MATERIAL SAFETY DATA SHEET. 1. Product and Company Identification

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1 MATERIAL SAFETY DATA SHEET Product Name CAS # Product use Distributed by LEGEND HMIS/NFPA Severe Serious 4 3 Moderate 2 Slight 1 Minimal 0 Emergency overview 1 Product and Company Identification Clearasil Daily Clear Oil Free Daily Face Wash - Sensitive (Salicylic Acid Formula) Mixture Face wash Reckitt Benckiser Morris Corporate Center IV 399 Interpace Parkway PO Box 225 Parsippany, NJ In Case of Emergency: Transportation Emergencies: 24 Hour Number: North America: CHEMTREC: Outside North America: Health / 1 Flammability 0 Physical Hazard 0 Personal Protection 2 Hazards Identification This product is regulated by the US FDA as an over-the-counter, monograph drug Warnings: For external use only When using this product, avoid contact with the eyes If product gets into the eyes rinse thoroughly with water Use with other topical acne medications, at the same time or immediately following use of this product, may increase dryness or irritation of the skin If this occurs, only one acne medication should be used unless directed by your doctor Limit use to the face and neck Stop use and ask a doctor if skin or eye irritation develops In case of accidental ingestion, get medical help or contact a Poison Control Center immediately Potential short term health effects Routes of exposure Eyes Skin Inhalation Ingestion Target organs Chronic effects Signs and symptoms OSHA Regulatory Status KEEP OUT OF REACH OF CHILDREN Eye, Skin contact, Inhalation, Ingestion May cause eye irritation Unlikely to cause skin irritation Not expected to be a skin sensitizer Unlikely to cause irritation due to inhalation Ingestion may cause gastrointestinal irritation Eyes Skin Potential environmental effects See section 12 The finished product is not expected to have chronic health effects Symptoms may include redness, edema, drying, defatting and cracking of the skin This acne product is in compliance with Title 21 of the Code of Federal Regulations, Part 207 and meets the regulatory requirements outlined in the OTC Monograph under 21 CFR Part 333D #20279 Page 1 of 8 Issue date 15-Jun-2012

2 3 Composition / Information on Ingredients Ingredient(s) CAS # Percent Lauric Acid Myristic Acid Palmitic Acid Potassium hydroxide Sodium Lauroyl Sarcosinate Stearic Acid Salicylic Acid First aid procedures Eye contact Skin contact Inhalation Ingestion Notes to physician General advice 4 First Aid Measures If product gets into the eyes, rinse thoroughly with water Stop use and ask a doctor if eye irritation develops Stop use and ask a doctor if skin irritation develops Remove to fresh air if inhalation causes eye watering, headaches, dizziness or other discomfort In case of accidental ingestion, get medical help or contact a Poison Control Center immediately Treat patient symptomatically If you feel unwell, seek medical advice (show the label where possible) Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves Show this safety data sheet to the doctor in attendance Avoid contact with eyes Keep out of reach of children 5 Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighters Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Personal precautions Environmental precautions Methods for containment Methods for cleaning up Not flammable by OSHA criteria Water spray Alcohol foam Dry chemical Firefighters should wear full protective clothing including self contained breathing apparatus May include and are not limited to: Oxides of carbon 6 Accidental Release Measures Floors may become slippery Do not touch or walk through spilled material Do not touch damaged containers or spilled material unless wearing appropriate protective clothing Do not discharge into lakes, streams, ponds or public waters Stop leak if you can do so without risk Prevent entry into waterways, sewers, basements or confined areas Before attempting clean up, refer to hazard data given above Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers Prevent large spills from entering sewers or waterways Contact emergency services and supplier for advice Never return spills to original containers for re-use #20279 Page 2 of 8 Issue date 15-Jun-2012

3 Handling Storage 7 Handling and Storage For external use only Avoid contact with eyes Ensure adequate ventilation When using do not eat or drink Keep out of reach of children Keep tightly closed in a dry and cool place Protect from freezing Allowances for excursions above 30 C: 40 C - Not more than 3 weeks Exposure limits Ingredient(s) Lauric Acid Myristic Acid Palmitic Acid Potassium hydroxide Salicylic Acid Sodium Lauroyl Sarcosinate Allowances for excursions below 0 C: Do not store below -20 C 8 Exposure Controls / Personal Protection Exposure Limits Mist: 5 mg/m3 TWA: 10 mg/m3 TWA: 15 mg/m3 Ceiling: 2 mg/m3 Stearic Acid Engineering controls Personal protective equipment Eye / face protection Hand protection Skin and body protection Respiratory protection Not normally required Not normally required under normal use conditions Not required No special requirements under normal use conditions Not normally required under normal use conditions #20279 Page 3 of 8 Issue date 15-Jun-2012

4 General hygiene considerations Avoid contact with eyes Handle in accordance with good industrial hygiene and safety practice When using do not eat or drink 9 Physical and Chemical Properties Appearance Cream Color White pearlescent Form Liquid Odor Odorless Odor threshold Physical state Liquid ph 8-9 Freezing point Boiling point Pour point Evaporation rate Flash point Auto-ignition temperature Flammability limits in air, lower, % by volume Flammability limits in air, upper, % by volume Vapor pressure Vapor density Specific gravity Octanol/water coefficient Solubility (H2O) VOC (Weight %) Percent volatile Soluble 10 Stability and Reactivity Reactivity This product may react with strong oxidizing agents Possibility of hazardous reactions Hazardous polymerization does not occur Chemical stability Stable under recommended storage conditions Conditions to avoid Do not mix with other chemicals Incompatible materials Acids Oxidizers Hazardous decomposition products May include and are not limited to: Oxides of carbon Component analysis - LC50 Ingredient(s) 11 Toxicological Information LC50 Lauric Acid Myristic Acid Palmitic Acid Potassium hydroxide Salicylic Acid Sodium Lauroyl Sarcosinate Stearic Acid #20279 Page 4 of 8 Issue date 15-Jun-2012

5 Component analysis - Oral LD50 Ingredient(s) LD50 Lauric Acid mg/kg rat Myristic Acid Palmitic Acid mg/kg rat Potassium hydroxide 214 mg/kg rat Salicylic Acid 891 mg/kg rat; 400 mg/kg cat; 480 mg/kg mouse Sodium Lauroyl Sarcosinate 2000 mg/kg rat Stearic Acid 5000 mg/kg rat Effects of acute exposure Eye May cause eye irritation Skin Unlikely to cause skin irritation Not expected to be a skin sensitizer Inhalation Unlikely to cause irritation due to inhalation Ingestion Ingestion may cause gastrointestinal irritation Sensitization The finished product is not expected to have chronic health effects Chronic effects The finished product is not expected to have chronic health effects Carcinogenicity The finished product is not expected to have chronic health effects Mutagenicity The finished product is not expected to have chronic health effects Reproductive effects The finished product is not expected to have chronic health effects Teratogenicity The finished product is not expected to have chronic health effects Name of Toxicologically Synergistic Products Ecotoxicity 12 Ecological Information Components of this product have been identified as having potential environmental concerns Ecotoxicity - Freshwater Fish - Acute Toxicity Data Myristic Acid Hr LC50 Oryzias latipes: 118 mg/l [static] Palmitic Acid Hr LC50 Oryzias latipes: 150 mg/l Potassium hydroxide Hr LC50 Gambusia affinis: 80 mg/l [static] Salicylic Acid Hr LC50 Leuciscus idus: 90 mg/l [static] Ecotoxicity - Water Flea - Acute Toxicity Data Myristic Acid Hr EC50 Artemia salina: >27 mg/l Salicylic Acid Hr EC50 Daphnia magna: 105 mg/l; 48 Hr EC50 Daphnia magna: 870 mg/l [Static] Persistence / degradability Bioaccumulation / accumulation Mobility in environmental media Environmental effects Aquatic toxicity Partition coefficient Chemical fate information Disposal instructions Waste from residues / unused products Contaminated packaging 13 Disposal Considerations Review federal, provincial, and local government requirements prior to disposal #20279 Page 5 of 8 Issue date 15-Jun-2012

6 14 Transport Information UN/ID No US Department of Transportation (DOT): Classification: Not regulated Proper shipping name US DOT Hazard Class Subsidiary Risk Packing group DOT RQ (lbs) ERG NO Transportation of Dangerous Goods (TDG - Canada): Classification: Not regulated Proper shipping name Status Packing group IMDG (Marine Transport): Classification: Not regulated Proper shipping name Class Subsidiary Risk Packing group IMDG Page Marine pollutant EMS MFAG Maximum Quantity IATA/ICAO (Air): Classification: Not regulated Proper shipping name Class Subsidiary Risk: Packing group Maximum Quantity #20279 Page 6 of 8 Issue date 15-Jun-2012

7 15 Regulatory Information Occupational Safety and Health Administration (OSHA) 29 CFR hazardous chemical US Federal regulations Yes This acne product is in compliance with Title 21 of the Code of Federal Regulations, Part 207 and meets the regulatory requirements outlined in the OTC Monograph under 21 CFR Part 333D US - CERCLA/SARA - Hazardous Substances and their Reportable Quantities Potassium hydroxide Lb final RQ; 454 kg final RQ US - CWA (Clean Water Act) - Hazardous Substances Potassium hydroxide Present CERCLA (Superfund) reportable quantity Potassium hydroxide: Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Section 302 extremely No hazardous substance Section 311 hazardous chemical Yes Clean Air Act (CAA) Clean Water Act (CWA) Hazardous substance State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm US - California - 8 CCR Section Director's List of Hazardous Substances Potassium hydroxide Present Stearic Acid Present US - Louisiana - Reportable Quantity List for Pollutants Potassium hydroxide Lb final RQ; 454 kg final RQ US - Massachusetts - Right To Know List Potassium hydroxide Present US - Minnesota - Hazardous Substance List Potassium hydroxide Present US - New Jersey - Right to Know Hazardous Substance List Potassium hydroxide sn 1571 US - New York - Reporting of Releases Part List of Hazardous Substances Potassium hydroxide Lb RQ (air); 100 lb RQ (land/water) US - Pennsylvania - RTK (Right to Know) List Potassium hydroxide Environmental hazard US - Rhode Island - Hazardous Substance List Potassium hydroxide Toxic (caustic); Flammable (caustic) Inventory status Country(s) or region Inventory name On inventory (yes/no)* United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) Disclaimer Further information 16 Other Information This product should only be used as directed on the label and for the purpose intended To the best of our knowledge, the information contained herein is accurate However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein Final determination of suitability of any material is the sole responsibility of the user All materials may present unknown hazards and should be used with caution Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist Clearasil Daily Clear Oil Free Daily Face Wash - Sensitive, v40 (Salicylic Acid Formula) Issue date 15-Jun-2012 #20279 Page 7 of 8 Issue date 15-Jun-2012

8 Effective date 15-Jun-2012 Prepared by Reckitt Benckiser Regulatory Department Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document #20279 Page 8 of 8 Issue date 15-Jun-2012