Address: Attn: Client: Tel:+ Fax: + e-mail: Code: The following sample was (were) submitted and identified by the client as: Sample description: RAW MATERIAL Batch No.: Job no Report No.: 17-010611 Reference No.: NARANJA FELPA Composition indicated: UNKNOWN Serie : Receiving Date: 06/07/2017 Test Start Date: 08/07/2017 Test End Date: 19/07/2017 SOP description s * SOP 25 - Colour fastness to artificial light for fabrics - Xenom lamp * SOP 52-Determination of arylamines for natural samples * SOP 52-Determination of arylamines for synthetic samples SOP 58-Determination of formaldehyde by photometric in textile samples (DC) * SOP 70-Determination of allergenous dyes SOP 55-Determination of cadmium and lead in textile samples by ICP-MS * SOP 20-Determination of the content of phenols SOP 60-Colour Fastness to Rubbing (Direct Contact) SOP 62-Colour Fastness to Acid perspiration (Direct contact) SOP 62-Colour Fastness to Alkaline perspiration (Direct contact) SOP 13 - Colour fastness to domestic washing C06 *SUMMARY OF TEST CONCLUSIONS Sample Tested Pag. 1 of 11
* 250 SOP 25 - Colour fastness to artificial light for fabrics - Xenom lamp 5 S-170708-00138 S-170708-00138 Colour change Blue Scale 7 Hours test process 30 - Applied standard based in UNE-EN ISO 105-B02:2001 (Equivalent to ISO 105-B02:1994) - NA = not applicable Note 1: Used Blue scale from 1 to 8. * 520 SOP 52-Determination of arylamines for natural samples Composite Sample S-170711-00743 (N = 6) 6 S-170711-00669 S-170711-00743 0-dianisidine (3,3-dimethoxybenzidine) 119-90-4 n.d. 2,4,5-trimethylaniline 137-17-7 n.d. 2,4-Diaminotoluene 95-80-7 n.d. 2,4-dimethylaniline 95-68-1 n.d. 2,6-dimethylaniline 87-62-7 n.d. 2-Nafthylamine 91-59-8 n.d. 3,3-dichlorobenzidine 91-94-1 n.d. 3,3-dimethylbenzidine 119-93-7 n.d. 4,4-Diaminediphenyl sulfide 139-65-1 n.d. 4,4-Oxydianiline 101-80-4 n.d. 4,4-diaminophenylmethane 101-77-9 n.d. 4,4-methylen-bis-(2-Chloroaniline) 101-14-4 n.d. 4,4-methylendi-o-toluidine 838-88-0 n.d. 4-Aminoazobenzene 60-09-3 n.d. Pag. 2 of 11
S-170711-00743 4-Aminobiphenyl 92-67-1 n.d. 4-Chloro-o-toluidine 95-69-2 n.d. 4-Chloroaniline 106-47-8 n.d. 4-Methoxy-m-phenilenediamine 615-05-4 n.d. 5-Nitro-o-toluidine 99-55-8 n.d. 6-methoxy-m-toluidine 120-71-8 n.d. Benzidine 92-87-5 n.d. o-aminoazotoluene 97-56-3 n.d. o-anisidine 90-04-0 n.d. o-toluidine 95-53-4 n.d. - Applied standard UNE-EN 14362-1:2012 - Requirement by the client= 20 mg Kg-1 for textile 30 mg Kg-1 for leather goods - (Nº=..) = number of subsamples included. If N>number of subsamples visible, in this composite sample it mixed different references by customer indications. Report Unit: mg Kg-1 n.d.= not detected (<MDL) MDL (Method Detection Limit )= 1,0 mg Kg-1 * 522 SOP 52-Determination of arylamines for synthetic samples Composite Sample S-170711-00747 (N = 5) 7 S-170711-00670 S-170711-00747 0-dianisidine (3,3-dimethoxybenzidine) 119-90-4 n.d. 2,4,5-trimethylaniline 137-17-7 n.d. 2,4-Diaminotoluene 95-80-7 n.d. 2,4-dimethylaniline 95-68-1 n.d. 2,6-dimethylaniline 87-62-7 n.d. 2-Nafthylamine 91-59-8 n.d. Pag. 3 of 11
S-170711-00747 3,3-dichlorobenzidine 91-94-1 n.d. 3,3-dimethylbenzidine 119-93-7 n.d. 4,4-Diaminediphenyl sulfide 139-65-1 n.d. 4,4-Oxydianiline 101-80-4 n.d. 4,4-diaminophenylmethane 101-77-9 n.d. 4,4-methylen-bis-(2-Chloroaniline) 101-14-4 n.d. 4,4-methylendi-o-toluidine 838-88-0 n.d. 4-Aminoazobenzene 60-09-3 n.d. 4-Aminobiphenyl 92-67-1 n.d. 4-Chloro-o-toluidine 95-69-2 n.d. 4-Chloroaniline 106-47-8 n.d. 4-Methoxy-m-phenilenediamine 615-05-4 n.d. 5-Nitro-o-toluidine 99-55-8 n.d. 6-methoxy-m-toluidine 120-71-8 n.d. Benzidine 92-87-5 n.d. o-aminoazotoluene 97-56-3 n.d. o-anisidine 90-04-0 n.d. o-toluidine 95-53-4 n.d. - Applied standard UNE-EN 14362-1:2012 - Requirement by the client= 20 mg Kg-1 for textile 30 mg Kg-1 for leather goods - (Nº=..) = number of subsamples included. If N>number of subsamples visible, in this composite sample it mixed different references by customer indications. Report Unit: mg Kg-1 n.d.= not detected (<MDL) MDL (Method Detection Limit )= 1,0 mg Kg-1 582 SOP 58-Determination of formaldehyde by photometric in textile samples (DC) Composite Sample S-170711-00745 (N = 6) 8 S-170711-00671 Pag. 4 of 11
Formaldehyde 50-00-00 S-170711-00745 - Applied standard ITX-GB/T 2912.1/2012 - Requirement by the client, products for over 3 years= 75 mg Kg-1 for items of direct contact 300 mg Kg-1 garment with indirect contact - (Nº=..) = number of subsamples included. If N>number of subsamples visible, in this composite sample it mixed different references by customer indications. Report Unit: mg Kg-1 n.d.= not detected = <LOQ LOQ (Limit of quantification )= 2,0 mg Kg-1 * 700 SOP 70-Determination of allergenous dyes 9 S-170711-00672 S-170711-00672 Disperse Blue 1 2475-45-8 n.d. Disperse Blue 102 12222-97-8 n.d. Disperse Blue 106 12223-01-7 n.d. Disperse Blue 124 61951-51-7 n.d. Disperse Blue 26 3860-63-7 n.d. Disperse Blue 3 2475-46-9 n.d. Disperse Blue 35 56524-77-7 n.d. Disperse Blue 7 3179-90-6 n.d. Disperse Brown 1 23355-64-8 n.d. Disperse Orange 1 2581-69-3 n.d. Disperse Orange 3 730-40-5 n.d. Pag. 5 of 11
S-170711-00672 Disperse Orange 37 13301-61-6 n.d. Disperse Red 1 2872-52-8 n.d. Disperse Red 11 2872-48-2 n.d. Disperse Red 17 3179-89-3 n.d. Disperse Yellow 1 119-15-3 n.d. Disperse Yellow 3 2832-40-8 n.d. Disperse Yellow 39 12236-29-2 n.d. Disperse Yellow 49 54824-37-2 n.d. Disperse Yellow 9 6373-73-5 n.d. - Applied standard DIN 54231 - Requirement by the client= 50,0 mg Kg-1 Report Unit: mg Kg-1 n.d.= not detected (<MDL) MDL (Method Detection Limit )= 1,0 mg Kg-1 550 SOP 55-Determination of cadmium and lead in textile samples by ICP-MS Composite Sample S-170711-00751 (N = 4) 11 S-170711-00674 S-170711-00751 Cadmium 7440-43-9 n.d. Lead 7439-92-1 n.d. - Applied standard CPSC-CH-E1002-08.3 (2012) - Requirement by the client, products for over 3 years= 75,0 mg Kg-1 for cadmium 100,0 mg Kg-1 for lead Pag. 6 of 11
Report Unit: mg Kg-1 n.d.= not detected = <LOQ LOQ (Limit of quantification )= 50,0 mg Kg-1 * 200 SOP 20-Determination of the content of phenols 10 S-170711-00673 S-170711-00673 PCP 87-86-5 n.d. TeCP 25167-83-3 n.d. - Requirement by the client= 0,05 mg Kg-1. Report Unit mg Kg-1 n.d= not detected (<MDL) MDL (Method Detection Limit )= 0,05 mg Kg-1 600 SOP 60-Colour Fastness to Rubbing (Direct Contact) 1 S-170708-00134 S-170708-00134 Cross Staining Length direction Dry Colour Change 5 Length direction Dry Staining 3 Length direction Wet Colour Change 4/5 Length direction Wet Staining 2 (**) Width direction Dry Colour Change 4/5 Width direction Dry Staining 2/3 (**) Width direction Wet Colour Change 4/5 Width direction Wet Staining 2 (**) Pag. 7 of 11
- Applied standard UNE-EN ISO 105-X12:2016 (Equivalent to ISO 105-X12:2016) - Requirement by the client, products for over 3 years= 3 in Grey Scale ISO 105-A02 for Colour Change 3 in Grey Scale ISO 105-A03 for Colour Staining. - Requirement by the client, products intended for children under 3 years= 4 in Grey Scale ISO 105-A02 for Colour Change 4 in Grey Scale ISO 105-A03 for Colour Staining. - = not applicable Note 1: Rubbing plug with a cylinder of (16 ± 0.1) mm, which apply a downward force of (9 ± 0.2) N Note 2: Only for Hair fabrics: Rubbing plug with a rectangular area of 19 mm x 25.4 mm, which apply a downward force of (9 ± 0.2) N Note 3: Adjacent Fabric Monofibre used: Cotton Note 4: Impregnation/absorption percentage for wet rubbing: 95-100 % Note 5: Conditioning time for analyzed fabrics and adjacent fabrics: 4 hours Note 6: Environmental conditions: (20±2) ºC and (65±2) % of RH 621 SOP 62-Colour Fastness to Acid perspiration (Direct contact) 2 S-170708-00135 S-170708-00135 Colour Change 5 Cross Staining Staining Acetate 5 Staining Acrylic 5 Staining Cotton 5 Staining Linen Staining Polyamide 5 Staining Polyester 5 Staining Silk Staining Viscose Staining Wool 5 - Applied standard UNE-EN ISO 105-E04:2013 (Equivalent to ISO 105-E04:2013) - Requirement by the client, products for over 3 years= 3 in Grey Scale ISO 105-A02 for Colour Change 3 in Grey Scale ISO 105-A03 for Colour Staining. - Requirement by the client, products intended for children under 3 years= 3-4 in Grey Scale ISO 105-A02 for Colour Change 3-4 in Grey Scale ISO 105-A03 for Colour Staining. - = not applicable Pag. 8 of 11
Note 1: Acid solution used with ph 5.5 (± 0.2) Note 2: Adjacent Fabric Monofibre used: if only appear two results in staining Note 3: Adjacent Fabric Multifibre type used: DW, see results if appear more than two results in staining. Note 4: Perspirometer position for test: Vertical 622 SOP 62-Colour Fastness to Alkaline perspiration (Direct contact) 3 S-170708-00136 S-170708-00136 Colour Change 5 Cross Staining Staining Acetate 5 Staining Acrylic 5 Staining Cotton 5 Staining Linen Staining Polyamide 5 Staining Polyester 5 Staining Silk Staining Viscose Staining Wool 5 - Applied standard UNE-EN ISO 105-E04:2013 (Equivalent to ISO 105-E04:2013) - Requirement by the client, products for over 3 years= 3 in Grey Scale ISO 105-A02 for Colour Change 3 in Grey Scale ISO 105-A03 for Colour Staining. - Requirement by the client, products intended for children under 3 years= 3-4 in Grey Scale ISO 105-A02 for Colour Change 3-4 in Grey Scale ISO 105-A03 for Colour Staining. - = not applicable Note 1: Alkaline solution used with ph 8 (± 0.2) Note 2: Adjacent Fabric Monofibre used: if only appear two results in staining Note 3: Adjacent Fabric Multifibre type used: DW, see results if appear more than two results in staining. Note 4: Perspirometer position for test: Vertical Pag. 9 of 11
130 SOP 13 - Colour fastness to domestic washing C06 4 S-170708-00137 S-170708-00137 Colour Change 5 Cross Staining Staining Acetate 5 Staining Acrylic 5 Staining Cotton 5 Staining Linen Staining Polyamide 5 Staining Polyester 5 Staining Silk Staining Viscose Staining Wool 5 Washing Temperature 30ºC - Applied standard UNE-EN ISO 105-C06:2010 (Equivalent to ISO 105-C06:2010) - = not applicable - Requirement recommended= 3 in Grey Scale ISO 105-A02 for Colour Change 3 in Grey Scale ISO 105-A03 for Colour Staining. Note 1: Test Temperature: Indicated in results table Note 2: Test number according with Tª: A1S (40ºC - 30 min) / A1M (40ºC - 45 min) / B1S (50ºC - 30 min) / B1M (50ºC - 45 min) / C1S (60 ºC - 30 min) / C1M (60 ºC - 40 min) Note 3: Steel balls used: Yes Note 4: Treatment with acetic acid: No Note 5: Detergent used: ECE phosphate reference detergent (B) Note 6: Adjacent Fabric Monofibre used: if only appear two results in staining Note 7: Adjacent Fabric Multifibre type used: DW, see results if appear more than two results in staining. Pag. 10 of 11
TEST REPORT Date: 19/07/2017 Issue Signed: Manuel Lolo Signed: Pablo Perez General Manager Chemical Lab Manager Signed: Esteban Ramirez Physical Lab Manager Pag. 11 of 11