SAFETY DATA SHEET HYDROFIX WET
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1 Revision Date 23/03/12 Revision 1 Supersedes date 2010 SAFETY DATA SHEET SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Product No. N Relevant identified uses of the substance or mixture and uses advised against Identified uses Fount Solution 1.3. Details of the supplier of the safety data sheet Supplier STEHLIN HOSTAG INK UK LTD UNIT D4 LINKMEL CLOSE QUEENS DRIVE INDUSTRIAL ESTATE NOTTINGHAM NG2 1NA Tel : Fax : sds@stehlin.co.uk 1.4. Emergency telephone number SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical and Chemical Hazards Human health Environment Classification (1999/45/EEC) R43. Not classified. Skin Sens. 1 - H317 Not classified. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. Human health May cause sensitisation by skin contact 2.2. Label elements Contains A mixture of: 5-chloro-2-methyl-2 H -isothiazol-3-one(ec ) and 2-1.5%methyl-2-H- is othiazol-3one (EC ) 93;1) Label In Accordance With (EC) No. 1272/2008 Signal Word Hazard Statements Warning H317 May cause an allergic skin reaction. 1 / 6
2 Precautionary Statements 2.3. Other hazards P280 Wear protective gloves/protective clothing/eye protection/face protection. P IF ON SKIN: Wash with plenty of soap and water. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures A mixture of: 5-chloro-2-methyl-2 H -isothiazol-3-one(ec ) and 2-1.5%methyl-2-H- is othiazol-3one (EC ) 93;1) <0.1% CAS-No.: EC No.: Classification (EC 1272/2008) Acute Tox. 3 - H301 Acute Tox. 3 - H311 Acute Tox. 2 - H330 Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Skin Sens. 1 - H317 Classification (67/548/EEC) T;R23/24/25. Xi;R36/38. R43. 2-Bromo-2-Nitropopane-1,3-Diol < 0.5% CAS-No.: EC No.: Classification (EC 1272/2008) Acute Tox. 4 - H302 Acute Tox. 4 - H312 Skin Irrit. 2 - H315 Eye Dam. 1 - H318 STOT SE 3 - H335 Aquatic Acute 1 - H400 Classification (67/548/EEC) Xn;R21/22. Xi;R37/38,R41. N;R50. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures General information In case of doubt, or when symptoms persist, seek medical advice. In case of unconsciousness give nothing by mouth, place in recovery position and seek medical advice. Inhalation Remove to fresh air, keep patient warm and at rest. Ingestion Do not induce vomiting. If accidentally swallowed, obtain medical attention. Keep at rest. Skin contact Remove contaminated clothing. Wash skin thoroughly with soap and water or use recognised skin cleanser Do NOT use solvents or thinners Eye contact Irrigate copiously with clean fresh water, holding the eyelids apart and seek medical advice. Remove contact lenses, if present and easy to do. Continue rinsing Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed 2 / 6
3 SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog. Unsuitable extinguishing media Strong water jet Special hazards arising from the substance or mixture 5.3. Advice for firefighters Special Fire Fighting Procedures Cool closed containers that are near the source of the fire. Dike and collect extinguishing water. Protective equipment for fire-fighters Appropriate breathing apparatus may be required. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Ventillate the area Environmental precautions If the product contaminates lakes, rivers or sewages, inform competent authorities in accordance with local regulations. Do not allow to enter surface water or drains Methods and material for containment and cleaning up Clean with a detergent, preferably. Avoid the use of solvents. Contain and collect spillages with non-combustible absorbent material (e.g.sand, diatomaceous earth, vermiculite ) and place in container for disposal according to local regulations Reference to other sections See section 7 for information on safe Handling. See section 8 for information on personal protective equipment. See section 13 for disposal information. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Avoid inhalation of vapours. Smoking, eating and drinking should be prohibited in areas of storage and use. Comply with health and safety at work laws. Avoid concentrations higher than the occupational exposure limits (see section 8) 7.2. Conditions for safe storage, including any incompatibilities Keep containers tightly closed. No smoking Containers which are open must be carefully resealed and kept upright to prevent leakage. Store in accordance with national regulations concerning water pollution. Must be kept in orginal packaging. Store in dry, well ventillated area out of direct sunlgiht and away from sources of heat or ignition. Protect from frost 7.3. Specific end use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters 8.2. Exposure controls Engineering measures If relevant apply technical measures to comply with the OEL. This can be achieved by a good general extraction and - if practically feasible- by the use of a local exhaust ventilation. Respiratory equipment If the occupational exposure limits can't be met, in exceptional cases suitable respiratory protection should be worn only for a short period of time. 3 / 6
4 Hand protection There is no one glove material or combination of materials that will give unlimited resistance to any individual or combination of chemicals. Thickness of the glove material > 0.4mm; penetration time (maximum wearing period) > 480 min. Observe the instructions and details for use, storage, maintenance and replacement provided by the protective glove manufacturer. Penetration time of glove material dependant on intensity and duration of exposure to skin. Recommended glove articles: DIN EN 374. Barrier creams can help protecting exposed skin areas. In no case should they be used after contact. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. Eye protection Wear approved safety goggles. Skin protection All parts of the skin should be washed after contact. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Liquid Colour As Labelled Odour Characteristic. Initial boiling point and boiling 100 range Vapour pressure 23 Pa 20 Flash point > Other information SECTION 10: STABILITY AND REACTIVITY Reactivity Chemical stability Stable under normal temperature conditions and recommended use Possibility of hazardous reactions Conditions to avoid Incompatible materials Materials To Avoid Keep well away from oxidising agents and strongly alkaline or strongly acidic materials in order to avoid exothermic reactions Hazardous decomposition products Exposure to high temperatures may produce hazardous decomposition products such as :- Carbon Dioxide, Carbon Monoxide and smoke. SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects Skin contact Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin, resulting in skin dryness. May cause sensitisation by skin contact. Eye contact The liquid splashed in the eyes may cause irritation and reversible damage. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity Do not allow to enter drains and watercourses. 4 / 6
5 12.1. Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: DISPOSAL CONSIDERATIONS Waste treatment methods The users attention is drawn to the possible existence of regional or national regulations regarding disposal. This material and its container must be disposed of as hazardous waste Waste Class other solvents and solvent mixtures SECTION 14: TRANSPORT INFORMATION UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Chemical Safety Assessment No chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION Issued By B.A Hayden HSQE Manager Revision Date 23/03/12 Revision 1 Supersedes date 2010 SDS No Safety Data Sheet Status Approved. Date issued: 22/3/12 5 / 6
6 Risk Phrases In Full R21/22 R36/38 R37/38 R43 R41 R23/24/25 R50 Hazard Statements In Full H318 H319 H315 H330 H302 H312 H317 H335 H301 H311 H400 Harmful in contact with skin and if swallowed. Irritating to eyes and skin. Irritating to respiratory system and skin. May cause sensitisation by skin contact. Risk of serious damage to eyes. Toxic by inhalation, in contact with skin and if swallowed. Very toxic to aquatic organisms. Causes serious eye damage. Causes serious eye irritation. Causes skin irritation. Fatal if inhaled. Harmful if swallowed. Harmful in contact with skin. May cause an allergic skin reaction. May cause respiratory irritation. Toxic if swallowed. Toxic in contact with skin. Very toxic to aquatic life. Disclaimer This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 6 / 6
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