Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet NFPA HMIS Personal Protective Equipment 0 Health Hazard Fire Hazard 0 See Section 15. Section 1. Chemical Product and Company Identification Common Name/ Trade Name Manufacturer Commercial Name(s) Synonym Chemical Name Cassia oil SPECTRUM LABORATORY PRODUCTS INC. 144 S. SAN PEDRO STREET GARDENA, CA 9048 Cinnamon Oil; Oil of Cassia; Cinnamonium Cassia, oleoresin Cassia Oil Catalog Number(s). CAS# RTECS TSCA CI# CI15, C179, C FI TSCA 8(b) inventory: Cassia oil IN CASE OF EMERGENCY CHEMTREC (4hr) Page Number: 1 Chemical Family Chemical Formula Supplier SPECTRUM LABORATORY PRODUCTS INC. 144 S. SAN PEDRO STREET GARDENA, CA 9048 CALL (310) Section.Composition and Information on Ingredients Name CAS # Exposure Limits TWA (mg/m 3 ) STEL (mg/m 3 ) CEIL (mg/m 3 ) % by Weight 1) Cassia oil Toxicological Data on Ingredients Cinnamon oil: ORAL (LD50): DERMAL (LD50): Acute: 800 mg/kg [Rat]. 670 mg/kg [Mouse]. Acute: 30 mg/kg [Rabbit]. Section 3. Hazards Identification Potential Acute Health Effects Potential Chronic Health Effects Hazardous in case of skin contact (irritant, permeator), of eye contact (irritant). Slightly hazardous in case of ingestion, of inhalation. Severe over-exposure can result in death. CARCINOGENIC EFFECTS: MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. TERATOGENIC EFFECTS: DEVELOPMENTAL TOXICITY: Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in one or many human organs.

2 Cassia oil Page Number: Section 4. First Aid Measures Eye Contact Skin Contact Serious Skin Contact Inhalation Serious Inhalation Ingestion Serious Ingestion Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical attention. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. Seek medical attention. Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear. Section 5. Fire and Explosion Data Flammability of the Product Auto-Ignition Temperature Flash Points Flammable Limits Products of Combustion Fire Hazards in Presence of Various Substances Explosion Hazards in Presence of Various Substances Fire Fighting Media and Instructions Fire Hazards Explosion Hazards Combustible. CLOSED CUP: C (190 F). Flammable in presence of open flames and sparks, of heat. Non-flammable in presence of shocks. Risks of explosion of the product in presence of mechanical impact: Risks of explosion of the product in presence of static discharge: SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet. Section 6. Accidental Release Measures Small Spill Large Spill Absorb with an inert material and put the spilled material in an appropriate waste disposal. Combustible material. Poisonous liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.

3 Cassia oil Page Number: 3 Section 7. Handling and Storage Precautions Storage Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame). Sensitive to light. Store in light-resistant containers. Section 8. Exposure Controls/Personal Protection Engineering Controls Personal Protection Personal Protection in Case of a Large Spill Exposure Limits Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location. Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Section 9. Physical and Chemical Properties Physical state and appearance Liquid. Odor Cinnamon Molecular Weight ph (1% soln/water) Not applicable. Taste Color Yellowish to brown. Boiling Point Melting Point Critical Temperature Specific Gravity (Water = 1) Vapor Pressure Vapor Density Volatility Odor Threshold Water/Oil Dist. Coeff. Ionicity (in Water) Dispersion Properties Solubility Insoluble in cold water, hot water. Solubility in 70% Ethanol: 1 volume in 3 volumes of 70% Ethanol Section 10. Stability and Data Stability Instability Temperature Conditions of Instability Incompatibility with various substances Corrosivity The product is stable. Light, air, incompatible materials Non-corrosive in presence of glass.

4 Cassia oil Page Number: 4 Corrosivity Polymerization Light Sensitive. Air Sensitive. Darkens and thickens on exposure to air. No other information found. Will not occur. Section 11. Toxicological Information Routes of Entry Toxicity to Animals Chronic Effects on Humans Other Toxic Effects on Humans Toxicity to Animals Chronic Effects on Humans other Toxic Effects on Humans Absorbed through skin. Dermal contact. Eye contact. Inhalation. Acute oral toxicity (LD50): 670 mg/kg [Mouse]. Acute dermal toxicity (LD50): 30 mg/kg [Rabbit]. MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. Hazardous in case of skin contact (irritant, permeator). Slightly hazardous in case of ingestion, of inhalation. May affect genetic material (mutagenic) Acute Potential Health Effects: Skin: Causes skin irritation. May be absorbed through skin. Harmful if absorbed through skin. Eyes: Causes eye irritation. Inhalation: inhalation of vapor may cause respiratory tract irritation. Inhalation of high concentrations of vapor may cause anesthetic effects. Ingestion: May cause gastrointestinal tract irritation. Symptoms may include nausea, vomiting, diarrhea, buring sensation in mouth, chest, stomach, and rectal area, abdominal cramps, dizziness, double vision. May also affect cardiovascular system and respiration (acute pulmonary edema, respiratory stimulation). Section 1. Ecological Information Ecotoxicity BOD5 and COD Products of Biodegradation Toxicity of the Products of Biodegradation the Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Section 13. Disposal Considerations Waste Disposal Waste must be disposed of in accordance with federal, state and local environmental control regulations. Section 14. Transport Information DOT Classification Identification CLASS 6.1: Poisonous material. UNNA: 810 : Toxic Liquid, Organic, n.o.s. (Cassia Oil) PG: III Special Provisions for Transport

5 Cassia oil Page Number: 5 DOT Section 15. Other Regulatory Information and Pictograms Federal and State Regulations California Proposition 65 Warnings Other Regulations TSCA 8(b) inventory: Cassia oil California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: No products were found. California prop. 65: This product contains the following ingredients for which the State of California has found to cause birth defects which would require a warning under the statute: No products were found. OSHA: Hazardous by definition of Hazard Communication Standard (9 CFR ). Other Classifications WHMIS (Canada) CLASS B-3: Combustible liquid with a flash point between 37.8 C (100 F) and 93.3 C (00 F). CLASS D-1B: Material causing immediate and serious toxic effects (TOXIC). DSCL (EEC) R4- Toxic in contact with skin. R36/38- Irritating to eyes and skin. S6- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39- Wear suitable protective clothing, gloves and eye/face protection. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). HMIS (U.S.A.) Health Hazard Fire Hazard Personal Protection 0 h National Fire Protection Association (U.S.A.) Health 0 Flammability Specific hazard WHMIS (Canada) DSCL (Europe) TDG (Canada) ADR (Europe) Protective Equipment Gloves. Lab coat.

6 Cassia oil Page Number: 6 Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles. Section 16. Other Information MSDS Code References Other Special Considerations C4360 Validated by Sonia Owen on 10//007. Verified by Sonia Owen. Printed 8/13/009. CALL (310) Notice to Reader All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products, Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.