SAFETY DATA SHEET CRL RTV408 INDUSTRIAL AND CONSTRUCTION SILICONE WITHOUT FUNGICIDE

Transcription

1 Revision Date: SAFETY DATA SHEET CRL RTV408 INDUSTRIAL AND CONSTRUCTION SILICONE WITHOUT FUNGICIDE According to Regulation (EU) No 453/2010 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product Product No. CRL RTV408 INDUSTRIAL AND CONSTRUCTION SILICONE WITHOUT FUNGICIDE RTV408C, RTV408BRZ, RTV408AL, RTV408BGE, RGV408DT, RTV408BL 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Sealant 1.3. Details of the supplier of the safety data sheet Supplier: 1.4. Emergency telephone number +44 (0) Monday - Friday 08:00-17:00 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture C.R.Laurence of Europe Charles Babbage Avenue Kingsway Business Park Rochdale OL16 4NW Local Tel: Freephone: Local Fax: Freefax: crl@crlaurence.co.uk Classification (1999/45/EEC) Xi;R38, R41. R43. Human Health Risk of serious damage to eyes. Irritating to skin. The product contains a sensitising substance which may provoke an allergic reaction among sensitive individuals Label elements Contains: METHYLOXIMINO SILANE VINYLOXIMINO SILANE Labelling Irritant Risk Phrases Safety Phrases R38 R41 R43 Irritating to skin. Risk of serious damage to eyes. May cause sensitisation by skin contact. S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37/39 Wear suitable gloves and eye/face protection. S60 This material and its container must be disposed of as hazardous waste. 1 / 7

2 2.3. Other hazards CRL RTV408 INDUSTRIAL AND CONSTRUCTION SILICONE WITHOUT FUNGICIDE SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures 3-AMINOPROPYLTRIETHOXYSILANE % CAS-No.: EC No.: Acute Tox. 4 - H302 Skin Corr. 1B - H314 C;R34 Xn;R22 CARBON BLACK 0-0.2% CAS-No.: EC No.: Carc. 2 - H351 Carc. Cat. 3;R40. METHYLOXIMINO SILANE % CAS-No.: EC No.: Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Skin Sens. 1 - H317 Xi;R36/38. R43. VINYLOXIMINO SILANE % CAS-No.: EC No.: Skin Irrit. 2 - H315 Eye Dam. 1 - H318 Skin Sens. 1 - H317 Xi;R38,R41. R43. The Full Text for all R-Phrases and Hazard Statements is Displayed in Section 16 SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation. Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. Ingestion DO NOT INDUCE VOMITING! Rinse mouth thoroughly. Get medical attention. Skin Contact Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention if irritation persists after washing. Eye Contact Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention Most important symptoms and effects, both acute and delayed Inhalation. May cause irritation to the respiratory system. Vapours may cause headache, fatigue, dizziness and nausea. 2 / 7

3 Ingestion May cause discomfort if swallowed. Skin Contact Skin irritation. May cause sensitisation by skin contact. Eye Contact May cause severe irritation to eyes. Corneal damage Indication of any immediate medical attention and special treatment needed The severity of the symptoms described will vary dependant of the concentration and the length of exposure. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing Media Fire can be extinguished using: Water spray, fog or mist. Unsuitable Extinguishing Media Do not use water jet as an extinguisher, as this will spread the fire Special hazards arising from the substance or mixture Hazardous Combustion Products Not known. Unusual Fire & Explosion Hazards No unusual fire or explosion hazards noted. Specific Hazards Not noted Advice for firefighters Special Fire Fighting Procedures No specific fire fighting procedure given. Protective Measures In Fire Self contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Wear protective clothing as described in Section 8 of this safety data sheet Environmental precautions Do not discharge into drains, water courses or onto the ground Methods and material for containment and cleaning up Absorb in vermiculite, dry sand or earth and place into containers. Containers with collected spillage must be properly labelled with correct contents and hazard symbol Reference to other sections Wear protective clothing as described in Section 8 of this safety data sheet. See section 11 for additional information on health hazards. For waste disposal, see section 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Read and follow manufacturer's recommendations. Avoid spilling, skin and eye contact. Avoid inhalation of vapours. Wash hands after handling Conditions for safe storage, including any incompatibilities Store in tightly closed original container in a dry, cool and well-ventilated place Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters 3 / 7

4 STD TWA - 8 Hrs STEL - 15 Min Notes CARBON BLACK WEL 3,5 mg/m3 7 mg/m3 WEL = Workplace Exposure Limit Exposure controls Protective Equipment Engineering Measures Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit is not exceeded. Hand Protection Use protective gloves made of: Impermeable material. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. Eye Protection Wear approved safety goggles. Other Protection Wear appropriate clothing to prevent any possibility of skin contact. Hygiene Measures Promptly remove any clothing that becomes contaminated. Wash promptly if skin becomes contaminated. When using do not eat, drink or smoke. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Paste Colour Misc. colours Solubility Insoluble in water Relative Density Other information Volatile Organic Compound (VOC) 14% maximum g/litre SECTION 10: STABILITY AND REACTIVITY Reactivity Reaction with: Strong oxidising substances Chemical stability Stable under normal temperature conditions and recommended use Possibility of hazardous reactions Hazardous Polymerisation Will not polymerise Conditions to avoid Not noted Incompatible materials Materials To Avoid Strong oxidising substances Hazardous decomposition products Not noted. SECTION 11: TOXICOLOGICAL INFORMATION 4 / 7

5 11.1. Information on toxicological effects Inhalation May cause irritation to the respiratory system. Vapours may cause headache, fatigue, dizziness and nausea. Ingestion. May cause discomfort if swallowed. Nausea, vomiting. Skin Contact Irritating to skin. May cause sensitisation by skin contact. Eye Contact Risk of serious damage to eyes. Toxic Conc. - LC 50 Toxic Conc. - LC 50 3-AMINOPROPYLTRIETHOXYSILANE 1750 mg/kg (oral rat) 4000 mg/kg (der-rbt) CARBON BLACK <15400 mg/kg (oral rat) > 3000 mg/kg (der-rbt) METHYLOXIMINO SILANE 930 mg/kg (oral rat) > 1000 mg/kg (der-rbt) 20 mg/l/4h (inh-rat) VINYLOXIMINO SILANE 930 mg/kg (oral rat) > 1000 mg/kg (der-rbt) 20 mg/l/4h (inh-rat) SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity: The product components are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment Toxicity Persistence and degradability Degradability: There are no data on the degradability of this product Bioaccumulative potential Bioaccumulative Potential: No data available on bioaccumulation Mobility in soil Mobility: The product is insoluble in water Results of PBT and vpvb assessment Not determined Other adverse effects Not determined. 5 / 7

6 3-AMINOPROPYLTRIETHOXYSILANE LC 50, 96 Hrs, Fish mg/l IC 50, 72 Hrs, Algae, mg/l 1450 CARBON BLACK LC 50, 96 Hrs, Fish mg/l >1000 EC 50, 48 Hrs, Daphnia, mg/l > 5600 METHYLOXIMINO SILANE Ecotoxicity No data on possible environmental effects have been found. VINYLOXIMINO SILANE Ecotoxicity No data on possible environmental effects have been found. SECTION 13: DISPOSAL CONSIDERATIONS Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. Recover and reclaim or recycle, if practical. SECTION 14: TRANSPORT INFORMATION General UN number The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID) UN Proper shipping name 14.3 Transport hazard class(es) Packing group Environmental hazards Environmentally Hazardous Substance/Marine Pollutant No Special precautions for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Approved Code Of Practice Classification and Labelling of Substances and Preparations Dangerous for Supply. Guidance Notes Workplace Exposure Limits EH40. EU Legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments Chemical Safety Assessment No chemical safety assessment has been carried out. 6 / 7

7 SECTION 16: OTHER INFORMATION Revision Comments This is first issue. Issued By HS&E Manager. Revision Date Risk Phrases In Full R34 Causes burns. R22 Harmful if swallowed. R36/38 Irritating to eyes and skin. R38 Irritating to skin. R40 Limited evidence of a carcinogenic effect. R43 May cause sensitisation by skin contact. R41 Risk of serious damage to eyes. Hazard Statements In Full H318 Causes serious eye damage. H319 Causes serious eye irritation. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H302 Harmful if swallowed. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. 7 / 7