SAFETY DATA SHEET Revised edition no : 0

Transcription

1 Page : 1 of 6 Danger 1 Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name : Identification of the product : Liquid. Product code : Type of product : Solvent Use : Cosmetic care product Company identification : 4500 Seaboard Rd, Ste. C Orlando, FL UNITED STATES 2 Hazards identification 2.1. Classification of the substance or mixture Hazard Class and Category Code Physical hazards : Flammable liquids - Category 2 - Danger (CLP : Flam. Liq. 2) Health hazards : Eye irritation - Category 2A - Warning (H319) Specific Target Organ Toxicity - Single exposure - Narcotic effects - Category 3 - Warning (H336) 2.2. Label elements GHS - Labelling with H and P Code Hazard pictograms Hazard pictograms code Signal word Hazard statements : GHS02 - GHS07 : Danger : H319 : Causes serious eye irritation. H336 : May cause drowsiness or dizziness. H225 : Highly flammable liquid and vapour. Precautionary statements - General : P102 : Keep out of reach of children. P103 : Read label before use. - Prevention : P280 : Wear protective gloves/protective clothing/eye protection/face protection. P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 : Keep container tightly closed. P240 : Ground/bond container and receiving equipment. P241 : Use explosion-proof electrical/ ventilating/lighting/ / equipment. P261 : Avoid breathing dust/fume/gas/mist/ vapours/spray. P264 : Wash with water thoroughly after handling. P271 : Use only outdoors or in a well-ventilated area.

2 Page : 2 of 6 2 Hazards identification (continued) - Response : P304+P340+P315 : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get immediate medical advice / attention. P303+ P361+P353 : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P305+P351+P338+P315 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice / attention. P : In case of fire, use appropriate media specified by the manufacturer/supplier or the competent authority for extinction, if water increases risk. - Storage : P405 : Store locked up. P403 : Store in a well-ventilated place. - Disposal considerations : P501 : Dispose of this material and its container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation Other hazards Symptoms relating to use - Inhalation : Symptoms of overexposure to vapours include drowsiness, weakness, headache, dizziness, nausea, vomiting, dimming of vision. - Skin contact : Prolonged or repeated contact may cause skin to become dry or cracked. - Eye contact : Redness, pain. Blurred vision. Burning sensation. - Ingestion : Abdominal pain, nausea. 3 Composition/information on ingredients 3.1 Substance / 3.2 Preparation : Preparation. Components : This product is hazardous. Substance name Contents CAS No EC No Index No Registration no Classification Acetone : > 75 % Flam. Liq. 2 (H225) Eye irrit 2 (H319) STOT SE 3 (H336) STOT RE (EUH066) Full text of R-phrases see chapter 16 Full text of H-statements see chapter 16 Note 1: Listed in Annex IV / V REACH, exempted from registration. Note 2: Registration deadline not expired. 4 First aid measures 4.1 First aid measures - Inhalation : Assure fresh air breathing. Inhalation of vapour can cause breathing difficulties. Obtain medical attention. - Skin/eye contact : Immediately flush eyes thoroughly with water for at least 15 minutes. - Skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. - Eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. - Ingestion : Rinse mouth. Spit. If swallowed, seek medical advice immediately and show this container or label Most important symptoms and : May cause chemical burns to skin and cornea (with temporary disturbance to effects, both acute and delayed vision).

3 Page : 3 of 6 4 First aid measures (continued) 5 Fire-fighting measures Flammable class : This product is flammable Extinguishing media : Large quantity of water. Foam. Dry chemical. Carbon dioxide (CO2). Surrounding fires : Use water spray or fog for cooling exposed containers. Protection against fire : Do not enter fire area without proper protective equipment, including respiratory protection Special hazards arising from the : Heavier than air, vapours may travel long distances along ground, ignite and flash substance or mixture back to source. Special procedures : Exercise caution when fighting any chemical fire Advice for fire-fighters : No data available. 6 Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions : No naked lights. No smoking. Evacuate and limit access. Equip cleanup crew with proper protection Environmental precautions : Prevent entry to sewers and public waters. Notify authorities if product enters sewers or public waters Methods and material for containment and cleaning up Clean up methods 6.5 Additional information : None. : Clean up any spills as soon as possible, using an absorbent material to collect it. Use suitable disposal containers. 7 Handling and storage General 7.1. Precautions for safe handling Precautions in handling and storage Handling 7.2. Conditions for safe storage, including any incompatibilities Storage : No naked lights. No smoking. Storage - away from 7.3. Specific end use(s) : Cosmetic care product. : Good ventilation of the workplace required. : Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. : Keep in fireproof place. Keep container closed when not in use. Use special care to avoid static electric charges. : Heat sources. 8 Exposure controls/personal protection 8.1. Control parameters

4 Page : 4 of 6 8 Exposure controls/personal protection (continued) Personal protection - Respiratory protection : Where excessive vapour may result, wear approved mask. - Hand protection : Gloves. - Skin protection : Protective clothing not absolutely necessary. - Eye protection : Chemical goggles or safety glasses. - Ingestion : When using, do not eat, drink or smoke. Industrial hygiene : Provide local exhaust or general room ventilation to minimize dust and/or vapour concentrations. Occupational Exposure Limits : Acetone : Value 8h (CZ) [mg/m3] : 800 Acetone : Value 15min. (CZ) [mg/m3] : 1500 Acetone : MAK (AU) Tagesmittelwert (ml/m³) : 500 Acetone : MAK (AU) Kurzzeitwerte (mg/m³) : 4800 Acetone : MAK (AU) Tagesmittelwert (mg/m³) : 1200 Acetone : MAK (AU) Kurzzeitwerte (ml/m³) : 2000 Acetone : Tentativ Grænserværdi (DK) (ppm) : 2420 Acetone : Grænserværdier (DK) (ppm) : 1210 Acetone : ILV (EU) - 8 H - [mg/m³] : 1210 Acetone : ILV (EU) - 8 H - [ppm] : 500 Acetone : TLV -TWA [ppm] : 500 Acetone : TLV -STEL [ppm] : 750 Acetone : LTEL - UK [mg/m³] : 1210 Acetone : LTEL - UK [ppm] : 3620 Acetone : LTEL - UK [ppm] : 500 Acetone : STEL - UK [mg/m³] : 1500 Acetone : VME - France [mg/m³] : 1800 Acetone : VME - France [ppm] : 750 Acetone : Arbeitsplatzgrenzwert AGW - Germany [mg/m³] TRGS 900 : 500 Acetone : AGW - Germany [ppm] : 1200 Acetone : Spitzenbegrenzung / Überschreitungsfaktor AGW - Germany TRGS 900 : 2 Acetone : VLA-ED [ppm] : 500 Acetone : VLA-ED [mg/m³] : 1210 Acetone : NGV - [ppm] : 250 Acetone : NGV - [mg/m³] : 600 Acetone : KTV - [ppm] : 500 Acetone : KTV - [mg/m³] : 500 Acetone : Grænserværdier (DK) (ppm) : 250 Acetone : HTP-värden - 8 H - [ppm] : 500 Acetone : HTP-värden - 8 H - [mg/m³] : 1200 Acetone : HTP-värden - 15min - [ppm] : 630 Acetone : Grænserværdier (DK) : 600 Acetone : HTP-värden - 15min - [mg/m³] : 1500 Acetone : GV Value Limit (Norway) [ppm] : 125 Acetone : GV Value Limit (Norway) [mg/m³] : 295 Acetone : 8-Hour TWA (PL) (NDS) (mg/m³) : 600 Acetone : 15-Minute STEL (PL)(NDSCh) (mg/m³) : 1800 Acetone : TLV-TWA (Belgium) (ppm) : 500 Acetone : TLV-STEL (Belgium) (ppm) : 1000 Acetone : Valori Limite di Soglia 8 ore (ppm) : 500 Acetone : Valori Limite di Soglia 8 ore (mg/m3) : 1210

5 Page : 5 of 6 8 Exposure controls/personal protection (continued) 9 Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state at 20 C : Liquid. Colour : Clear. Odour : Characteristic. ph value : Not applicable. Molecular weight : Melting point [ C] : -95 Boiling point [ C] : 56 Density : Vapour pressure [20 C] : 24.7 Vapour pressure mm/hg : 177 (20 C) Relative density, gas (air=1) : 2 Solubility in water [% weight] : Complete. Flash point [ C] : -18 Explosion limits - lower [%] : ca 2.1 Explosion limits - upper [%] : ca Other information : None. 10 Stability and reactivity Reactivity : Stable under normal conditions Chemical stability : Stable under normal conditions Possibility of hazardous : Reacts with : Strong oxidizing agents. reactions Conditions to avoid : Overheating Incompatible materials : Strong oxidizers Hazardous decomposition : None under normal conditions. products Hazardous properties : Vapour mixes readily with air, forming explosive mixtures. 11 Toxicological information Information on toxicological effects Toxicity information : Irritating to eyes. Rat oral LD50 [mg/kg] : > 5000 Rabbit dermal LD50 [mg/kg] : > 5000 Rat inhalation LC50 [mg/kg] : No data available. Rat inhalation LC50 [mg/l/4h] : > Ecological information Toxicity : Not classified as dangerous preparation/substance.

6 Page : 6 of 6 12 Ecological information (continued) Persistence and degradability : Easily biodegradable Bioaccumulative potential : No data available. BOD5-value [mg/l] : No data available. COD-value [mg/l] : No data available. LC50-96 Hour - fish [mg/l] : > Hour-EC50 - Daphnia magna [mg/l] : > Disposal considerations General : Dispose in a safe manner in accordance with local/national regulations. 14 Transport information UN number : 1266 Labelling ADR ADR/RID : Group : III Class : 3 H.I. nr : UN proper shipping name : PERFUMERY PRODUCTS 15 Regulatory information Safety, health and : Ensure all national/local regulations are observed. environmental regulations/legislation specific for the substance or mixture 16 Other information Users of breathing apparatus must be trained. Users of breathing apparatus must be trained. List of full text of H-statements in section 3. Revision : Revision - See : * Further information : None. The contents and format of this SDS are in accordance with UN GHS regulation : EUH066 : Repeated exposure may cause skin dryness or cracking. H225 : Highly flammable liquid and vapour. H319 : Causes serious eye irritation. H336 : May cause drowsiness or dizziness. DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. End of document