MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Product name CAS # Product use Product Use Distributed by AMOPE PEDI PERFECT Daily Moisturizer Mixture This MSDS is designed for workplace employees, emergency personnel and for other conditions and situations where there is a greater potential for large-scale or prolonged exposure, in accordance with requirements of the U.S. Government's Occupational Safety and Health Administration (OSHA). This MSDS is not applicable for consumer use of our products. For consumer use, all precautionary and first aid language is provided on the product label in accordance with the applicable government regulation. Skin Cream Reckitt Benckiser Morris Corporate Center IV 399 Interpace Parkway Parsippany, NJ 07054-0225 In Case of Emergency: 1-800-338-6167 Transportation Emergencies: 24 Hour Number: North America: CHEMTREC: 1-800-424-9300 Outside North America: 1-703-527-3887 LEGEND Severe 4 Serious 3 Moderate 2 Slight 1 Minimal 0 HEALTH / 1 FLAMMABILITY 0 PHYSICAL HAZARD 0 PERSONAL PROTECTION X 0 1 0 2. Hazards Identification Emergency overview KEEP OUT OF REACH OF CHILDREN. Potential short term health effects Routes of exposure Eye, Skin contact,, Ingestion. Eyes Causes irritation. Skin The finished product is not expected to cause irritation. Not expected to be a skin sensitizer. No risks anticipated in normal use. Ingestion Ingestion may cause gastrointestinal irritation. Target organs Eyes. Skin. Respiratory system. Reproductive System. Chronic effects Signs and symptoms Symptoms may include redness, edema, drying, defatting and cracking of the skin. OSHA regulatory status This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Potential environmental effects See section 12. 3. Composition/Information on Ingredients Components CAS # Percent Glycerin 56-81-5 10-20 Dimethicone 63148-62-9 2.5-10 Mineral Oil 8042-47-5 2.5-10 #24980 Page: 1 of 8 Issue date 15-July-2014
Components CAS # Percent Sodium Gluconate Cetearyl Alcohol Dimethylimidazolidinone Rice Starch Glyceryl stearate Niacinamide 527-07-1 2.5-10 67762-27-0 1-2.5 172275-79-5 1-2.5 123-94-4 1-2.5 98-92-0 1-2.5 4. First Aid Measures First aid procedures Eye contact Skin contact Ingestion Notes to physician General advice Immediately rinse eye for several minutes with plenty of lukewarm water whilst separating the eyelids. If irritation persists, seek medical attention. Cosmetic product designed to be in contact with the skin. In case of accidental and excess application of the product, rinse with water. Not an anticipated route of exposure. Move victim to fresh air. If symptoms persist, obtain medical attention. Do not induce vomiting. Immediately rinse the mouth with water. Drink one pint (500mL) of water unless there is evidence of burns or difficulty swallowing. Seek medical advice immediately. Treat patient symptomatically. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with eyes. Keep out of reach of children. 5. Fire Fighting Measures Flammable properties Not flammable by OSHA criteria. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment and precautions for firefighters Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Water spray. Foam. Carbon dioxide. Dry chemical. Firefighters should wear full protective clothing including self contained breathing apparatus. May include and are not limited to: Oxides of carbon. Oxides of nitrogen. Oxides of sulfur. 6. Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up Keep unnecessary personnel away. Do not touch or walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep people away from and upwind of spill/leak. Floors may become slippery. Do not discharge into lakes, streams, ponds or public waters. Advise authorities if product has penetrated drains, sewers or water pipes. Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confined areas. Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. #24980 Page: 2 of 8 Issue date 15-July-2014
7. Handling and Storage Handling Storage Ensure adequate ventilation. Avoid contact with eyes. Use good industrial hygiene practices in handling this material. Avoid spillage on carpets, clothes and flooring. Use according to package label instructions. Keep out of reach of children. Store in a closed container away from incompatible materials. Do not store contents under direct sunlight. Keep from freezing. Allowances for excursions above 30 C: >50 C - Not permitted. 40 C - Not more than 8 weeks. Allowances for excursions below 0 C: Do not store below -20 C. 8. Exposure Controls/Personal Protection Occupational exposure limits US. ACGIH Threshold Limit Values Components Type Value Form Mineral Oil (CAS 8042-47-5) TWA 5 mg/m3 Inhalable fraction. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Form Mineral Oil (CAS 8042-47-5) Exposure limits Engineering controls Personal protective equipment Eye / face protection Hand protection Skin and body protection Respiratory protection General hygiene considerations PEL 5 mg/m3 Respirable fraction. 15 mg/m3 Total dust. PEL 5 mg/m3 Mist. Chemicals listed in section 3 that are not listed here do not have established limit values for ACGIH or OSHA PEL. General ventilation normally adequate. Consult the product label for special protection or precautions that have been identified for using this product under directed consumer use conditions. The following recommendations are given for workplace employees, emergency personnel and for other conditions and situations where there is a greater potential for large-scale or prolonged exposure. Follow standard industrial hygiene practices. Not required. Not normally required. Appearance Lotion Color White. Form Cream Odor Characteristic Odor threshold Physical state Liquid. ph 4.70-5.80 Freezing point Boiling point Where exposure guideline levels may be exceeded, use an approved NIOSH respirator. Handle in accordance with good industrial hygiene and safety practice. When using do not eat or drink. Wash hands before breaks and immediately after handling the product. 9. Physical and Chemical Properties #24980 Page: 3 of 8 Issue date 15-July-2014
Pour point Evaporation rate Flash point Auto-ignition temperature Flammability limits in air, upper, % by volume Flammability limits in air, lower, % by volume Vapor pressure Vapor density Specific gravity Partition coefficient (n-octanol/water) Solubility (water) Relative density Viscosity VOC Percent volatile Reactivity Possibility of hazardous reactions Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Insoluble 0.950-1.050 g/cm-1 10. Stability and Reactivity This product may react with oxidizing agents. Hazardous polymerization does not occur. Stable under recommended storage conditions. Do not mix with other chemicals. Temperatures below 5 C and >40 C. Keep from freezing. Oxidizing agents. May include and are not limited to: Oxides of carbon. Oxides of nitrogen. Oxides of sulfur. 11. Toxicological Information Toxicological data Components Cetearyl Alcohol (CAS 67762-27-0) Dimethicone (CAS 63148-62-9) Species Rabbit Rabbit Test Results 8000 mg/kg 10000 mg/kg > 2000 mg/kg > 17000 mg/kg #24980 Page: 4 of 8 Issue date 15-July-2014
Components Species Test Results Dimethylimidazolidinone Rice Starch (CAS 172275-79-5) Glyceryl stearate (CAS 123-94-4) Niacinamide (CAS 98-92-0) Rabbit Mouse Rabbit > 10000 mg/kg 23000 mg/kg > 143 mg/m³, 4 Hours 23000 mg/kg > 12600 mg/kg 27200 mg/kg > 2000 mg/kg 5000 mg/kg > 2.2 mg/l, 4 Hours > 2000 mg/kg 2000 mg/kg Mouse 2500 mg/kg Sodium Gluconate (CAS 527-07-1) 3500 mg/kg #24980 Page: 5 of 8 Issue date 15-July-2014
Components Species Test Results > 2000 mg/kg Effects of acute exposure Eye contact Skin contact Ingestion Sensitization Chronic effects Carcinogenicity Mutagenicity Reproductive effects Teratogenicity Name of Toxicologically Synergistic Products Causes irritation. The finished product is not expected to cause irritation. Not expected to be a skin sensitizer. No risks anticipated in normal use. Ingestion may cause gastrointestinal irritation. Ecotoxicity See below Ecotoxicological data Components Cetearyl Alcohol (CAS 67762-27-0) Crustacea EC50 12. Ecological Information Species Daphnia Test Results 1666 mg/l, 48 Hours Dimethicone (CAS 63148-62-9) Aquatic Fish Channel catfish (Ictalurus punctatus) 2.36-4.15 mg/l, 96 hours Aquatic Fish Rainbow trout,donaldson trout (Oncorhynchus mykiss) 51000-57000 mg/l, 96 hours Persistence and degradability Bioaccumulation / Accumulation Mobility in environmental media Environmental effects Aquatic toxicity Partition coefficient Glycerin -1.76 Niacinamide -0.37 Chemical fate information 13. Disposal Considerations Disposal instructions Waste from residues / unused products Contaminated packaging Dispose in accordance with all applicable regulations. Dispose of empty packaging with normal household trash. #24980 Page: 6 of 8 Issue date 15-July-2014
U.S. Department of Transportation (DOT) Not regulated as dangerous goods. Transportation of Dangerous Goods (TDG - Canada) Not regulated as dangerous goods. IATA/ICAO (Air) Not regulated as dangerous goods. IMDG (Marine Transport) Not regulated as dangerous goods. 14. Transport Information 15. Regulatory Information Occupational Safety and Health Administration (OSHA) 29 CFR 1910.1200 Yes hazardous chemical US federal regulations This cosmetic product is in compliance with Title 21 of the Code of Federal Regulations, Part 701 and 740. All components of this product are either on the TSCA Inventory, or are exempt from TSCA Inventory. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. US CAA Section 111 Volatile Organic Compounds: Listed substance Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. US CAA Section 612 SNAP Program: Listed substance US CAA VOCs with Negligible Photochemical Activity: Listed substance Dimethicone (CAS 63148-62-9) CERCLA (Superfund) reportable quantity None Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No State regulations This product is not subject to warning labeling under the California Proposition 65 regulation. US - California Hazardous Substances (Director's): Listed substance US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance Not listed. US - Minnesota Haz Subs: Listed substance US - New Jersey RTK - Substances: Listed substance US - Texas Effects Screening Levels: Listed substance Dimethicone (CAS 63148-62-9) Sodium Gluconate (CAS 527-07-1) #24980 Page: 7 of 8 Issue date 15-July-2014
US. Massachusetts RTK - Substance List US. Pennsylvania RTK - Hazardous Substances US. Rhode Island RTK Not regulated. Country(s) or region Inventory name On inventory (yes/no)* United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory No *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) 16. Other Information Disclaimer This product should only be used as directed on the label and for the purpose intended. To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Further information AMOPE PEDI PERFECT Daily Moisturizer 250mL 0243005v5.0 Issue date 15-July-2014 Effective date 15-July-2014 Prepared by Dell Tech Laboratories, Ltd. Phone: (519) 858-5021 Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document. This MSDS conforms to the ANSI Z400.1/Z129.1-2010 Standard. #24980 Page: 8 of 8 Issue date 15-July-2014