NEWTON SYSTEM LIQUID WATERPROOFING MEMBRANES

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1 DATA SHEET MSDS DoP System 100 NEWTON 110 WATSTOP (Part A) Rev May 2017 PRODUCT CODE Product and Company Identification PRODUCT IDENTIFIER Commercial name Newton 110 Watstop (Part A) Product type and use Epoxy resin Reach registration number Exempt Relevant identified uses of the substance and uses advised against Epoxy cement waterproofing Company Address Newton Waterproofing Systems, Newton House, Sovereign Way, Tonbridge, Kent TN9 1RH Web address of the competent person info@newtonwaterproofing.co.uk Emergency telephone number +44 (0) am - 5pm (GMT) Mon - Fri 2. Hazard Identification Irritant 3. Ingredients Composition/Information The product, if brought into contact with the eyes causes irritation that may last for over 24 hours, and if brought into contact with the skin it causes significant inflammation, erythema, scabs, edema or skin sensitisation. The product contains epoxy resins, which can cause cross sensitisation to other epoxy mixtures. Avoid breathing vapours. Toxic to aquatic organisms, it may cause long-term adverse effects in the aquatic environment. DANGEROUS SUBSTANCES FOR HEALTH IN ACCORDANCE WITH DIRECTIVE 67/548/EEC AND FOLLOWING ADJUSTMENTS OR FOR WHICH THERE ARE RECOGNISED EXPOSURE LIMITS AND THEIR RANKING: Chemical name Index No. CAS No. EC No. Epoxy Propyl Ester of Acetic Trialkyl Acid Epoxy Resin Hazardous to the environment REACH Registration Number Conc. (%w/w) % % Quartz Sand % 4. First-Aid Measures General Information Remove immediately all contaminated parts Classification N: R51/53 Xi: R43 N: R51/53 Xi: R36/38, R43 Page 1 of 14

2 NEWTON 110 WATSTOP (Part A) Inhalation Air the room. Immediately take the patient away from the contaminated area and let him rest in a well ventilated area. If the patient feels unwell, see a doctor Skin contact Immediately remove all contaminated clothing. Wash immediately with plenty of water and soap the areas of the body that have come into contact with the product, even if only suspected. Eye contact Wash immediately with plenty of running water, keeping eyelids open for at least 10 minutes. Protect the eyes with sterile gauze or a clean, dry tissue. See a doctor. Ingestion A suspension of activated charcoal suspended in water and medicinal paraffin mineral oil may be administered. 5. Fire Measures Suitable extinguishing Water, CO2, foam, or chemical powder, depending on the materials involved in the fire Forbidden fire extinguisher None in particular Combustion risks The original ingredients or unidentified toxic and/or irritant compounds may be present in the combustion fumes. Under conditions of incomplete combustion or pyrolysis, phenolic oxides and/or carbon monoxide can develop. Avoid breathing the fumes Protection measures Cool containers to prevent product decomposition and the development of substances potentially hazardous to health and safety. Always wear full fire prevention and use Use respiratory system protection 6. Accidental Release Measures Personal precautions Use mask, gloves and protective clothing Environmental precautions Contain spreading with sand or earth. Do not pour the product into pipes and water courses. If the product has entered a watercourse, sewer system or has contaminated soil or vegetation, please warn authorities. Clean up methods Quickly collect the product wearing protective clothing. Collect the product for reuse, if possible, or for safe disposal. Absorb the product with inert material such as earth or sand, and pour it into drums for storage. Consult local regulations before disposal. After the product has been stored, clean the area and the material used with water 7. Handling and Storage Handling Avoid contact and inhalation of vapours; see section 8. While working, avoid eating, drinking and smoking Incompatible materials None in particular Storage Store the product in premises at temperatures between 5 C and 35 C. Keep containers tightly closed Rooms indication Well ventilated rooms 8. Personal Protection/Exposure Control Precautions Adequately ventilate the premises where the product is stored and/or manipulated Page 2 of 14

3 NEWTON 110 WATSTOP (Part A) Respiratory protection If the room is not adequately ventilated, use respiratory system protection Hand protection Use protective rubber gloves Eye protection Avoid eye contact Skin protection Wear full protective clothes for skin. Change any contaminated clothes Exposure limite values of single components None All protective equipment must conform to EC standards (such as EN 374 for gloves and EN 166 for glasses), and be maintained and stored properly. The duration of use of devices for protection against chemical agents depends on several factors (type of use, climatic and storage conditions), which can considerably reduce the time required by the EC standards of usability. Always consult your protective equipment supplier. Train the employee to use the devices provided. 9. Physical and Chemical Properties Aspect Liquid Colour Light brown Smell Typical ph 6 Flammability liquid Partially flammable Flammability solid/gas - Boiling point - Flash point > 100 C Flammability limits in air (% in vol.) - Density 1.44kg/L (at 23 C) Water solubility Partially soluble Liposolubility Soluble Viscosity 69,200 mpa (at 20 C) 10. Stability and Reactivity Conditions to avoid Stable under normal conditions. Product can ignite if in contact with strong oxidising agents. Do not expose to direct sunlight or temperatures lower than 0 C 11. Toxicological Information Penetration methods Ingestion and inhalation Toxicological information No toxicological information is available at the moment on the product. In the evaluation of the toxicity of the preparation always keep in mind the concentration of the individual components specified in section 2 Corrosiveness/Irritation Eyes: Direct contact may cause temporary irritation Skin: Prolonged exposure during use may cause skin irritation Sensitisation: Possible with repeated contact Page 3 of 14

4 NEWTON 110 WATSTOP (Part A) More information Epoxy resins contained in this product are only a minor skin irritant, how ever all epoxy resins may cause skin sensitisation. Susceptibility to skin sensitisation varies from person to person: in a sensitised individual the allergic dermatitis may not appear initially, and may only appear after several days or weeks of frequent and/or prolonged contact. This is why contact with the skin should be avoided. Exposure to small amounts of material can cause erythema and edema 12. Ecological Information Biodegradability No experimental data available, but it is expected that the product is only partially biodegradable. Please follow good working practices and avoid dispersion into the environment List of substances that are dangerous to the environment: Chemical name Index No. CAS No. EC No. Epoxy Propyl Ester of Acetic Trialkyl Acid Epoxy Resin 13. Disposal Conc. (%w/w) % % Classification H411: Toxic to aquatic life with long-lasting effects H411: Toxic to aquatic life with long-lasting effects Recycle, if possible. Small quantities on the floor can be washed with water, great quantities must be collected using absorbent material (soil/sand) and pour it into drums for storage. Operate according to current local and national requirements: Disposal of hardened product (CER code) Disposal of non-hardended product (CER code) The European waste code suggested here is based on the composition of the product. According to the specific fields of application it may be necessary to assign a different code to the refuse. 14. Transport Information UN Number 3082 RID/ADR 9, III IMO/IMDG 9, III MAR/POL 73/78, annex III No ICAO/IATA 9, III 15. Regulatory Information DIRECTIVE CE/99/45 (CLASSIFICATION AND LABELLING): Symbols Xi: Irritant N: Dangerous for the environment R-phrases R36/38: Irritating to eyes and skin R43: May cause sensitisation by skin contact R51/53: Toxic to aquatic life with long-lasting effects Page 4 of 14

5 NEWTON 110 WATSTOP (Part A) S-phrases S24: Avoid contact with skin S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice S37: Wear suitable gloves S56: Dispose of this material and its container at a collection point for hazardous or special waste S57: Use appropriate container to avoid environmental contamination Special provisions The product contains epoxy resins. Read the information provided by the manufacturer 16. Further Information Main bibliography NIOSH - Registry of toxic effects of chemical substances (1983) National Institute of Health - Material Safety Data Sheets of organic solvents used in industrial technological processes (1985) National Institute of Health - National inventory of chemical substances ECDIN - Environmental chemicals data and information network - Joint research centre, Commission of the European Communities ACGIH - Threshold limit values (2000) SAX s - Dangerous properties of industrial materials - tenth edition The information enclosed therein is based on our knowledge at the above date. They are only reported to the indicated product and they do not consitute guarantee of special qualities. The user must make sure of the suitability of this information, and its completeness in relation to the specific use for which it is intended. This schedule revokes and replaces any previous edition. Disclaimer This Material Safet Data Sheet (MSDS) is based on the legal regulations listed in REACH Regulation (CE/1907/2006), and successive amendments and integration The information enclosed in this MSDS are based on the information reported in the MSDS of the raw materials that compose the product, and are based on our knowledge at the above date. The information relates only to the specific product and may not apply to the same when used in combination with other materials or in any process unless specified in the product safety data sheet They are only reported to the indicated product and they do not constitute guarantee of special qualities No statement or guarantee concerning accuracy, reliability and completeness of the information contained in this MSDS is released. The company does not assume any liability for damages to persons or property that may result from using the product other than that for which it was intended. The MSDS does not replace but complements the text or rules that regulate the activity of use The user must make sure of this information s suitability and completeness in relation to the specific use intended This schedule revokes and replaces any prevous edition Page 5 of 14

6 DATA SHEET MSDS DoP System 100 NEWTON 110 WATSTOP (Part B) Rev May 2017 PRODUCT CODE Product and Company Identification PRODUCT IDENTIFIER Commercial name Newton 110 Watstop (Part B) Product type and use Epoxy resin Reach registration number Exempt Relevant identified uses of the substance and uses advised against Epoxy cement waterproofing Company Address Newton Waterproofing Systems, Newton House, Sovereign Way, Tonbridge, Kent TN9 1RH Web address of the competent person info@newtonwaterproofing.co.uk Emergency telephone number +44 (0) am - 5pm (GMT) Mon - Fri 2. Hazard Identification Irritant 3. Ingredients Composition/Information The product, if brought into contact with the skin can cause skin sensitisation. DANGEROUS SUBSTANCES FOR HEALTH IN ACCORDANCE WITH DIRECTIVE 67/548/EEC AND FOLLOWING ADJUSTMENTS OR FOR WHICH THERE ARE RECOGNISED EXPOSURE LIMITS AND THEIR RANKING: Chemical name Index No. CAS No. EC No. n.n-dimethyl-1.3- diaminopropane 4. First-Aid Measures triazaundecano-1.11-diamino REACH Registration Number Conc. (%w/w) <3.2% <3.2% Classification C: R21/22, R34, R43 N: R52/53 C: R10, R22, R34, R43 Inhalation Air the room. Skin contact Immediately remove all contaminated clothing. Wash immediately with plenty of water and soap the areas of the body that have come into contact with the product, even if only suspected. Eye contact Wash immediately with plenty of running water, keeping eyelids open for at least 10 minutes. Page 6 of 14

7 NEWTON 110 WATSTOP (Part B) Ingestion Clean the mouth and drink a lot of water. In case of discomfort consult a doctor, showing this safety data sheet. A suspension of activated charcoal suspended in water and medicinal paraffin mineral oil may be administered 5. Fire Measures Forbidden fire extinguisher None in particular The product does not present a fire hazard Combustion risks The fumes that are released during a fire may contain ingredients as such or unidentified compounds toxic and/or irritating. The fumes may contain oxides of nitrogen. Avoid breathing the fumes Protection measures Always wear full fire prevention equipment and use protection for the respiratory system 6. Accidental Release Measures Personal precautions Use mask, gloves and protective clothing Environmental precautions Contain spreading with sand or earth. If the product has entered a water course, sewer system or has contaminated soil or vegetation, please warn authorities. Clean up methods Quickly collect the product wearing protective clothing. Do not pour the product into pipes and water courses. Collect the product for reuse, if possible, or for safe disposal. Absorb the product with inert material such as earth or sand, and pour it into drums for storage. After the product has been stored, clean the area and the material used with water 7. Handling and Storage Handling Avoid contact with eyes and skin. While working, avoid eating, drinking and smoking Incompatible materials None in particular Storage Do not store the product in direct sunlight or freezing conditions. Store at temperatures between 5 C and 35 C. Keep containers tightly closed Rooms indication Well ventilated rooms 8. Personal Protection/Exposure Control Precautions Adequately ventilate the premises where the product is stored and/or manipulated Respiratory protection Not necessary for normal use Hand protection Use protective rubber gloves Eye protection Avoid eye contact Skin protection Wear full protective clothes for skin. All protective equipment must conform to EC standards (such as EN 374 for gloves and EN 166 for glasses), and be maintained and stored properly. The duration of use of devices for protection against chemical agents depends on several factors (type of use, climatic and storage conditions), which can considerably reduce the time required by the EC standards of usability. Always consult your protective equipment supplier. Train the employee to use the devices provided. Page 7 of 14

8 NEWTON 110 WATSTOP (Part B) 9. Physical and Chemical Properties Aspect Semi dense Colour Yellowy Smell Typical ph 10 Flammability Self-extinguishable Boiling point 100 C Flammability limits in air (% in vol.) - Density 0.97kg/L (at 20 C) Water solubility Dispersible Liposolubility Insoluble Viscosity 200,000 mpa (at 20 C) 10. Stability and Reactivity Conditions to avoid Stable under normal conditions. Product can ignite if in contact with primary metals (alkali and alkaline earth) 11. Toxicological Information Penetration methods Ingestion and inhalation Contains strong reducing agents. The product can generate toxic gases in contact with oxidising mineral acids, halogenated organic substances, organic peroxides and hydroperoxides, and strong oxidising agents. The product can ignite if in contact with strong oxidising agents. Toxicological information No toxicological information is available at the moment on the product. In the evaluation of the toxicity of the preparation always keep in mind the concentration of the individual components specified in section 2 Corrosiveness/Irritation Eyes: Direct contact may cause temporary irritation Skin: Prolonged exposure during use may cause skin irritation Sensitisation: Possible with repeated contact Carcinogenesis: No effects Mutagenesis: No effects Teratology: No effects More information Susceptibility to skin sensitisation varies from person to person: in a sensitised individual the allergic dermatitis may not appear initially, and may only appear after several days or weeks of frequent and/or prolonged contact. This is why contact with the skin should be avoided. Exposure to small amounts of material can cause erythema and edema 12. Ecological Information Biodegradability No experimental data available, but it is expected that the product is only partially biodegradable. Toxicity to aquatic organisms No experimental data available, but it is expected that the product is not totally harmless. Please follow good working practices and avoid dispersion into the environment Page 8 of 14

9 NEWTON 110 WATSTOP (Part B) List of substances that are hazardous to the environment: Chemical name Index No. CAS No. EC No. Conc. (%w/w) Classification 13. Disposal triazaundecano-1.11-diamino <3.2% H412: Harmful to aquatic life with long-lasting effects Recycle, if possible. Operate according to current local and national requirements: Disposal of non-hardended product (CER code) The European waste code suggested here is based on the composition of the product. According to the specific fields of application it may be necessary to assign a different code to the refuse. 14. Transport Information UN Number - RID/ADR Not classified as dangerous goods IMO/IMDG Not classified as dangerous goods MAR/POL 73/78, annex III No ICAO/IATA Not classified as dangerous goods 15. Regulatory Information DIRECTIVE CE/99/45 (CLASSIFICATION AND LABELLING): Symbols Xi: Irritant R-phrases R21/22: Harmful if in contact with skin or ingested R34: Causes burns R43: May cause sensitisation by skin contact R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment S-phrases S24: Avoid contact with skin S37: Wear suitable gloves Content triazaundecano-1.11-diamino 16. Further Information Main bibliography NIOSH - Registry of toxic effects of chemical substances (1983) National Institute of Health - Material Safety Data Sheets of organic solvents used in industrial technological processes (1985) National Institute of Health - National inventory of chemical substances ECDIN - Environmental chemicals data and information network - Joint research centre, Commission of the European Communities ACGIH - Threshold limit values (2000) SAX s - Dangerous properties of industrial materials - tenth edition The information enclosed therein is based on our knowledge at the above date. They are only reported to the indicated product and they do not consitute guarantee of special qualities. The user must make sure of the suitability of this information, and its completeness in relation to the specific use for which it is intended. This schedule revokes and replaces any previous edition. Page 9 of 14

10 NEWTON 110 WATSTOP (Part B) Disclaimer This Material Safet Data Sheet (MSDS) is based on the legal regulations listed in REACH Regulation (CE/1907/2006), and successive amendments and integration The information enclosed in this MSDS are based on the information reported in the MSDS of the raw materials that compose the product, and are based on our knowledge at the above date. The information relates only to the specific product and may not apply to the same when used in combination with other materials or in any process unless specified in the product safety data sheet They are only reported to the indicated product and they do not constitute guarantee of special qualities No statement or guarantee concerning accuracy, reliability and completeness of the information contained in this MSDS is released. The company does not assume any liability for damages to persons or property that may result from using the product other than that for which it was intended. The MSDS does not replace but complements the text or rules that regulate the activity of use The user must make sure of this information s suitability and completeness in relation to the specific use intended This schedule revokes and replaces any prevous edition Page 10 of 14

11 DATA SHEET MSDS DoP System 100 NEWTON 110 WATSTOP (Part C) Rev May 2017 PRODUCT CODE Product and Company Identification PRODUCT IDENTIFIER Commercial name Newton 110 Watstop (Part C) Product type and use Epoxy resin Reach registration number Exempt Relevant identified uses of the substance and uses advised against Epoxy cement waterproofing Company Address Newton Waterproofing Systems, Newton House, Sovereign Way, Tonbridge, Kent TN9 1RH Web address of the competent person info@newtonwaterproofing.co.uk Emergency telephone number +44 (0) am - 5pm (GMT) Mon - Fri 2. Hazard Identification Irritant 3. Ingredients Composition/Information This product contains cement The product, if brought into contact with the eyes, causes irritation that may last for over 24 hours If inhaled causes irritation to the respiratory system If brought into contact with the skin causes significant inflammation with erythema, scabs, edema, and skin sensitisation DANGEROUS SUBSTANCES FOR HEALTH IN ACCORDANCE WITH DIRECTIVE 67/548/EEC AND FOLLOWING ADJUSTMENTS OR FOR WHICH THERE ARE RECOGNISED EXPOSURE LIMITS AND THEIR RANKING: Chemical name Index No. CAS No. EC No. REACH Registration Number Conc. (%w/w) Classification Alumina cement % Xi: R38/R41 4. First-Aid Measures Inhalation Immediately remove the patient from the contaminated premises and let them rest in a well ventilated area. Seek medical advice Skin contact Immediately remove all contaminated clothing. Wash immediately with plenty of water and soap the areas of the body that have come into contact with the product, even if only suspected. Eye contact Wash immediately with plenty of running water, keeping eyelids open for at least 10 minutes. Protect the eyes with a sterile gauze or a clean, dry tissue. See a doctor Page 11 of 14

12 NEWTON 110 WATSTOP (Part C) Ingestion Clean the mouth and drink a lot of water. A suspension of activated charcoal suspended in water and medicinal paraffin mineral oil may be administered 5. Fire Measures 6. Accidental Release Measures The product does not present a fire hazard Personal precautions None in particular; use gloves, a mask and protective clothing Environmental precautions Contain spreading with sand or earth. Do not pour the product into pipes and water courses If the product has entered a watercourse, sewer system or has contaminated soil or vegetation, please warn authorities Clean up methods Quickly collect the product wearing protective clothing. Collect the spill mechanically, avoiding excessive dust, before pouring into drums for storage. After the product has been collected, clean the area and the equipment used with water 7. Handling and Storage Handling Avoid contact with eyes and skin and exposure to high concentrations of dust. While working, avoid eating, drinking and smoking Incompatible materials Keep away from water or from wet areas Storage Store at temperatures between 5 C and 35 C. Keep containers tightly closed Rooms indication Well ventilated rooms 8. Personal Protection/Exposure Control Exposure limits TLV-TWA 10mg/m 3 (powder) Precautions Adequately ventilate the premises where the product is stored and/or manipulated Respiratory protection Not necessary for normal use. A dust mask during pouring is advisable Hand protection Use protective rubber gloves Eye protection Avoid eye contact Skin protection Wear full protective clothes for skin. 9. Physical and Chemical Properties Aspect Powder Colour Dark grey Smell Typical ph Flammability point > 1,270 C Boiling point - Auto-ignition - Flammability limits in air (% in vol.) - Real specific gravity 3.2g/cm 3 Page 12 of 14

13 NEWTON 110 WATSTOP (Part C) Bulk density 1.5g/cm 3 Solubility Partially soluble 10. Stability and Reactivity Conditions to avoid Stable under normal conditions Materials to avoid None in particular 11. Toxicological Information Penetration methods Ingestion and inhalation Toxicological information No toxicological information is available at the moment on the product. In the evaluation of the toxicity of the preparation always keep in mind the concentration of the individual components specified in section 2 Corrosiveness/Irritation Eyes: Direct contact may cause temporary irritation Skin: Prolonged exposure during use may cause skin irritation Sensitisation: Repeated contact with cement paste may cause dermatitis or eczema Carcinogenesis: No effects Mutagenesis: No effects Teratology: No effects More information The product contains cement. The cement in contact with sweat or other body fluids produces a strongly alkaline reaction. For this reason, contact with eyes and skin should be avoided 12. Ecological Information 13. Disposal 14. Transport Information UN Number - Please follow good working practice and avoid dispersion into the environment Recycle, if possible. Operate according to current local and national requirements RID/ADR Not classified as dangerous goods IMO/IMDG Not classified as dangerous goods MAR/POL 73/78, annex III No ICAO/IATA Not classified as dangerous goods 15. Regulatory Information DIRECTIVE CE/99/45 (CLASSIFICATION AND LABELLING): Symbols Xi: Irritant R-phrases R38: May cause irritation by skin contact R41: Risk of serious eye damage Page 13 of 14

14 NEWTON 110 WATSTOP (Part C) S-phrases S24/25: Avoid skin and eye contact S26: In case of eye contact, wash immediately with plenty of water and seek medical advice S37: Wear suitable gloves Special provisions The product contains high levels of alumina cement. Read the information provided by the manufacturer 16. Further Information Main bibliography NIOSH - Registry of toxic effects of chemical substances (1983) National Institute of Health - Material Safety Data Sheets of organic solvents used in industrial technological processes (1985) National Institute of Health - National inventory of chemical substances ECDIN - Environmental chemicals data and information network - Joint research centre, Commission of the European Communities ACGIH - Threshold limit values (2000) SAX s - Dangerous properties of industrial materials - tenth edition The information enclosed therein is based on our knowledge at the above date. They are only reported to the indicated product and they do not consitute guarantee of special qualities. The user must make sure of the suitability of this information, and its completeness in relation to the specific use for which it is intended. This schedule revokes and replaces any previous edition. Disclaimer This Material Safet Data Sheet (MSDS) is based on the legal regulations listed in REACH Regulation (CE/1907/2006), and successive amendments and integration The information enclosed in this MSDS are based on the information reported in the MSDS of the raw materials that compose the product, and are based on our knowledge at the above date. The information relates only to the specific product and may not apply to the same when used in combination with other materials or in any process unless specified in the product safety data sheet They are only reported to the indicated product and they do not constitute guarantee of special qualities No statement or guarantee concerning accuracy, reliability and completeness of the information contained in this MSDS is released. The company does not assume any liability for damages to persons or property that may result from using the product other than that for which it was intended. The MSDS does not replace but complements the text or rules that regulate the activity of use The user must make sure of this information s suitability and completeness in relation to the specific use intended This schedule revokes and replaces any prevous edition Page 14 of 14