Safety Data Sheet. Classified as hazardous

Transcription

1 Page: 1 1. Identification GHS Product Identifier Company Name Address Telephone/Fax Number Recommended use the chemical and restrictions on use Other Names 2. Hazard Identification GHS classification the substance/mixture Signal Word (s) Hazard Statement (s) Pictogram (s) CHEM-SUPPLY PTY LTD (ABN ) 38-0 Bedford Street GILLMAN SA 013 Australia Tel: (08) Fax: (08) Food acidulant, flavouring, wine manufacture, manufacture various esters and salts, chelating agent and laboratory reagent. Name Product Code LR Hydroxysuccinic acid DL-Malic acid FCC DL-Malate Apple acid Malic acid 3% solution EMERGENCY CONTACT NUMBER: Business hours: 8:30am to :00pm, Monday to Friday. ML008 MP008 Chem-Supply Pty Ltd does not warrant that this product is suitable for any use or purpose. The user must ascertain the suitability the product before use or application intended purpose. Preliminary testing the product before use or application is recommended. Any reliance or purported reliance upon Chem-Supply Pty Ltd with respect to any skill or judgement or advice in relation to the suitability this product any purpose is disclaimed. Except to the extent prohibited at law, any condition implied by any statute as to the merchantable quality this product or fitness for any purpose is hereby excluded. This product is not sold by description. Where the provisions Part V, Division 2 the Trade Practices Act apply, the liability Chem-Supply Pty Ltd is limited to the replacement supply equivalent goods or payment the cost replacing the goods or acquiring equivalent goods. Eye Damage/Irritation: Category 1 Skin Corrosion/Irritation: Category 2 Specific target organ toxicity - Single Exposure Category 3 DANGER H31 Causes skin irritation. H318 Causes serious eye damage. H33 May cause respiratory irritation. Corrosion, Exclamation mark statement Prevention statement Response P280 Wear protective gloves/protective clothing/eye protection/face protection. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash thoroughly after handling. P30+P31+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. P302+P32 IF ON SKIN: Wash with plenty soap and water. P332+P313 If skin irritation occurs: Get medical advice/attention. P362 Take f contaminated clothing and wash before reuse. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P312 Call a POISON CENTER or doctor/physician if you feel unwell.

2 Page: 2 statement Storage P403+P233 Store in a well-ventilated place. Keep container tightly closed. 3. Composition/information on ingredients Chemical Characterization Ingredients Solid Name CAS Proportion Hazard Symbol Risk Phrase Malic acid % Xi Found naturally in apples, blackcurrants and figs. 4. First-aid measures Inhalation Remove victim to fresh air. If breathing becomes difficult, seek medical attention. Ingestion Skin Eye contact First Aid Facilities Advice to Doctor. Fire-fighting measures Specific Methods Temp. 6. Accidental release measures R36/37/38 Rinse mouth thoroughly with water immediately. Give plenty water to drink. Do not induce vomiting. Seek medical advice if effects persist. Wash with plenty soap and water. If irritation occurs seek medical advice. Irrigate with copious quantity water for 1 minutes. Seek medical assistance if symptoms persist. Maintain eyewash fountain and safety shower in work area. Treat symptomatically or consult a Poisons Centre. For advice, contact the National Poisons Centre (Phone Australia ; New Zealand ) or a doctor. Small fire: Use dry chemical, CO2, water spray or foam. Large fire: Use water spray, fog or foam. If safe to do so, move undamaged containers from the fire area. Cool containers with flooding quantities water until well after the fire is out C Personal Avoid inhalation, contact with skin, eyes and clothing. Precautions Personal Protection Wear protective clothing specified for normal operations (see Section 8) Clean-up Methods - Small Spillages 7. Handling and storage Precautions for Safe Handling Conditions for safe storage, including any incompatabilities Sweep up (avoid generating dust) and remove to a suitable, clearly labelled container for disposal in accordance with local regulations. Avoid generation or accumulation dusts. Avoid prolonged or repeated contact with skin and eyes. Wear suitable protective clothing. Keep container tightly closed when not in use. Keep material away from sparks, flames and other ignition sources. Store in well ventilated area. Store away from sources heat or ignition. Store in a cool,dry place. Keep containers closed at all times. Store away from incompatible substances. Slightly hydroscopic. 8. Exposure controls/personal protection Other Exposure Appropriate engineering controls methods. Respiratory Protection A time weighted average (TWA) concentration for an 8 hour day, and day week has not been established by NOHSC Australia for this product. There is a blanket limit 10 mg/m³ for dusts or mists when limits have not otherwise been established. In industrial situations maintain the concentrations values below the TWA. This may be achieved by process modification, use local exhaust ventilation, capturing substances at the source, or other Where ventilation is not adequate, respiratory protection may be required. Avoid breathing dust, vapours or mists. Respiratory protection should comply with AS Respiratory Protective Devices and be selected in accordance with AS Selection, Use and Maintenance Respiratory Protective Devices. Filter capacity and respirator type depends on exposure levels. In event emergency or planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection is required, institute a complete respiratory protection program including selection, fit testing, training, maintenance and inspection.

3 Page: 3 Eye Protection Hand Protection Body Protection Hygiene Measures The use a face shield, chemical goggles or safety glasses with side shield protection as appropriate. Must comply with Australian Standards AS 1337 and be selected and used in accordance with AS Hand protection should comply with AS 2161, Occupational protective gloves - Selection, use and maintenance. Clean clothing or protective clothing should be worn, preferably with an apron. Clothing for protection against chemicals should comply with AS 376 Clothing for Protection Against Hazardous Chemicals. Always wash hands before smoking, eating or using the toilet. Wash contaminated clothing and other protective equipment before storing or re-using. 9. Physical and chemical properties Form Solid Appearance Odour Temperature Melting Point Boiling Point Solubility in Water White to almost white crystalline granular powder. Odourless C DL malic acid: C (L-malic acid: C). Decomposes before boiling at C. Soluble in water (~30 20 C). Solubility in Organic Very soluble in alcohol. Slightly soluble in ether. Insoluble in benzene and acetone. Solvents Specific Gravity 20 C ph Vapour Pressure ~ 2.3 (10 g/l, H2O, 20 C) < C) Vapour Density 4.6 g/l (Air=1) Partition Coefficient: n-octanol/water Flash Point C Flammability Auto-Ignition Temperature Molecular Weight Combustible. 349 C Stability and reactivity Chemical Stability Conditions to Avoid Incompatible Materials Hazardous Products Hazardous Polymerization Taste: Strongly acidic. Dissociation constant: DL pka = 3.40 Indefinitely stable at room temperature in the orginal sealed, unopened container. If exposed to air will oxidise to oxaloacetic acid. Dust generation. Heat, flames, ignition sources and incompatibles. Strong oxidizing agents, reducing agents, strong bases, amines, carbonates, alkali metals, carbon monoxide, carbon dioxide. Unsuitable container materials: iron, zinc, and aluminium. Aqueous solutions malic acid may release explosive hydrogen gas if in contact with these active metals. Carbon oxide and carbon dioxide. Will not occur. 11. Toxicological Acute Toxicity - Oral LD0 (rat): 3200 mg/kg Ingestion May be harmful if swallowed. Irritation mucous membranes in the mouth, pharynx, oesophagus and gastrointestinal tract. Symptoms may include nausea, vomiting and diarrhea. Moderately toxic by ingestion. May cause mild to moderate burns in the oesophagus and more severe burns in the stomach. Metabolic disturbances and systemic acidosis may occur.

4 Page: 4 Inhalation Skin Eye Carcinogenicity Chronic Effects Mutagenicity 12. Ecological information Persistence and degradability Bioaccumulative Potential Inhalation dust is irritating to the upper respiratory tract (nose, throat, lungs). May be harmful if large amounts are inhaled. Symptoms may include coughing and dyspnoea. Moderately irritating to the skin. May be harmful if absorbed through the skin. Prolonged skin contact may give rise to irritation in certain sensitive individuals. Causes severe eye irritation. No evidence carcinogenic properties. Prolonged or repeated eye contact may cause conjunctivitis. Prolonged or repeated skin contact may cause dermatitis. Increased inhalation and ingestion this material may affect behaviour and respiration causing weakness, respiratory distress and cyanosis. No evidence mutagenic properties. Readily biodegradable. Harmful due to ph shift. log P(o/w) = Disposal considerations Disposal Considerations 14. Transport information Transport 1. Regulatory information Regulatory Poisons Schedule 16. Literature References Contact Person/Point Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and disposed according to relevant local, state and federal government regulations. Not classified as a Dangerous Good according to the Australian Code for the Transport Dangerous Goods by Road and Rail (ADG); by the IATA Air Transport Dangerous Goods Regulations; or by the IMDG (International Maritime Dangerous Goods) Code. Listed in the Australian Inventory Chemical Substances (AICS). Not Scheduled Empirical Formula & C4 H6 O Structural Formula...End Of MSDS... 'Standard for the Uniform Scheduling Medicines and Poisons No. 1', Commonwealth Australia, November Lewis, Richard J. Sr. 'Hawley's Condensed Chemical Dictionary 13th. Ed.', Rev., John Wiley and Sons, Inc., NY, National Road Transport Commission, 'Australian Code for the Transport Dangerous Goods by Road and Rail 7th. Ed.', Safe Work Australia, 'National Code Practice fot the Preparation Safety Data Sheets for Hazardous Chemicals', Standards Australia, 'SAA/SNZ HB 76:2010 Dangerous Goods - Initial Emergency Response Guide', Standards Australia/Standards New Zealand, Safe Work Australia, 'Approved Criteria for Classifying Hazardous Substances [NOHSC:1008 (2004)]'. Safe Work Australia, 'Hazardous Substances System, 200'. Safe Work Australia, 'National Code Practice for the Labelling Safe Work Hazardous Substances (2011)'. Safe Work Australia, 'National Exposure Standards for Atmospheric Contaminants in the Occupational Environment [NOHSC:1003(199) 3rd Edition]'. Paul McCarthy Ph. (08) DISCLAIMER STATEMENT: All information provided in this data sheet or by our technical representatives is compiled from the best knowledge available to us. However, since data, safety standards and government regulations are subject to change and the conditions handling and use, or misuse, are beyond our control, we make no warranty either expressed or implied, with respect to the completeness or accuracy to the information contained herein. Chem-Supply accepts no responsibility whatsoever for its accuracy or for any results that may be obtained by customers from using the data and disclaims all liability for reliance on information provided in this data sheet or by our technical representatives.

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