SAFETY DATA SHEET according to Regulation (EU) 2015/830

Transcription

1 SAFETY DATA SHEET according to Regulation (EU) 205/830 /5 SECTION : Identification of the substance/mixture and of the company/undertaking.. Product identifier Product name.3. Details of the supplier of the safety data sheet Company Address Web Telephone Advanced Healthcare Ltd Units 2-4 Leavers Estate, Chiddingstone Causeway, Tonbridge, Kent, TN 8JU, UK Fax +44 (0) address of the competent person.4. Emergency telephone number Emergency telephone number SECTION 2: Hazards identification +44 (0) (Use for Emergency also) sales@ahl.uk.com sales@ahl.uk.com +44(0) Classification of the substance or mixture (8.00 am pm Mon - Fri) date Classification - 999/45/ЕC Main hazards Classification - EC 272/ Label elements Hazard pictograms F; R Xi; R36 R66-67 Symbols: Highly flammable. Irritating to eyes. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness. : EUH066; Eye Irrit. 2: H39; STOT SE 3: H336; Signal Word Hazard Statement Warning EUH066 - Repeated exposure may cause skin dryness or cracking. Eye Irrit. 2: H39 - Causes serious eye irritation. STOT SE 3: H336 - May cause drowsiness or dizziness. Copyright 208 ChemSoft Limited. All rights reserved

2 date 2/ Label elements Prevention Response Storage P26 - Avoid breathing dust/fume/gas/mist/vapours/spray. P264 - Wash thoroughly after handling. P27 - Use only outdoors or in a well-ventilated area. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P35+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P32 - Call a POISON CENTER/doctor/ /if you feel unwell. P337+P33 - If eye irritation persists: Get medical advice/attention. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P405 - Store locked up. Medical devices as defined in Directive 93/42/EEC and which are invasive or used in direct physical contact with the human body, are exempted from the provisions of regulation (EC) No 272/2008 (CLP/GHS) usually if they are in the finished state and intended for the final user. SECTION 3: Composition/information on ingredients 3.2. Mixtures 67/548/EEC / 999/45/EC Chemical Name Index No. CAS No. EC No. REACH Registration Number Conc. (%w/w) Classification Ethyl acetate % F; R Xi; R36 R66 R67 M-factor. Butanone (Butan-2-one (methyl % F; R Xi; R36 R66 R67 ethyl ketone)) Polyethyl Methacrylate % Xn; R20/22 EC 272/2008 Chemical Name Index No. CAS No. EC No. REACH Registration Number Conc. (%w/w) Classification Ethyl acetate % Flam. Liq. 2: H225; Eye Irrit. 2: H39; STOT SE 3: H336; Butanone (Butan-2-one (methyl ethyl ketone)) % Flam. Liq. 2: H225; Eye Irrit. 2: H39; STOT SE 3: H336; M-factor. SECTION 4: First aid measures 4.. Description of first aid measures Inhalation Eye contact Skin contact Ingestion Irritating to respiratory system. Inhalation may cause coughing, tightness of the chest and irritation of the respiratory system. Move the exposed person to fresh air. Seek medical attention. Irritating to eyes. Rinse immediately with plenty of water for 5 minutes holding the eyelids open. Seek medical attention if irritation or symptoms persist. Irritating to skin. Wash off immediately with plenty of soap and water. Remove contaminated clothing. Seek medical attention if irritation or symptoms persist. Ingestion may cause nausea and vomiting. Seek medical attention if irritation or symptoms persist. DO NOT INDUCE VOMITING. SECTION 5: Firefighting measures 5.. Extinguishing media Carbon oxides Special hazards arising from the substance or mixture 5.3. Advice for firefighters Highly flammable. Burning produces irritating, toxic and obnoxious fumes. Vapour may travel considerable distance to source of ignition and flash back. Copyright 208 ChemSoft Limited. All rights reserved

3 date 3/ Advice for firefighters SECTION 6: Accidental release measures Wear protective clothing. Wear suitable respiratory equipment when necessary. 6.. Personal precautions, protective equipment and emergency procedures 6.2. Environmental precautions 6.3. Methods and material for containment and cleaning up SECTION 7: Handling and storage 7.. Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities SECTION 8: Exposure controls/personal protection 8.. Control parameters Ensure adequate ventilation of the working area. Wear suitable protective equipment. Eliminate all sources of ignition. Evacuate personnel to a safe area. Do not allow product to enter drains. Prevent further spillage if safe. Absorb with inert, absorbent material. Sweep up. Transfer to suitable, labelled containers for disposal. Clean spillage area thoroughly with plenty of water. Avoid contact with eyes and skin. Ensure adequate ventilation of the working area. Wear suitable protective clothing. Keep in a cool, dry, well ventilated area. Keep containers tightly closed. Store in correctly labelled containers Exposure Limit Values Butanone (Butan-2-one (methyl ethyl ketone)) WEL 8-hr limit ppm: 200 WEL 8-hr limit mg/m3: 600 WEL 5 min limit ppm: 300 WEL 5 min limit mg/m3: 899 WEL 8-hr limit mg/m3 total - WEL 5 min limit mg/m3 total - WEL 8-hr limit mg/m3 total - WEL 5 min limit mg/m3 total - Ethyl acetate WEL 8-hr limit ppm: 200 WEL 8-hr limit mg/m3: Exposure controls WEL 5 min limit ppm: 400 WEL 5 min limit mg/m3: - WEL 8-hr limit mg/m3 total - WEL 5 min limit mg/m3 total WEL 8-hr limit mg/m3 total - WEL 5 min limit mg/m3 total Appropriate engineering controls Individual protection measures Eye / face protection Skin protection - Handprotection Respiratory protection Ensure adequate ventilation of the working area. Wear chemical protective clothing. Approved safety goggles. Chemical resistant gloves. Wear suitable respiratory equipment when necessary. SECTION 9: Physical and chemical properties 9.. Information on basic physical and chemical properties Copyright 208 ChemSoft Limited. All rights reserved

4 4/5 9.. Information on basic physical and chemical properties Appearance Viscous liquid. Colour Clear Odour Characteristic Solubility Immiscible in water SECTION 0: Stability and reactivity 0.2. Chemical stability Stable under normal conditions Possibility of hazardous reactions Oxidising agents Conditions to avoid Heat, sparks and open flames. SECTION : Toxicological information.. Information on toxicological effects date Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation..4. Toxicological Information Polyethyl Methacrylate May cause irritation to skin. May cause irritation to eyes. May cause irritation to respiratory system. Oral Rat LD50: 5000 mg/kg No data is available on this product. SECTION 2: Ecological information No data is available on this product. SECTION 3: Disposal considerations General information Dispose of in compliance with all local and national regulations. Disposal methods Disposal of packaging For disposal within the EC, the appropriate code according to the European Waste Catalogue (EWC) should be used. Do NOT reuse empty containers. Empty containers can be sent for disposal or recycling. SECTION 4: Transport information The product is not classified as dangerous for carriage. SECTION 5: Regulatory information 5.. Safety, health and environmental regulations/legislation specific for the substance or mixture No data available. SECTION 6: Other information Copyright 208 ChemSoft Limited. All rights reserved

5 5/5 Other information Text of risk phrases in Section 3 Text of Hazard Statements in Section 3 date This document differs from the previous version in the following areas:. 2 - Disposal Advice for firefighters Precautions for safe handling. 8 - Skin protection - Handprotection. - Skin corrosion/irritation. - Respiratory or skin sensitisation. - Serious eye damage/irritation. 5 - Labelling. 5 - Symbols Safety, health and environmental regulations/legislation specific for the substance or mixture. R - Highly flammable. R20/22 - Harmful by inhalation and if swallowed. R36 - Irritating to eyes. R66 - Repeated exposure may cause skin dryness or cracking. R67 - Vapours may cause drowsiness and dizziness. EUH066 - Repeated exposure may cause skin dryness or cracking. Flam. Liq. 2: H225 - Highly flammable liquid and vapour. Eye Irrit. 2: H39 - Causes serious eye irritation. STOT SE 3: H336 - May cause drowsiness or dizziness. The information supplied in this Safety Data Sheet is designed only as guidance for the safe use, storage and handling of the product. This information is correct to the best of our knowledge and belief at the date of publication however no guarantee is made to its accuracy. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any other process. Copyright 208 ChemSoft Limited. All rights reserved