3887 Health / 2 Flammability 0 Physical Hazard 0 Personal Protection 2 Hazards Identification 0 2 0 This product is regulated by the US FDA as a personal care cosmetic Warnings: For external use only When using this product, avoid contact with the eyes If product gets into the eyes rinse thoroughly with water Skin irritation and dryness is more likely to occur if you use another topical acne medication at the same time If irritation occurs, only use one topical acne medication at a time Limit use to the face and neck If swallowed, get medical help or contact a Poison Control Center right away Potential short term health effects Routes of exposure Eyes Skin Inhalation Ingestion Target organs Chronic effects Signs and symptoms OSHA Regulatory Status KEEP OUT OF REACH OF CHILDREN Eye, Skin contact, Inhalation, Ingestion Avoid contact with eyes May cause eye irritation upon direct contact with the eyes Skin irritation and dryness is more likely to occur if you use another topical acne medication at the same time Health injuries are not known or expected under normal use Ingestion may cause gastrointestinal irritation Eyes Skin Respiratory system s The finished product is not expected to have chronic health effects Symptoms may include redness, edema, drying, defatting and cracking of the skin This acne product is in compliance with Title 21 of the Code of Federal Regulations, Part 207 and meets the regulatory requirements outlined in the OTC Monograph under 21 CFR Part 333D #23263 Page 1 of 7 Issue date 07-Nov-2012
Potential environmental effects Components of this product have been identified as having potential environmental concerns 3 Composition / Information on Ingredients Ingredient(s) CAS # Percent 68585-34-2 61789-40-0 69-72-7 10-20 1-25 1-25 First aid procedures Eye contact Skin contact Inhalation Ingestion Notes to physician General advice 4 First Aid Measures If product gets into the eyes, rinse thoroughly with water Remove contact lenses if present Flush immediately with large amounts of water, especially under lids for at least 15 minutes If irritation or other effects persist, obtain medical treatment Stop use and ask a doctor if skin irritation develops If irritation occurs wash thoroughly with soap and water Remove contaminated clothing and consult a physician Remove to fresh air if inhalation causes eye watering, headaches, dizziness or other discomfort If swallowed, get medical help or contact a poison control center right away If swallowed in quantity DO NOT INDUCE VOMITING! Rinse mouth thoroughly and seek medical attention immediately Symptoms may be delayed If you feel unwell, seek medical advice (show the label where possible) Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves Show this safety data sheet to the doctor in attendance Avoid contact with eyes Keep out of reach of children 5 Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighters Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Personal precautions Environmental precautions Methods for containment Methods for cleaning up Not flammable by OSHA criteria Dry chemical Carbon dioxide Water spray Firefighters should wear full protective clothing including self contained breathing apparatus May include and are not limited to: Oxides of carbon 6 Accidental Release Measures Do not touch or walk through spilled material Do not touch damaged containers or spilled material unless wearing appropriate protective clothing Keep unnecessary personnel away Do not discharge into lakes, streams, ponds or public waters Advise authorities if product has penetrated drains, sewers or water pipes Stop leak if you can do so without risk Prevent entry into waterways, sewers, basements or confined areas Before attempting clean up, refer to hazard data given above Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers Prevent large spills from entering sewers or waterways Contact emergency services and supplier for advice Never return spills to original containers for re-use #23263 Page 2 of 7 Issue date 07-Nov-2012
Handling Storage 7 Handling and Storage Ensure adequate ventilation Use good industrial hygiene practices in handling this material When using do not eat or drink Keep container tightly closed Avoid contact with eyes Wash hands after handling Keep out of reach of children Store in a cool, dry place Allowances for excursions above 30 C: 60 C - Not permitted 50 C - Not more than 5 days 40 C - Not permitted Exposure limits Ingredient(s) Allowances for excursions below 0 C: Do not store below -20 C 8 Exposure Controls / Personal Protection Exposure Limits ACGIH-TLV OSHA-PEL ACGIH-TLV OSHA-PEL Engineering controls Personal protective equipment ACGIH-TLV OSHA-PEL Not normally required if good ventilation is maintained Consult the product label for special protection or precautions that have been identified for using this product under directed consumer use conditions The following recommendations are given for workplace employees, emergency personnel and for other conditions and situations where there is a greater potential for large-scale or prolonged exposure Eye / face protection Hand protection Skin and body protection Respiratory protection Not normally required Emergency responders should wear full eye and face protection Not required Emergency responders should wear impermeable gloves As required by employer code Not normally required if good ventilation is maintained General hygiene considerations Handle in accordance with good industrial hygiene and safety practice When using do not eat or drink Avoid contact with eyes Wash hands after handling 9 Physical and Chemical Properties Appearance Color Form Odor Odor threshold Gel with blue exfoliating particles Pale blue Liquid Green, Melon, Floral, Aromatic #23263 Page 3 of 7 Issue date 07-Nov-2012
Physical state Liquid ph 35-45 Melting point Freezing point Boiling point Pour point Evaporation rate Flash point Auto-ignition temperature Flammability limits in air, lower, % by volume Flammability limits in air, upper, % by volume Vapor pressure Vapor density Specific gravity Octanol/water coefficient Solubility (H2O) Viscosity > 20300 F (> 95 C) > 093 G/mL Soluble 10,000-30,000 Cps (LV #4, 12 rpm, 60 seconds) 10 Stability and Reactivity Reactivity This product may react with strong oxidizing agents Possibility of hazardous reactions Hazardous polymerization does not occur Chemical stability Stable under recommended storage conditions Conditions to avoid Do not mix with other chemicals Incompatible materials Acids Oxidizers Hazardous decomposition products May include and are not limited to: Oxides of carbon Component analysis - LC50 Ingredient(s) 11 Toxicological Information LC50 Component analysis - Oral LD50 Ingredient(s) Effects of acute exposure Eye Skin Inhalation Ingestion Sensitization Chronic effects Carcinogenicity Mutagenicity Reproductive effects Teratogenicity LD50 2700 mg/kg rat 891 mg/kg rat; 400 mg/kg cat; 480 mg/kg mouse 1700 mg/kg rat Avoid contact with eyes May cause eye irritation upon direct contact with the eyes Skin irritation and dryness is more likely to occur if you use another topical acne medication at the same time Health injuries are not known or expected under normal use Ingestion may cause gastrointestinal irritation The finished product is not expected to have chronic health effects The finished product is not expected to have chronic health effects The finished product is not expected to have chronic health effects The finished product is not expected to have chronic health effects The finished product is not expected to have chronic health effects The finished product is not expected to have chronic health effects #23263 Page 4 of 7 Issue date 07-Nov-2012
Name of Toxicologically Synergistic Products Ecotoxicity 12 Ecological Information Components of this product have been identified as having potential environmental concerns Ecotoxicity - Freshwater Algae - Acute Toxicity Data 61789-40-0 72 Hr EC50 Desmodesmus subspicatus: 10-100 mg/l; 96 Hr EC50 Desmodesmus subspicatus: 055 mg/l Ecotoxicity - Freshwater Fish - Acute Toxicity Data 61789-40-0 96 Hr LC50 Brachydanio rerio: 10-100 mg/l; 96 Hr LC50 Brachydanio rerio: 2 mg/l 69-72-7 [semi-static] 48 Hr LC50 Leuciscus idus: 90 mg/l [static] Ecotoxicity - Water Flea - Acute Toxicity Data 61789-40-0 48 Hr EC50 Daphnia magna: 65 mg/l 69-72-7 24 Hr EC50 Daphnia magna: 105 mg/l; 48 Hr EC50 Daphnia magna: 870 mg/l [Static] Persistence / degradability Bioaccumulation / accumulation Mobility in environmental media Environmental effects Aquatic toxicity Partition coefficient Chemical fate information Disposal instructions Waste from residues / unused products Contaminated packaging 13 Disposal Considerations Review federal, state and local government requirements prior to disposal Do not dispose of large quantities down the drain 14 Transport Information UN/ID No US Department of Transportation (DOT): Classification: Not regulated Proper shipping name US DOT Hazard Class Subsidiary Risk Packing group DOT RQ (lbs) ERG NO #23263 Page 5 of 7 Issue date 07-Nov-2012
Transportation of Dangerous Goods (TDG - Canada): Classification: Not regulated Proper shipping name Status Packing group IMDG (Marine Transport): Classification: Not regulated Proper shipping name Class Subsidiary Risk Packing group IMDG Page Marine pollutant EMS MFAG Maximum Quantity IATA/ICAO (Air): Classification: Not regulated Proper shipping name Class Subsidiary Risk: Packing group Maximum Quantity 15 Regulatory Information Occupational Safety and Health Administration (OSHA) 29 CFR 19101200 hazardous Yes chemical US Federal regulations This acne product is in compliance with Title 21 of the Code of Federal Regulations, Part 207 and meets the regulatory requirements outlined in the OTC Monograph under 21 CFR Part 333D All components of this product are either on the Toxic Substances Control Act list (TSCA) or exempt US - CAA (Clean Air Act) - HON Rule - SOCMI Chemicals 69-72-7 Group III US - CAA (Clean Air Act) - Volatile Organic Compounds (VOCs) in SOCMI 69-72-7 Present #23263 Page 6 of 7 Issue date 07-Nov-2012
CERCLA (Superfund) reportable quantity Phosphoric acid: 50000000 Sodium hydroxide: 10000000 Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Section 302 extremely hazardous substance Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No No Section 311 hazardous chemical Yes Clean Water Act (CWA) Hazardous substance State regulations This product is not subject to warning labeling under the California Proposition 65 regulation Inventory status Country(s) or region Inventory name On inventory (yes/no)* United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory No A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) Disclaimer 16 Other Information This product should only be used as directed on the label and for the purpose intended To the best of our knowledge, the information contained herein is accurate However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein Final determination of suitability of any material is the sole responsibility of the user All materials may present unknown hazards and should be used with caution Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist Further information CLEARASIL DAILY CLEAR Daily Facial Scrub, 5 fl oz - 0137094 v30 Issue date 07-Nov-2012 Effective date 01-Nov-2012 Prepared by Reckitt Benckiser Regulatory Department 800-333-3899 Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document This MSDS conforms to the ANSI Z4001/Z1291-2010 Standard #23263 Page 7 of 7 Issue date 07-Nov-2012