Conception et Fabrication de Produits Médicaux et Paramédicaux
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1 aa Conception et Fabrication de Produits Médicaux et Paramédicaux aasafety Data Sheet According to Regulation (EC) No. 1907/2006 (amended by Regulation (EU) No. 2015/830) Version: 1 Version date: 13/12/2016 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name / designation : NANOFIL - R&S. Article No (user) : 1605/1606/1607/1608/1609/1610 / 1615/1616/1617/1618/1619/ Relevant identified uses of the substance or mixture and uses advised against Dental Composite Details of the supplier of the safety data sheet Supplier 1.4 Emergency Telephone Number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] 2.2. Label elements Classification : CFPM Street: 2 bis Chemin du loup Postal code / City: Tremblay en France Country: France Telephone: +33 (0) Telefax: +33 (0) info@cfpm-medical.fr Hazard statements Skin Irrit. 2 H315 Causes skin irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. Eye Irrit. 2 H319 Causes serious eye irritation. Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms Signal word Warning Product identifiers - Hazard Statements H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. Supplemental Hazard information (EU) - Precautionary Statements - General - Precautionary Statements - Prevention P280 - Wear protective gloves/protective clothing/eye protection/face protection. Precautionary Statements - Response P302+P352 - IF ON SKIN: Wash with plenty of water/ P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332+P313 - If skin irritation occurs: Get medical advice/attention. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. Precautionary Statements - Storage - Precautionary Statements - Disposal - Page 1 sur 7
2 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance C (%) Classification Specific concentration Note limits 2-Propenoic acid, 2-methyl-, 1,2- ethanediylbis(oxy-2,1-ethanediyl) ester CAS N : EC N : IDX N : % C< 10.0% Skin Sens. 1: H317 STOT SE 3; H335: C 10 % - 2-Propenoic acid, 2-methyl-, (1- methylethylidene)bis[4,1- phenyleneoxy(2-hydroxy-3,1- propanediyl)] ester CAS N : EC N : IDX N : Mixtures 3.3. Remark Text phrases and H- EUH-: see section 16. SECTION 4: First aid measures 4.1. Description of first aid measures Following skin contact Following eye contact Following ingestion 5.0% C< 10.0% 4.2. Most important symptoms and effects, both acute and delayed Skin Irrit. 2: H315 Skin Sens. 1: H317 Eye Irrit. 2: H319 Page 2 sur 7 STOT SE 3; H335: C 10 % - : After contact with skin, wash immediately with plenty of water and soap. : After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult an ophthalmologist immediately. : Get medical advice/attention if you feel unwell Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters 5.4. Additional information SECTION 6: Accidental release measures : Foam. Extinguishing powder. Carbon dioxide (CO2). Sand. Water spray Personal precautions, protective equipment and emergency procedures Avoid contact with skin and eyes Environmental precautions Do not allow to enter into surface water or drains.
3 6.3. Methods and material for containment and cleaning up Wipe up with absorbent material (eg. cloth, fleece). Wash with plenty of water Reference to other sections 6.5. Additional information SECTION 7: Handling and Storage 7.1. Precautions for safe handling Protective measures Avoid contact with skin, eyes and clothes. Read label before use. Keep out of reach of children. Reserved for industrial and professional use. Advices on general occupational hygiene In the immediate working surroundings there must be: Provide eye shower and label its location conspicuously Conditions for safe storage, including any incompatibilities Keep container tightly closed C. Protect from sunlight Specific end uses SECTION 8: Exposure controls / personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls Personal protection equipment Eye/face protection Skin protection 8.3. Additional information SECTION 9: Physical and chemical Properties 9.1. Information on basic physical and chemical properties Physical state: Colour: Odour: Odour threshold: PH: Melting point/freezing point: Initial boiling point and boiling range: Flash point: Evaporation rate: Flammability: Upper/lower flammability or explosive limits: Vapour pressure: Vapour density: Relative density: : Suitable eye protection: Eye glasses. : When using do not eat, drink or smoke. Hand protection: By short-term hand contact: Disposable gloves. Body protection: Suitable protective clothing: Chemical protection clothing. Solid Colors: A1 / D2; A2 / B2; A3 / D3. A3.5 / B3; A4 / C4; C2 / C3 2.2 g/ml Page 3 sur 7
4 Solubility(ies): Partition coefficient: n-octanol/water (Log KOC): Auto-ignition temperature: Decomposition temperature: Viscosity: Explosive properties: Oxidising properties: 9.2. Other safety information SECTION 10: Stability and Reactivity Insoluble Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Protect from sunlight Incompatible materials Hazardous decomposition products Additional information SECTION 11: Toxicological information Acute oral toxicity 2-Propenoic acid, 2-methyl-, 1,2-ethanediylbis(oxy-2,1-ethanediyl) ester (CAS: ) Species : Rat subendpoint Operator Value Units LD mg/kg bw Acute skin toxicity Acute inhalation toxicity Skin corrosion Page 4 sur 7
5 11.5. Eye damage Skin sensitisation STOT RE STOT SE Carcinogenicity Reproductive and Developmental Toxicity genotoxicity Additional information Causes severe skin burns and eye damage. May cause an allergic skin reaction. Causes severe skin burns and eye damage. May cause an allergic skin reaction. SECTION 12: Ecological information Toxicity Based on available data, the classification criteria are not met Persistence and degradability The product has not been tested. Page 5 sur 7
6 12.3. Bioaccumulative potential The product has not been tested Mobility in soil The product has not been tested Results of PBT and vpvb assessment Other adverse effects Additional ecotoxicological information SECTION 13: Disposal considerations Waste treatment methods Product/Packaging disposal Waste treatment options: Appropriate disposal / Product: Can be incinerated together with household waste in compliance with applicable technical regulations following consultation with approved waste disposal managment companies and authorities in charge Additional information SECTION 14: Transport information UN number The product is not hazardous according to the applicable transport regulations (ADR / RID / ADN / IMDG / ICAO / ITA) UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Additional information SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Chemical Safety Assessment Additional information SECTION 16: Other information Page 6 sur 7
7 Creation date: 17/07/2017 Version date: 13/12/2016 Printing date: 17/07/ Indication of changes Not applicable (first edition of the MSDS) Abbreviations and acronyms ADN / ADNR: Regulations concerning the transport of dangerous substances in barges on the waterways. ADR / RID: European Agreement concerning the International Carriage of Dangerous Goods by Road / Regulations concerning the international carriage of dangerous goods by rail. CAS: Chemical Abstract Service Number. CLP: Classification, labeling and packaging. IATA: International Air Transport Association. IMDG: International Maritime Dangerous Goods Code. DPD Dangerous Preparation Directive. UN number: United Nations number. No EC: European Commission Number. VPvB: very persistent and very bioaccumulative substances Key literature references and sources for data Classification for mixtures and used evaluation method according to regulation (EC) 1272/2008 [CLP] Classification of the mixture is in accordance with the evaluation method described in Regulation (EC) No 1272/ Relevant R-, H- and EUH-phrases (Number and full text) H315 H317 H Training advice Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Refer to Sections 4, 5, 6, 7 and 8 of this safety data sheet Additional information The information given in this Safety Data Sheet is based on our present knowledge and on european and national regulations. This Safety Data Sheet describes safety requirements relative to identified uses, it doesn't guarantee all the product properties particularly in the case of non identified uses. The product mustn't be used for any uses other than those identified under heading 1. Since the user's working conditions are not known by us, it is the responsability of the user to take all necessary measures to comply with legal requirements for specific uses and avoid negative health effects. Page 7 sur 7
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