Products for Personal Care

Transcription

1 Products for Personal Care

2

3 Contents Product Intelimer 8600 Intelimer IPA 13 1 / 13 6 Hybridur 875 Applications Sun Care Hair Care Low ph Systems Color Cosmetics Antiperspirant/Deodorant Other Markets

4 Have Questions? For Questions, Literature, and Samples: Air Products and Chemicals 7201 Hamilton Boulevard Allentown, PA USA Tel: (US) (Outside US) Fax: Web:

5 Intelimer 8600

6

7 INTELIMER 8600 Emulsion Polymer Description Intelimer 8600 emulsion polymer is an easy to use, low viscosity, high solids emulsion. It is thermally responsive and heat activated. Intelimer 8600 emulsion polymer exhibits flexible, water-resistant films above 40 C that become reversibly rigid and impermeable below 35 C. Applications Intelimer 8600 emulsion polymer has a variety of applications. Its effective controlled release of actives makes it valuable for various applications, like sun care. It is stable in low ph levels, making it useful in acne and anti-aging formulations. In hair care, it is designed for easy re-styling without shampoo and re-set using only a personal hair dryer. It improves curl retention, volume, humidity resistance and hold. Typical Properties (not to be used as specifications) Appearance Total Solids ph Melt Temperature Density (lbs/gal) 25 C (cps) Milky White Liquid % C Chemistry Advantages Intelimer 8600 polymer is a patented, side chain crystalline homopolymer with a long chain acrylate group in the back bone. Intelimer 8600 polymer has a very sharp melt point with small hysterisis. The polymer s temperature switch characteristics allows it to exhibit sharp changes in properties such as permeability, adhesion and viscosity over temperature ranges as narrow as narrow as 1 to 2 C. Advantages of Intelimer 8600 emulsion polymer include: INCI Name Reversible styling-restyling Exceptional humidity resistance and curl retention Easy wash out Compatible with Carbomer type rheology modifiers Improved retention of actives Enhanced SPF in Sun Care formulations Improved water resistance Stable in wide ph range including low ph levels Easy to use Intelimer 8600 Salicylic Acid Retention Study (in o/w emulsion with ph 3.5) C8-22 Alkyl Acrylate/Methacrylic Acid Crosspolymer Intelimer Temperature Switch Technology Intelimer technology allows for the design of a tailored trigger temperature (Tm) within a 0-70 C (± 1 C ) range which allows for: Triggered viscosity and flow control Triggered permeation, fragrance release and moisture permeation control Triggered ease of removal or wash-off Triggered waterproofing and gloss control Instron Stiffness of Curl by Gram Force Required During Unfurling the Curl from 1 to 50 Cyclese Control (no polymer) Using Intelimer % K90 2% PVP-VA 2% Polyquaternium 55 2% Intelimer 8600 Commercial #12 5 mins 10 mins 20 mins

8 Quick Start Guide Formulating Guidance Intelimer 8600 polymer is an easy to use polymer that can be added at any point in the formulation. Also, the polymer can be used across a wide range of temperature. Recommended use level as a styling polymer is 0.5 to 3%. Order of Addition No specific order of addition is required since Intelimer 8600 polymer can be incorporated at any point in the formulation. Remember Temperature is not a factor in working with the Intelimer 8600 emulsion polymer. Therefore, cold processing formulations can be prepared using the polymer. Intelimer 8600 polymer is in the form of white dispersion at ~50% solids. No neutralizer is required for Intelimer 8600 polymer. Intelimer 8600 polymer provides style-restyle properties (with the use of curling rod, flat iron, etc.) without requiring reapplication of the finished formulation. Intelimer 8600 polymer does not form clear gels. In working with ethanol or other alcohol systems, Intelimer 8600 needs to be dispersed in water before adding alcohol or alcohol/water mixture. Direct addition of Intelimer 8600 to ethanol or ethanol/water mixture will cause coagulation of the polymer. Storage / Shipping The product should be protected from freezing and should be sealed tightly in its container. Should air penetrate the container, product may form a dry film or dry polymer chuncks along the exposed surface. Please filter out this dry material using a cheese cloth. Product sold in 210 kgs containers. Larger quantities packaged to meet customer handling requirements. Handling Precautions Refer to the Material Safety Data Sheet for Intelimer 8600 emulsion polymer. For Samples or More Information If you would like additional information or technical assistance in preparing specific formulations, write or call Air Products and Chemicals, Inc. Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2008 Pub. No GLB-Sep08 The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto.

9 Intelimer IPA 13-1 / 13-6

10 Intelimer Polymers Temperature Switch Technology Intelimer IPA 13-1 and 13-6 Polymers Deliver new properties through Intelimer IPA 13-1 and 13-6 polymers Intelimer IPA 13-1 and 13-6 polymers are associative oil phase thickeners designed to thicken a wide variety of oil phase materials, including mineral oil, hydrogenated polyisobutylene (HPIB), vegetable oils, oil esters, and triglycerides. They are particularly effective in polar and nonpolar oils. Intelimer IPA 13-1 and 13-6 polymers also have a built-in temperature switch that enables change in properties, like viscosity, at a trigger temperature. For Antiperspirant/Deodorant Improved control and release of actives Nonwhitening property Rheology modifier in w/o and w/si emulsions Thickening agent in anhydrous stick formulations Intelimer 13-6 Formulation Commercial Product 1 Commercial Product 2 Black Leneta Chart Comparison on Whitening nonwhitening hazy whitening Aluminum Release Across Time Aluminum release (mg/l) Intelimer 13-6 Commercial Product 15 min 1 hr 2 hr 3 hr 4 hr 5 hr 6 hr For Lip Care Improved moisturization and silkiness Low tackiness and greasiness Ease of removal Light feel with easy spreadability Thickening agent Reduced migration of oils outside of lip area Enhanced pigment dispersion 1.5 x 10 8 Cooling Curve Viscosity [cp] Heating Curve Viscosity [cp] Thixotropic Profile of Anhydrous Gel with Intelimer 13-6 Heating and cooling curves showed immediate recrystallization and recovery, suggesting prevention of the migration of oils outside of the applied area. 1 x Temp [ºC]

11 INTELIMER IPA 13-1 Polymer Description Intelimer IPA 13-1 polymer is an associative oil phase thickener designed to thicken a wide variety of oil phase materials including mineral oil, hydrogenated polyisobutylene (HPIB), vegetable oils, oil esters, triglycerides, etc. It is particularly effective in nonpolar oils. Intelimer IPA 13-1 polymer has a built-in temperature switch (48 C) to allow change in properties at the trigger temperature. Applications Intelimer IPA 13-1 polymer is intended for cosmetic and personal care products across selected skin care, hair care and color cosmetics, applications and within several media including lotions, creams, and sticks. Ideal for: Modifying formulation texture, touch and feel Suspending small particles (e.g., pigments, beads, fillers) Modifying formulation hydrophobicity and viscosity Advantages Sensory modified texture, touch and feel Versatility thickener with added temperature switch Processability ease of mixing and use at convenient process temperatures Typical Properties (not to be used as specifications) Appearance White to Light Yellow Pellets Total Solids 100 % 93 C (cps) 650 Melt Temperature 48 C Chemistry Intelimer IPA 13-1 polymer is a patented, side chain crystalline homopolymer with a long chain acrylate group in the back bone. It has a very sharp melt point with small hysterisis. The polymer s temperature switch characteristics allow it to exhibit sharp changes in properties such as permeability, adhesion and viscosity over temperature ranges as narrow as 1 to 2 C. INCI Name Poly C10-30 alkyl acrylate Intelimer Temperature Switch Technology Intelimer technology allows for the design of a tailored trigger temperature (Tm) within a 0-70 C (± 1 C ) range which allows for: Triggered viscosity and flow control Triggered permeation, fragrance release and moisture permeation control Triggered ease of removal or wash-off Triggered waterproofing and gloss control Viscosity (cps at 25C) Figure 1. Viscosity of thickened hydrocarbon oils (Intelimer IPA 13-1/oil=10/90 by wt) Mineral oil IPP Triglyceride Finsolv TN Shear time (seconds) Viscosity (cps at 25C) Figure 2. Viscosity of emulsions (Intelimer IPA13-1/oil/DI water/mgso 4 =3/27/69.5/0.5 by wt) Mineral oil IPP Finsolv TN Shear time (seconds)

12 Quick Start Guide Formulating Guidance Intelimer IPA 13-1 polymer is added into the oil phase; it is soluble in the oil phase at 5 C above its melt temperature. The polymer has the ability to modify the rheology of emulsions. Recommended use level: 1-3% for emulsions, 3-15% for anhydrous formulations. Order of Addition In order to ensure maximum benefit and efficiency from the polymer, we recommend that you follow this order of addition: For w/o and w/si emulsion: 1. Combine Intelimer 13-1 and all other oil phase ingredients and melt while mixing. 2. Combine water phase ingredients in a separate vessel and heat to desired temperature. 3. Add water phase into oil phase while stirring and homogenize for 3 to 6 minutes. 4. Package at desired temperature. For o/w emulsion: 1. Combine Intelimer 13-1 and all other oil phase ingredients and melt while mixing. 2. Combine water phase ingredients in a separate vessel and heat to desired temperature. 3. Add oil phase into water phase while stirring and homogenize 3-6 minutes. 4. Package at desired temperature. For Anhydrous formulation: 1. Add all the ingredients, including the polymer, while mixing and heat to 55 C or to the desired melt temperature for all of the ingredients. 2. Continue to mix until all the ingredients are dissolved. 3. Cool to desired temperature and package. Remember Increasing the temperature above the polymer s melt point does not adversely affect polymer properties. No neutralizer is required when using Intelimer 13-1 polymer. For w/o and w/si emulsion, add a small amount of electrolyte (NaCl or MgSo4) into the water phase in order to enhance stability of the emulsion. For o/w emulsion a small amount of water-phase thickener is required to ensure elevated temperature stability. No water-phase thickener is required for w/o and w/si formulations. The final formulation needs to rest overnight to achieve stable viscosity. A small amount of plasticizer will enhance the flexibility of polymer film if desired. Storage / Shipping Store below 40 C to prevent melting or softening. Product sold as pellets melting about 48 C in five gallon pails containing 11kgs. Larger quantities packaged to meet customer handling requirements. Handling Precautions Refer to the Material Safety Data Sheet for Intelimer IPA 13-1 polymer. For Samples or More Information If you would like additional information or technical assistance in preparing specific formulations, write or call Air Products and Chemicals, Inc. Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2008 Pub. No GLB-Sep08 The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto.

13 INTELIMER IPA 13-6 Polymer Description Intelimer IPA 13-6 polymer is an associative oil phase thickener designed to thicken a wide variety of oil phase materials including mineral oil, hydrogenated polyisobutylene (HPIB), vegetable oils, oil esters, triglycerides, etc. It is particularly effective in nonpolar oils. Intelimer IPA 13-6 polymer has a built-in temperature switch (65 C) to allow change in properties at the trigger temperature. Applications Intelimer IPA 13-6 polymer is intended for cosmetic and personal care products across selected skin care, hair care and color cosmetic applications and within lotions, creams, and sticks. Ideal for: Modifying formulation texture, touch and feel Suspending small particles (e.g., pigments, beads, fillers, etc.) Modifying formulation hydrophobicity and viscosity Advantages Sensory modified texture, touch and feel Versatility thickener with added temperature switch Processability ease of mixing and use at convenient process temperatures Typical Properties (not to be used as specifications) Appearance White to Light Yellow Pellets Total Solids 100 % 93 C (cps) 600 Melt Temperature 65 C Chemistry Intelimer IPA 13-6 polymer is a patented, side chain crystalline homopolymer with a long chain acrylate group in the back bone. It has a very sharp melt point with small hysterisis. The polymer s temperature switch characteristics allows it to exhibit sharp changes in properties such as permeability, adhesion and viscosity over temperature ranges as narrow as 1 to 2 C. INCI Name Poly C10-30 alkyl acrylate Intelimer Temperature Switch Technology Intelimer technology allows for the design of a tailored trigger temperature (Tm) within a 0-70 C (± 1 C ) range which allows for: Triggered viscosity and flow control Triggered permeation, fragrance release and moisture permeation control Triggered ease of removal or wash-off Triggered waterproofing and gloss control Viscosity (cps at 25C) Figure 1. Viscosity of thickened hydrocarbon oils (Intelimer IPA 13-6/oil=10/90 by wt) Mineral oil IPP Triglyceride Finsolv TN Shear time (seconds) Thixotropic Profile 13-6 of Anhydrous Sunscreen Stick Temp Gel with Ramp Intelimer 13-6 Heating Curve Cooling Curve Viscosity ( ) [cp] Viscosity ( ) [cp] 1.5x10 8 1x10 8 Heating and cooling curves showed immediate recrystallization and recovery suggesting prevention of the migration of oils outside of the applied area Temp [ C]

14 Quick Start Guide Formulating Guidance Intelimer IPA 13-6 polymer is added into the oil phase; it is soluble in the oil phase at 5 C above its melt temperature. The polymer has the ability to thicken both o/w and w/o emulsions. Recommended use level: 1-3% for emulsions, 3-15% for anhydrous formulations. Order of Addition In order to ensure maximum benefit and efficiency from the polymer, we recommend that you follow this order of addition: For w/o and w/si emulsion: 1. Combine Intelimer 13-6 polymer and all other oil phase ingredients and melt while mixing. 2. Combine water phase ingredients in a separate vessel and heat to desired temperature. 3. Add water phase into oil phase while stirring and homogenize for 3 to 6 minutes. 4. Package at desired temperature. For o/w emulsion: 1. Combine Intelimer 13-6 polymer and all other oil phase ingredients and melt while mixing. 2. Combine water phase ingredients in a separate vessel and heat to desired temperature. 3. Add oil phase into water phase while stirring and homogenize 3 to 6 minutes. 4. Package at desired temperature. Remember Increasing the temperature above the polymer s melt point does not adversely affect polymer properties. No neutralizer is required when using Intelimer 13-6 polymer. For w/o and w/si emulsion, add a small amount of electrolyte (NaCl or MgSo4) into the water phase in order to enhance stability of the emulsion. For o/w emulsion a small amount of water-phase thickener is required to ensure elevated temperature stability. No water-phase thickener is required for w/o and w/si formulations. The final formulation needs to rest overnight to achieve stable viscosity. A small amount of plasticizer will enhance the flexibility of polymer film if desired. Storage / Shipping Store below 60 C. Product sold as pellets melting about 65 C in five gallon pails containing 11kgs. Larger quantities packaged to meet customer handling requirements. Handling Precautions Refer to the Material Safety Data Sheet for Intelimer IPA 13-6 polymer. For Anhydrous formulation: 1. Add all the ingredients, including the polymer, while mixing and heat to 70 C or to the desired melt temperature for all of the ingredients. 2. Continue to mix until all the ingredients are dissolved. 3. Cool to desired temperature and package. For Samples or More Information If you would like additional information or technical assistance in preparing specific formulations, write or call Air Products. Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2008 Pub. No GLB-Sep08 The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto.

15 Hybridur 875

16 Intelimer Polymers Temperature Switch Technology Hybridur 875 Polymer Dispersion Enhance your products with Hybridur 875 Polymer Dispersion Hybridur 875 polymer dispersion is a patented urethane-acrylic polymer. It is an excellent film-former, providing transfer resistance and water resistance for a wide variety of personal care formulations. The product provides enhanced performance properties when compared with conventional urethanes and urethane/acrylic emulsion polymers. For Skin Care Water resistance and rub-off resistance Improved dispersibility of pigments and actives Compatible with a wide variety of ingredients Easy to use Film-forming For Hair Care Flexible, durable properties, making it excellent as a styling polymer Improved stiffness and durability in high humidity conditions Enhanced gloss and clarity Compatible with wide set of ingredients

17 Hybridur 875 Polymer Dispersion Description Hybridur 875 polymer dispersion is a patented urethane-acrylic polymer dispersion. It exhibits excellent wetting, adhesion and barrier and film properties in a wide variety of Personal Care formulations. The product provides enhanced performance properties when compared with conventional urethanes and urethane/acrylic emulsion polymers. Applications Hybridur 875 polymer dispersion is intended for cosmetic and personal care products for skin care, hair care and color cosmetics including lotions, creams, gels, sticks, etc. Ideal for Imparting water resistance in skin care formulations Providing transfer resistance and long-lasting rub off resistance in skin care formulations Improving dispersability of pigments and actives Providing durable hold and high humidity resistance in hair care formulations Providing high stiffness and glossy clear film in hair care formulations Advantages Flexible, durable film forming polymer on skin and hair Water resistance Transfer resistance and long-lasting property on skin formulations Hair care formulations that are exceptionally stiff and durable at high humidity conditions Hair care formulations with high gloss and clarity Suitable in a variety of skin care formulations including creams, lotions, and gels Suitable to be formulated in cold process formulations Compatible with a wide variety of ingredients Easy to use Solvent and preservation free Typical Properties (not to be used as specifications) Viscosity (Brookfield cps) Total Solids 38-42% Density (g/ml) ph Particle size 75-80nm Particle Charge Anionic Acid Value 14-15mg KOH/g based on solids Chemistry Hybridur 875 polymer dispersion is anionically stabilized aliphatic urethane-acrylic hybrid polymer dispersion. It is easy to formulate and offers excellent film forming properties such as adhesion, durability, flexibility, toughness, clarity and gloss. Hybridur 875 polymer dispersion s unique film forming properties make it suitable for use in a variety of personal care formulations including skin care, hair care and color cosmetics. Formulations based on Hybridur 875 polymer dispersion have also been found to exhibit better dispersability of sunscreen actives and pigments and able to provide water resistance and rub-off resistance properties in emulsions and gel formulations. INCI Name Polyurethane-2 and Polymethyl Methacrylate Quick Start Guide In emulsions and gel formulations, Hybridur 875 polymer dispersion can be added to the water phase, or at the end of the formulation. The polymer can be formulated at any temperature. It is compatible with ethanol. Remember Hybridur 875 polymer dispersion is pre-neutralized; so neutralization is not required. Storage / Shipping Protect From Freezing Handling Precautions None

18 For Samples or More Information If you would like additional information or technical assistance in preparing specific formulations, write or call Air Products and Chemicals, Inc. Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2008 Pub. No GLB-Sep08 The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto.

19 Sun Care

20 Sun Care: Heat Up Your Label Claims The global sun care market is expected to grow nearly 6% per year through Are your products positioned to meet increasingly multifaceted consumer needs? Consider Intelimer temperature trigger technology. Our Intelimer 8600 emulsion polymer s unique structure boosts SPF and improves water resistance to ensure continuity of sun protection. Its unique temperature trigger technology improves retention of actives, enabling a more environmentally friendly solution that utilizes lower chemical levels. Its properties can also improve rheology and tackiness in formulations. Don t get burned. Check out for yourself what Air Products and Intelimer technology can offer your formulations. Visit the website below for more information and sample offers. Or call in the U.S. and Canada or Enhancing Competitive Positioning with Intelimer Technology Increased awareness of sun exposure-related health risks, coupled with broader incorporation of sun protection across skin, hair, and lip categories, has helped to spur growth of the sun care market. Air Products Intelimer polymer offering not only helps formulators enhance traditional sun protection qualities, but also provides flexibility to extend across other product categories. Key Trends in Sun Care Product efficacy is paramount, as health risks increase product scrutiny by the public, private, and nonprofit sectors Ease of use, including qualities such as runniness and tackiness, becomes a more distinguishing feature Continued innovation of technological platform becomes possible as newer active ingredients are explored to deliver increased protection levels Extension of sun protection across product categories How Intelimer 8600 Polymer Can Help Enhances efficacy through increased SPF protection and through its water-resistance and controlled-release properties Improves the texture of formulations, particularly those exacerbated by heat, such as runniness Operates across a variety of actives, providing a platform-neutral means for controlled release Is successfully utilized across various product markets, including hair care and lip care For samples or more information: If you would like additional information or technical assistance in preparing specific formulations, write or call: Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2008 (30245) US

21 Triggered Wash-Off Sunscreen Emulsion with Intelimer 8600 Polymer Formulating Guide U001 Description Triggered Wash-Off Sunscreen Emulsion with Intelimer 8600 is designed to be a flexibly water resistant sunscreen with good sensory benefits. Intelimer 8600 polymer is a hydrophobic film forming polymer with the unique benefits of water and rub-off resistance at low temperatures but easy wash-off when triggered by a preset higher temperature, such as that of a hot water shower. The polymer also provides SPF enhancement. Typical Properties (not to be used as specifications) Appearance White emulsion ph 6.3 Stability Passed 4 month 50 C Viscosity (cps) (Spindle 10 rpm) 12,900 14,000 In-vitro static SPF and SPF after 80 mins immersion using Intelimer 8600 in Formulation U001 Before immersion After 80 mins immersion In Vitro SPF Control (no (no polymer) Ganex V220 Intelimer 8600 SPF testing was conducted by IMS Inc. All samples were tested using the IMS Inc In-Vitro Waterproof Protocol. In-Vitro SPF measurements made both prior to, and after the samples have been immersed in a controlled temperature water bath at 40 C while agitated at 300 rpm for 80 minutes. Please note that these conditions are slightly more aggressive than typical In-vivo waterproof test conditions.

22 Ingredient / Trade Name INCI Designation %W/W Function Supplier Phase A Mineral Oil Mineral Oil USP 2.0 Emollient Polawax Emulsifying Wax NF 5.0 Emulsifier Croda Lipocol S-2 Steareth Emulsifier Lipo Lipocol S-21 Steareth Emulsifier Lipo Crodacol C-70 Cetyl Alcohol 1.0 Stabilizer Croda Uvinul MC 80 Octinoxate 7.5 Sunscreen Active BASF Uvinul M 40 Oxybenzone 6.0 Sunscreen Active BASF Neo Heliopan OS Octisalate 5.0 Sunscreen Active Symrise Phase B Deionized Water Deionized Water 68.7 Keltrol CG-T Xanthan Gum 0.3 Thickener CP Kelco Intelimer 8600 (49.13% solids) Germaben II Poly C8-22 Alkyl Acrylate/ Metacrylic Acid Cross Polymer Propylene Glycol, Diazolidinyl Urea, Methylparben, Propylparben 2.0 Film former/enhance retention of actives Air Products 1.0 Preservative ISP Procedure 1. Combine all Phase A ingredients into a vessel while stirring mixture. 2. In another vessel add deionized water then slowly add xanthan gum while stirring. Continue to stir until clear homogenous mixture forms. 3. Add other remaining Phase B ingredients one by one to gum mixture while continuing to stir. 4. Begin heating both vessels until the temperature of both vessels is between C. Once a C temperature has been achieved add Phase A to Phase B slowly while continuing to stir the mixture. 5. Remove from heat and homogenize the resulting emulsion for three minutes. 6. Let the emulsion cool to the desired temperature. 7. Adjust the ph with Triethanolamine (TEA 99%) and package. For Samples or More Information If you would like additional information or technical assistance in preparing specific formulations, write or call Air Products and Chemicals, Inc. Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2008 Pub. No GLB-Sep08 The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto.

23 Extra Protection Super Silky Sunscreen Lotion with Intelimer 8600 Polymer Formulating Guide U002 Description Extra Protection Super Silky Sunscreen Lotion with Intelimer 8600 polymer is designed to be a luxurious sun screen lotion that provides excellent wash off resistance along with wonderful sensory properties. The unique benefits of Intelimer 8600 in this formulation is that it improves wash off resistance and enhances SPF. Typical Properties (not to be used as specifications) Appearance White cream ph 6.6 Stability Passed 4 month 50 C Viscosity (cps) (Spindle 10 rpm) 41,000 50,000 In-vitro static SPF and SPF After 80 Mins Immersion Using Intelimer 8600 Formulation U002 Competitor poly Control (no poly) Intelimer 8600 In Vitro SPF SPF testing was conducted by IMS Inc. All samples were tested using the IMS Inc In-Vitro Waterproof Protocol. In-Vitro SPF measurements made both prior to, and after the samples have been immersed in a controlled temperature water bath at 40 C while agitated at 300 rpm for 80 minutes. Please note that these conditions are slightly more aggressive than typical in-vivo waterproof test conditions.

24 Ingredient/Trade Name INCI Designation %W/W Function Supplier Phase A Isopropyl Myristate Isopropyl Myristate 2.5 Emollient Finsolv TN C12-15 Alkyl Benzoate 3.0 Solublizer Innospec Mineral Oil USP Mineral Oil 3.5 Emollient T-Lite SF Titanium dioxide (and) Aluminum Hydroxide 1.2 Sun Screen BASF (and) Dimethicone Methicone copolymer Active Uvinul MC 80 Octinoxate 7.5 Sunscreen Active BASF Uvinul M 40 Oxybenzone 5.25 Sunscreen Active BASF Neo Heliopan OS Octisalate 4.75 Sunscreen Active Symrise Pristerene 4911 Stearic Acid 1.8 Stabilizer Croda Crodacol S-95 Stearyl Alcohol 2.2 Stabilizer Croda Stepan GMS Pure Glyceryl Stearate 2.0 Emulsifier Stepan Amphisol K Potassium Cetyl Phosphate 1.0 Emulsifier DSM Phase B Deionized Water Deionized Water 57.6 Keltrol CG-T Xanthan Gum 0.2 Thickener CP Kelco Veegum K Magnesium Aluminum Silicate 0.2 Intelimer 8600 (49.13% solids) Poly C8-22 Alkyl Acrylate/ Metacrylic Acid Cross Polymer 2.0 Film Former and SPF Enhancer Air Products Crotein C Hydrolyzed Collagen 0.15 Active Croda Germaben II Propylene Glycol, Diazolidinyl Urea, 1.0 Preservative ISP Methylparaben, Propylparaben Phase C Ceraphyl SLK Isodecyl Neopentanoate 1.0 Emollient ISP Alpha Tocopherol Vitamin E 0.5 Antioxident BASF Aloe Extract in Cyclomethicone 1.0 Active Bell Flavour & Fragrance Phase D D Panthenol Panthenol 0.5 Skin Protectant BASF Natural Alpha Bisabolol Alpha Bisabolol 0.10 Active Dow Corning 193 PEG-12 Dimethicone 1.0 Emollient Dow Corning Procedure 1. Combine all Phase A ingredients into a vessel while stirring mixture. 2. In another vessel add deionized water then slowly add xanthan gum while stirring. Continue to stir until clear homogenous mixture forms. 3. Add other remaining Phase B ingredients one by one to gum mixture while continuing to stir. 4. Begin heating both vessels until the temperature of both vessels is between C. Once a C temperature has been achieved add Phase A to Phase B slowly while continuing to stir the mixture. 5. Remove from heat and homogenize the resulting emulsion for three minutes. 6. Once the homogenized emulsion has cooled to 35 C add Phase C ingredients one by one while continuing to stir. 7. Once the above mixture has cooled to room temperature add Phase D ingredients one by one while continuing to stir. 8. Adjust the ph with Triethanolamine (TEA 99%) and package. For Samples or More Information If you would like additional information or technical assistance in preparing specific formulations, write or call Air Products. Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2008 Pub. No GLB-Sep08 The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto.

25 Sunscreen Lotion with Titanium Dioxide and Intelimer 8600 Polymer Formulating Guide U003 Description Sunscreen Lotion with Titanium Dioxide and Intelimer 8600 polymer is designed to be a high SPF sun screen lotion that provides excellent wash off resistance and sensory properties. The unique benefit of Intelimer 8600 in this formulation is that it improves wash off resistance and enhances SPF. Procedure 1. Combine all Phase A ingredients into a vessel while stirring. 2. In another vessel add deionized water then slowly add xanthan gum and PemulinTR-2 while stirring. Continue to stir until clear homogenous phase. 3. Add other remaining Phase B ingredients one by one to water phase while continuing to stir. Typical Properties (not to be used as specifications) Appearance White cream ph 6.8 Viscosity (cps) (Spindle 10 rpm) 20,000 50, Begin heating both vessels until the temperature of both vessels is between C. Once a C temperature has been achieved, add Phase A to Phase B slowly while continuing to stir. 5. Remove from heat and homogenize the resulting emulsion for three minutes. Ingredient/ Trade Name INCI Designation % w/w Function Supplier Phase A Ceraphyl 368 Ethylhexyl Palmitate 10.0 Emollient ISP Uvinul N539T Octocrylene 8.0 Sunscreen Active BASF Uviniul MC80 Octinoxate 7.5 Sunscreen Active BASF Uvinul M40 Oxybenzone 5.0 Sunscreen Active BASF Finsolv TN C12-15 Alkyl Benzoate 5.0 Solublizer Innospec Permethyl 222C C13-15 Alkane (and) C12-20 Isoparaffin 2.0 Emollient Presperse Dow Corning 245 Cyclomethicone 2.0 Emollient Dow Corning Dow Corning 556 Phenyltrimethicone 2.0 Emollient Dow Corning Cosmowax J Cetearyl Alcohol (and) Ceteareth Emulsifier Croda Crodacol C-70 Cetyl Alcohol 1.0 Stabilizer Croda T-Lite SF Titanium dioxide 10.0 Sunscreen Active BASF Phase B Deionized Water Deionized Water 41.4 Diluent Keltrol CG-T Xanthan Gum 0.2 Thickener CP Kelco Pemulin TR-2 Acrylates/C10-30 Alkyl Acrylate Crosspolymer 0.1 Emulsifier Lubrizol Intelimer 8600 (1% solids) Poly C8-22 Alkyl Acrylate/ Metacrylic Acid Cross Polymer 2.0 Film Former and SPF Enhancer Air Products Pricerine 9088 Glycerine 99.5% 2.0 Humectant Uniquema

26 For Samples or More Information If you would like additional information or technical assistance in preparing specific formulations, write or call Air Products and Chemicals, Inc. Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2008 Pub. No GLB-Sep08 The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto.

27 Sunscreen Lotion with Zinc Oxide and Intelimer 8600 Polymer Formulating Guide U004 Description Sunscreen Lotion with Zinc Oxide and Intelimer 8600 polymer is designed to be a high SPF sun screen lotion that provides excellent wash off resistance and sensory properties. The unique benefit of Intelimer 8600 in this formulation is that it improves wash off resistance and enhances SPF. Procedure 1. Combine all Phase A ingredients into a vessel while stirring mixture. 2. In another vessel add deionized water then slowly add xanthan gum and PemulinTR-2 while stirring. Continue to stir until clear homogenous phase. 3. Add other remaining Phase B ingredients one by one to water phase while continuing to stir. Typical Properties (not to be used as specifications) Appearance White cream ph 6.8 Stability Passed 4 month 50 C Viscosity (cps) (Spindle 10 rpm) 20,000 50, Begin heating both vessels until the temperature of both vessels is between C. Once a C temperature has been achieved add Phase A to Phase B slowly while continuing to stir. 5. Remove from heat and homogenize the resulting emulsion for three minutes. 6. Adjust ph as necessary with Citric Acid 10% solution. Ingredient INCI designation % w/w Function Supplier Phase A Cetiol LC Coco Caprylate (and) Coco Caprate 5.0 Emollient Cognis Uviniul MC80 Octinoxate 7.5 Sunscreen Active BASF Uvinul M40 Oxybenzone 6.0 Sunscreen Active BASF Neo Heliopan OS Octasalicylate 5.0 Sunscreen Active BASF Dodecamethyl Dow Corning 246 Cyclohexasiloxane 1.2 Emollient Dow Corning Crodacol 1618 Ctearyl Alcohol 4.5 Stabilizing Agent Croda Incropol CS-20 Cetearth Emulsifier Croda Zinclear -IM 50AB Zinc Oxide 15.0 Sunscreen Active Dow Chemical Dow Corning 200/50cst Dimethicone 4.2 Emollient Dow Corning Potassium Cetyl Phosphate 2.0 Emulsifier DSM Amphisol K Phase B Deionized Water Deionized Water 43.6 Diluent Keltrol CG-T Xanthan Gum 0.25 Thickener CP Kelco Pemulin TR-2 Acrylates/C10-30 Alkyl Acrylate Crosspolymer 0.25 Emulsifier Lubrizol Intelimer 8600 (1% solids) Poly C8-22 Alkyl Acrylate/ Metacrylic Acid Cross Polymer 2.0 Film Former and SPF Enhancer Air Products Pricerine 9088 Glycerine 99.5% 2.0 Humectant Uniquema Citric Acid anhydrous 10% solution 1.1 ph Adjuster

28 For Samples or More Information If you would like additional information or technical assistance in preparing specific formulations, write or call Air Products and Chemicals, Inc. Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2008 Pub. No GLB-Sep08 The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto.

29 Hair Care

30 Hair Care... Durability and Flexibility She doesn t want to worry about her curls. And she shouldn t have to. With global sales of styling agents exceeding $2 billion and the overall hair care market exceeding $10 billion in 2007, meeting her needs means meeting the needs of several others... several million, that is. Are your products ready? Consider adding Intelimer 8600 emulsion to your formulations. It offers benefits like enhanced curl durability and stiffness, even in high humidity; improved gloss and clarity; anti-frizz properties; low tackiness; and easy wash-off. Don t miss the wave. Check it out for yourself and see what Air Products and Intelimer technology can offer your formulations. Visit the website or call in the U.S. and Canada or Enhancing Your Competitive Positioning with Intelimer Technology Hair care remains a lucrative segment of personal care despite relatively more modest growth rates. Success under such competitive dynamics requires differentiation in functionality and capability. Air Products offerings can provide differentiable benefits while enabling flexibility for the future. Key Trends in Hair Care Increasing value penetration in specific niche segments like ethnic hair, through positioning and tailored functionality Broader functionality of hair care products as consumers demand more all-in-one solutions Use of fragrances and other nonfunctional qualities to drive product extensions Key Benefits of Intelimer 8600 Polymer Curl Durability High Humidity Resistance Gloss and Clarity Easy Wash-off Highly Compatible with Common Hair Care Ingredients Anti-frizz Styling/Restyling Low Tackiness How Air Products Can Help Products to meet niche needs, such as the curly hair and styling-restyling submarkets Solutions for deposition of hair-enhancing ingredients Products that improve delivery of fragrances and other ingredients For samples or more information: If you would like additional information or technical assistance in preparing specific formulations, write or call: Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2008 (30246) US

31 Hair Conditioning Cream with Intelimer 8600 Polymer Formulating Guide No. H001 Description Hair Conditioning Cream with Intelimer 8600 polymer has the dual function of conditioning and styling with easy to comb properties. The unique benefit of Intelimer 8600 polymer is superior hold while enabling style-restyle without the need for reapplication. This formulation can be used effectively with a curling iron or flat iron. Typical Properties (not to be used as specifications) Appearance White emulsion ph 6.84 Stability Passed 4 month 50 C Viscosity (cps) Brookfield RVT, 10 RPM, 25 C, Spindle D) 32,000-42,000 Instron Stiffness of Curl After 50 Cycles (Load in Grams of Force, 2% Polymer) Intelimer 8600 Polyquternium 55 PVP/VA Commercial Pomade Load in Grams of Force Curled hair tresses coated with different styling agents were subject to a series of controlled extensions in a controlled environment using Instron. Each hair tress was extended to a straight conformation before release. This force required to uncurl the hair tresses is directly proportional to the polymer curl. As evident above, a styling cream based on Intelimer 8600 shows significantly higher stiffness than competing alternatives. This along with its style / restyle capability makes products with Intelimer 8600 ideal for hair care.

32 Ingredient / Trade Name INCI Designation %W/W Function Supplier Deionized Water Water (Aqua) Diluent Carbopol 980 Carbomer 0.5 Thickener Noveon Intelimer 8600 C8-22 Alkyl Acrylate/ Methacrylic Acid Cross Polymer 2.1 Fixative Air Products Triethanolamine TEA (99%) 0.75 Neutralizer Ashland Dow Corning 556 Phenyl Trimethicone 0.5 Conditioner Dow Corning Dl Panthenol Panthenol 0.5 Conditioner BASF Dow Corning 1411 Cyclopentasiloxane(and) Dimethicone 1.0 Conditioner Dow Corning Glydant DMDM Hydantoin 0.5 Preservative Lonza Procedure 1. Disperse Carbomer into water while stirring and gently mix until it is fully dispersed. 2. Add all other ingredients including Intelimer 8600 polymer one-by-one while stirring and gently mix for fifteen to twenty minutes. 3. Fill into desired package. For Samples or More Information If you would like additional information or technical assistance in preparing specific formulations, write or call Air Products. Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2008 Pub. No GLB-Sep08 The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto.

33 Hair Combing Cream with Intelimer 8600 Polymer Formulating Guide No. H002 Description Hair Combing Cream with Intelimer 8600 polymer is designed to give non-tacky, easy to comb, anti-frizz, curl definition, and memory with flexibility properties to hair. Intelimer 8600 polymer provides the ability to style-restyle hair without reapplication of finished product. Typical Properties (not to be used as specifications) Appearance White emulsion ph 6.84 Stability Passed 4 month 50 C Viscosity (cps) Brookfield RVT, 10 RPM, 25 C, Spindle D) 32,000-42,000 Instron Stiffness of Curl After 50 Cycles (Load in Grams of Force, 2% Polymer) Intelimer 8600 Polyquternium 55 PVP/VA Commercial Pomade % Curl Retention A humidity curl retention test conducted at 90% humidity shows that styling and combing creams based on Intelimer 8600 polymer exhibit better humidity resistance and curl definition when compared with competitive and commercial products.

34 Ingredient / Trade Name INCI Designation %W/W Function Supplier Deionized Water Water (Aqua) Diluent Carbopol 980 Carbomer 0.5 Thickener Noveon Triethanolamine TEA (99%) 0.75 Neutralizer Ashland Glycerin Glycerin 2.0 Intelimer 8600 C8-22 Alkyl Acrylate/ Methacrylic Acid Cross Polymer 4.1 Fixative Air Products Jeesilc DMC 19-3 PEG-12 Dimethicone 0.5 Conditioner Jeen Intl Dow Corning 200/50 Dimethicone 2.0 Emollient Dow Corning Incroquat CTC-30 Cetrimonium Chloride 0.5 Conditioner Croda Germaben II Propylene Glycol, Diazolidinyl Urea, Methylparben, Propylparaben 0.5 Preservative Sutton Lab Procedure 1. Disperse Carbomer into water while stirring and gently mix until it is fully dispersed. 2. Add all other ingredients including Intelimer 8600 polymer one-by-one while stirring and gently mix for fifteen to twenty minutes. 3. Fill into desired package. For Samples or More Information If you would like additional information or technical assistance in preparing specific formulations, write or call Air Products and Chemicals, Inc. Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2008 Pub. No GLB-Sep08 The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto.

35 Hair Molding Cream with Intelimer 8600 Polymer Formulating Guide No. H003 Description Hair Molding Cream with Intelimer 8600 polymer is designed to give weightless styling and long lasting hold properties with exceptional smoothness. Intelimer 8600 polymer provides the ability to stylerestyle the hair without reapplication of finished product. This formulation can be used effectively with a curling iron or flat iron. Typical Properties (not to be used as specifications) Appearance White emulsion ph 4.2 Stability Passed 4 month 50 C Viscosity (cps) Brookfield RVT, 10 RPM, 25 C, Spindle D) 21,000-24,000 Average Stiffness at 50% Humidity And 73 F Temperature Peak Force (N) PVP K90 K30 PVP/VA PQ 55 Intelimer 8600 (1%) Intelimer 8600 (2%) An Instron Texture Analyser with 3-point bend fixture was used on hair tresses coated with different styling agents. Each hair tress was rested on two supports that were 50.8mm apart (2.0 inches). As evident from above, a styling cream based on Intelimer 8600 shows very good performance when compared with competing alternatives.

36 Ingredient / Trade Name Phase A Crodafos CES Abil OSW5 INCI Designation %W/W Function Supplier Cetearyl Alcohol (and) Dicetyl Phosphate (and) Ceteth-10 Phosphate Cyclopentasiloxane (and) Dimethiconol 6.0 Emulsifier Croda 2.5 Conditioner Degussa Isopropyl Myristate Isopropyl Myristate 10.0 Emollient Jojoba Oil Simmondsia Chinensis (Jojoba) Oil 0.5 Conditioner Desert Whale SF 1204 Cyclotetrasiloxane and Cyclopentasiloxane 4.3 Emollient Momentive Wheat Germ Oil Triticum Vulgare (Wheat) Germ Oil 0.5 Conditioner Desert Whale Phase B Deionized Water Water (Aqua) 66.6 Diluent Keltrol CG-T Xanthan Gum 0.8 Thickener CP Kelco Intelimer 8600 C8-22 Alkyl Acrylate/Methacrylic Acid Cross Polymer 6.2 Fixative Air Products Dow Corning 193 Fluid PEG-12 Dimethicone 2.0 Conditioner Dow Corning Glydant DMDM Hydantoin 0.5 Preservative Lonza Triethanolamine TEA (99%) 0.1 Neutralizer Ashland Procedure 1. Combine Phase A ingredients in a vessel and heat with agitation to C. 2. Disperse Xanthan Gum in Deionized Water in a separate vessel. 3. Add remaining Phase B ingredients into above vessel and heat with agitation to C. 4. Slowly add Phase A to Phase B while mixing. 5. Cool to desired fill temperature and package. For Samples or More Information If you would like additional information or technical assistance in preparing specific formulations, write or call Air Products and Chemicals, Inc. Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2008 Pub. No GLB-Sep08 The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto.

37 Hair Pomade with Intelimer 8600 Polymer Formulating Guide H004 Description Hair Pomade with Intelimer 8600 polymer is designed to give non-tacky, touchable and long lasting style. Intelimer 8600 polymer provides the ability to stylerestyle the hair without reapplication of product. Typical Properties (not to be used as specifications) Appearance White emulsion ph 4.01 Stability Passed 4 month 50 C Viscosity (cps) Brookfield RVT, 10 RPM, 25 C, Spindle D) 17,000-18,000 Low Tack Properties of Intelimer 8600 Polymer Intelimer 8600 PVP K90 A tack test developed to demonstrate tack properties of hair swatches coated with styling cream demonstrates that a styling cream based on Intelimer 8600 polymer exhibits significantly reduced tack versus an industry standard styling cream based on PVP K90.

38 For Samples or More Information If you would like additional information or technical assistance in preparing specific formulations, write or call Air Products. Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2008 Pub. No GLB-Sep08 The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto.

39 Hair Styling Cream with Intelimer 8600 Polymer Formulating Guide No. H005 Description Hair Styling Cream with Intelimer 8600 polymer is designed to give flexible curl, anti-frizz, and curl memory. Intelimer 8600 polymer provides the ability to style-restyle without reapplication of finished product. This formulation can be used effectively with a curling iron or flat iron. Typical Properties (not to be used as specifications) Appearance White emulsion ph 7.32 Stability Passed 4 month 50 C Viscosity (cps) Brookfield RVT, 10 RPM, 25 C, Spindle D) 35,000-42,100 Hair Swatches Following Anti-Frizz Test An anti-frizz test conducted at 70% humidity suggests that creams based on Intelimer 8600 polymer perform better when compared with competitive alternatives.

40 Ingredient / Trade Name INCI Designation %W/W Function Supplier Deionized Water Water (Aqua) Diluent Carbopol 980 Carbomer 0.5 Thickener Noveon Intelimer 8600 C8-22 Alkyl Acrylate/ Methacrylic Acid Cross Polymer 2.1 Fixative Air Products Triethanolamine TEA (99%) 0.75 Neutralizer Ashland Dow Corning 556 Phenyl Trimethicone 0.5 Conditioner Dow Corning Glydant DMDM Hydantoin 0.5 Preservative Lonza Procedure 1. Add Carbomer into water while stirring and let it disperse fully. 2. Combine all other ingredients including Intelimer 8600 polymer one-by-one and let it mix for fifteen to twenty minutes. 3. Fill into desired package. For Samples or More Information If you would like additional information or technical assistance in preparing specific formulations, write or call Air Products and Chemicals, Inc. Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2008 Pub. No GLB-Sep08 The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto.

41 Anhydrous Ethnic Hair Gel with Intelimer 13-1 Polymer Formulating Guide No. H006 Description Anhydrous Ethnic Hair Gel with Intelimer 13-1 polymer is designed to provide a conditioning, glossy appearance that is non-greasy with a silky look and feel. Procedure 1. Combine all the ingredients in the order listed except the preservative while stirring. 2. Then increase temperature of mixture to 60 C while stirring. Let Intelimer IPA 13-1 polymer dissolve completely. 3. Add preservative once the mixture has cooled to 45 C. Continue to cool to desired temperature and package. Typical Properties (not to be used as specifications) Appearance Anhydrous gel ph N/A Stability Passed 4 month 50 C Viscosity (cps) Anhydrous gel Note: To improve hand clarity of Intelimer anhydrous gel % of PEG-4 is recommended. The PEG-4 can be added along with the other ingredients while stirring and heating. Warning: Higher amount of PEG-4 are not recommended due to the fact higher level can cause the formulation to become unstable. Ingredient / Trade Name INCI Designation %W/W Function Supplier Mineral Oil Drakeol 7LT Mineral Oil 19.7 Conditioner Penreco Finsolv TN C12-15 Alkyl Benzoate 6.0 Solublizer Innospec Caprylic/Capric Triglyceride Caprylic/Capric Triglyceride 10.8 Conditioner Isopropyl Palmitate Isopropyl Palmitate 30.0 Conditioner Rita Eutanol G Octyldodecanol 16.5 Conditioner Momentive SF 1202 Cyclopentasiloxane 4.3 Shine Enhancer GE Silicones Uninol MC 80 Octinoxate 7.5 UVB Active BASF Intelimer IPA 13-1 Poly C10-30 alkyl acrylate 5.0 Thickener Air Products LiquaPar oil Isopropylparaben (and) Isobutylparaben (and) Butylparaben 0.2 Preservative ISP

42 For Samples or More Information If you would like additional information or technical assistance in preparing specific formulations, write or call Air Products and Chemicals, Inc. Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2008 Pub. No GLB-Sep08 The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto.

43 Scalp Treatment Serum with Intelimer 13-1 Polymer Formulating Guide No. H007 Description Hair Serum with Intelimer 13-1 polymer is designed to provide nourishment, conditioning and moisturizing to the scalp. Intelimer 13-1 polymer is used as an oil phase thickener to provide a non-drip formulation. Procedure 1. Combine all the ingredients in the below order except for the preservative while stirring. 2. Heat the mixture to 60 C while stirring. 3. Wait until the Intelimer IPA 13-1 is dissolved completely then start to cool. 4. Add preservative once the mixture has cooled to 45 C. Continue to cool to desired temperature and package. Typical Properties (not to be used as specifications) Appearance Anhydrous gel ph N/A Stability Passed 4 month 50 C Viscosity (cps) Anhydrous gel Note: To improve hand clarity of Intelimer anhydrous gel % of PEG-4 is recommended. The PEG-4 can be added along with the other ingredients while stirring and heating. Warning: Higher amount of PEG-4 is not recommended due to the fact higher level can cause the formulation to become unstable. Ingredient / Trade Name INCI Designation %W/W Function Supplier Mineral Oil Drakeol 7LT Mineral Oil 63.5 Conditioner Penreco Jojoba Oil Simmondsia Chinensis (Jojoba) Oil 16.0 Conditioner Jeen Intl Sawflower Oil Carthamus Tinctorius (Sawflower) Oil 16.5 Essential oil Jeen Intl Avocado Oil Persea Gratissima (Avocado) Oil 0.3 Essential oil Desert Whale Tea Tree Oil Evening Primerose Oil Melaleuca Alternifolia (Tea Tree) Leaf Oil Oenothera Biennis (Evening Primerose) Oil 0.3 Essential oil Desert Whale 0.2 Essential oil Desert Whale Intelimer IPA 13-1 Poly C10-30 alkyl acrylate 3.0 Thickener Air Products LiquaPar Oil Isopropylparaben (and) Isobutylparaben (and) Butylparaben 0.2 Preservative ISP

44 For Samples or More Information If you would like additional information or technical assistance in preparing specific formulations, write or call Air Products and Chemicals, Inc. Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2008 Pub. No GLB-Sep08 The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto.

45 Low ph Systems

46 Low ph Systems: Acne, Antiaging Beauty through Persistance Consumers are impatient for results, but we know most beauty actives work only with persistent exposure. Intelimer technology s controlled release of actives can help by extending the retention of actives on skin over longer time periods. Low ph systems encompass several fast-growing segments, notably antiaging and acne. Both are growing well above global GDP, with acne expected to grow over 4.5% per year and antiaging reaching double digits. Are your products positioned to capitalize on this growth? Consider Intelimer temperature trigger technology. Our Intelimer 8600 polymer improves controlled release of actives such as salicylic and glycolic acids, which can make products effective for longer periods of time and hence lead to more visible results. Intelimer 8600 polymer also enables a more environmentally friendly solution that utilizes the lower overall concentration of active chemicals. Enhanced water resistance and sensory benefits further make it a smart choice for formulators. For beauty that is skin deep check it out for yourself. See what Air Products and Intelimer technology can offer your formulations. Visit our website or call in the U.S. and Canada or Enhancing Competitive Positioning with Intelimer Technology Consumer age demographics and disposable incomes are positioning acne and antiaging as growth platforms for many consumer product companies. But continued interest depends upon consumers achieving visible results from these products. Air Products Intelimer polymer offering can enhance results by enabling actives to act more thoroughly and over a longer period of time. Intelimer also provides other attributes which are beneficial for different product formulations. Key Trends in Acne & Antiaging Shift to multifunctional products, thereby reducing the number of products consumers must purchase and use Continued concerns about long-term impact of actives How Intelimer 8600 Can Help Is successfully utilized across various product markets, including hair care and lip care Enables similar product performance with fewer actives For samples or more information: If you would like additional information or technical assistance in preparing specific formulations, write or call: Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: Product efficacy being enhanced through increased compliance awareness and bundling of product kits Can enhance compliance by reducing the frequency of product reapplication tell me more Air Products and Chemicals, Inc., 2008 (30247) US

47 Acne Treatment Cream with Intelimer 8600 Polymer Formulating Guide S001 Description Acne Treatment Cream with Intelimer 8600 is designed to be a leave on cream with excellent sensory benefits. Intelimer 8600 is a hydrophobic film forming polymer which works effectively in low ph systems. The unique benefit of Intelimer 8600 in this formulation is the effective retention of salicylic acid. Typical Properties (not to be used as specifications) Appearance White cream ph 3.5 to 4.2 Stability Passed 4 month 50 C Viscosity (cps) (Spindle 10 rpm) 21,500 22,000 Intelimer 8600 Salicylic Acid Retention Study Study using Using Formula S001 S001 Average % Salicylic Acid Retained 5mins 10 mins 20 mins Salicylic Acid retention study was conducted using in-vitro skin. Test was conducted on in-vitro skin by applying 2mg/cm2 of emulsion. Extraction of Salicylic Acid was conducted using DI water. Measurements of Salicylic acid were conducted on HPLC Water Alliance Model 2695 using supelcosil LC-18 column. The mobile phase was prepared by using 1:1 mixture of DI water and methanol.

48 Ingredient / Trade Name INCI Designation %W/W Function Supplier Phase A Isopropyl Myristate Isopropyl Myristate 10.0 Emollient Jojoba Oil Simmodsia Chinensis (Jojoba Oil) 1.0 Conditioner Jeen Intl SF1202 Cyclopentasiloxane 5.0 Emollient Momontive Crodafos CES Cetearyl Alcohol (and) Dicetyl Phosphate (and) 6.0 Emulsifiers Croda Ceteth-10 Phosphate Abil EM 97 Bis-PEG/PPG-14/14 Dimethicone 2.5 Emulsifiers Evonik Apricote Kernel Oil Prunus Armeniaca 0.4 Conditioner Desert Whale Sweet Almond Oil (Apricot) Kernel Oil Prunus Amygdalus Dulceis (Sweet Almond) Oil 0.6 Conditioner Desert Whale Phase B Deionized Water Water (Aqua) 68.5 Diluent Keltrol CG-T Xanthan Gum 0.9 Rheology Modifier CP Kelco Salicylic Acid Powder Salicylic Acid 2.0 Acne Active Intelimer 8600 (49.13% solids) Germaben II Poly C8-22 Alkyl Acrylate/ Metacrylic Acid Cross Polymer Propylene Glycol, Diazolidinyl Urea, Methylparben, Propylparben 2.1 Film former/enhance retention of actives Universal Preservative Air Products 1.0 Preservative ISP Procedure 1. Combine all Phase A ingredients into a vessel while stirring mixture. 2. In another vessel add deionized water then slowly add xanthan gum and salicylic acid while stirring. Continue to stir until clear homogenous mixture forms. 3. Add other remaining Phase B ingredients one by one to the gum and acid mixture while continuing to stir. 4. Begin heating both vessels until the temperature of both vessels is between C. Once a C temperature has been achieved add Phase A to Phase B slowly while continuing to stir the mixture. 5. Remove from heat and homogenize the resulting mixture for three minutes. 6. Let the emulsion cool to the desired temperature. 7. Adjust the ph with few drops of Triethanolamine (TEA 99%) and package. For Samples or More Information If you would like additional information or technical assistance in preparing specific formulations, write or call Air Products. Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2008 Pub. No GLB-Sep08 The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto.

49 Acne Treatment Lotion with Intelimer 8600 Polymer Formulating Guide S002 Description Acne Treatment Lotion with Intelimer 8600 is designed to be a leave on lotion with excellent sensory benefits. Intelimer 8600 polymer is a hydrophobic film forming polymer which works effectively in low ph systems. The unique benefit of Intelimer 8600 in this formulation is effective retention of salicylic acid. Typical Properties (not to be used as specifications) Appearance White lotion ph 3.5 to 4.2 Stability Passed 4 month 50 C Viscosity (cps) (Spindle 10 rpm) 4,600 5,000 Intelimer 8600 Salicylic Acid Retention Study Using Formula S002 Average % Salicylic Acid Retained 1min 2mins 5 mins Salicylic Acid retention study was conducted using in-vitro skin. Test was conducted on in-vitro skin by applying 2 mg/cm2 of emulsion. Extraction of Salicylic Acid was conducted using DI water. Measurements of Salicylic Acid were conducted on HPLC Water Alliance Model 2695 using supelcosil LC-18 column. The mobile phase was prepared by using 1:1 mixture of DI water and methanol.

50 Ingredient / Trade Name INCI Designation %W/W Function Supplier Phase A Mineral Oil USP Mineral Oil 12.5 Emollient Rite Aid Arlacel P135 PEG-30 dipolyhdroxy stearate 1.0 Emulsifier Croda Lipocol S-2 Steareth Emulsifier Lipo Lipocol S-21 Steareth Emulsifier Lipo Dow Corning 200/50cst Dimethicone 4.5 Emollient Dow Corning Finsolv TN C12-15 Alkyl Benzoate 4.5 Solublizing Agent Innospec Phase B Deionized Water Water (Aqua) 71.0 Salicylic Acid Powder Salicylic Acid 2.0 Acne Active Universal Preservative Keltrol G-T Xanthan Gum 0.9 Rheology Modifier CP Kelco Intelimer 8600 Poly C8-22 Alkyl Acrylate/ Film former/enhance 2.1 (49.13% solids) Metacrylic Acid Cross Polymer retention of actives Air Products DMDM Hydantoin Glydant plus Liquid 0.5 Preservative Lonza Procedure 1. Combine all Phase A ingredients into a vessel while stirring mixture. 2. In another vessel add deionized water then slowly add xanthan gum and salicylic acid while stirring. Continue to stir until clear homogenous mixture forms. 3. Add other remaining Phase B ingredients one by one to acid mixture while continuing to stir. 4. Begin heating both vessels until the temperature of both vessels is between C. Once a C temperature has been achieved add Phase A to Phase B slowly while continuing to stir the mixture. 5. Remove from heat and homogenize the mixture for three minutes. 6. Let the emulsion cool to the desired temperature. 7. Adjust the ph with Triethanolamine (TEA 99%) and package. For Samples or More Information If you would like additional information or technical assistance in preparing specific formulations, write or call Air Products. Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2008 Pub. No GLB-Sep08 The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto.

51 Extra Moisturizing Acne Treatment Night Cream with Intelimer 8600 Polymer Formulating Guide S003 Description Extra Moisturizing Acne Treatment Night Cream with Intelimer 8600 polymer is designed to be a leave-on night acne cream with super luxurious sensory benefits. Intelimer 8600 polymer is a hydrophobic film forming polymer which works effectively in wide ph ranges. The unique benefit of Intelimer 8600 in this formulation is effective retention of salicylic acid. Typical Properties (not to be used as specifications) Appearance White cream ph 3.5 to 4.2 Stability Passed 4 month 50 C Viscosity (cps) (Spindle 10 rpm) 75,500 88,000 Intelimer 8600 Salicylic Acid Retention Study using Formula S003 Average % Salicylic Acid Retained 1min 2mins 5 mins Salicylic Acid retention study was conducted using in-vitro skin. Test was conducted on in-vitro skin by applying 2mg/cm 2 of emulsion. Extraction of salicylic acid was conducted using DI water. Measurements of salicylic acid were conducted on HPLC Water Alliance Model 2695 using supelcosil LC-18 column. The mobile phase was prepared by using 1:1 mixture of DI water and methanol.

52 Ingredient / Trade Name INCI Designation %W/W Function Supplier Phase A Deionized water Deionized water 67.6 Keltrol CG-T Xanthan Gum 0.25 Thickener CP Kelco Pemulen TR-2 Acrylates/C Thickener Lubrizol Alkyl Acrylate Cross polymer Propylene glycol Propylene glycol 2.0 Humectant Rita Butylene glycol Butylene glycol 1.0 Humectant Ruger Hexylene glycol Hexylene glycol 1.0 Humectant Ruger Salicylic acid powder Salicylic acid 2.0 Acne Active Intelimer 8600 Poly C8-22 Alkyl Acrylate/ 2.2 Film Former/Enhance Air Products Metacrylic Acid Cross Polymer Retention of Actives Allantoin 0.5 Skin Protectant DSM Natural Alpha Bisabolol Alpha Bisabolol 0.15 Active Phase B Finsolv TN C12-15 Alkyl Benzoate 3.0 Solublizer Innospec Crodacol C-95 Cetyl alcohol 5.5 Stabilizer Croda Dow Corning 200/100 Dimethicone 5.6 Emollient Dow Corning Natural Beeswax Beeswax 2.5 Conditioner Rita Amphisol K Potassium cetyl phosphate 1.0 Emulsifier DSM Glyceryl stearate 2.0 Emulsifier Hydrogenated caster oil 1.0 Stabilizer Arlacel 165 PEG-100 stearate 1.5 Emulsifier Croda Cetiol LC Coco caprylate/caprate 1.0 Emollient Cognis Procedure 1. Combine all Phase A ingredients into a vessel while stirring mixture. 2. In another vessel add deionized water then slowly add xanthen gum and salicylic acid while stirring. Continue to stir until clear homogenous mixture forms. 3. Add other remaining Phase B ingredients one by one to the gum and acid mixture while continuing to stir. 4. Begin heating both vessels until the temperature of both vessels is between C. Once a C temperature has been achieved add Phase A to Phase B slowly while continuing to stir the mixture. 5. Remove from heat and homogenize the resulting mixture for three minutes. 6. Let the emulsion cool to the desired temperature. 7. Adjust the ph with few drops of Triethanolamine (TEA 99%) and package. For Samples or More Information If you would like additional information or technical assistance in preparing specific formulations, write or call Air Products and Chemicals, Inc. Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2008 Pub. No GLB-Sep08 The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto.

53 Color Cosmetics

54 Color Cosmetics: Attractive Made Easy The color cosmetics market is growing, but only modestly when compared with other personal care categories. This is leading to increasingly competitive dynamics. Solutions that meet aspirational needs and deliver practical benefits will differentiate themselves under these conditions. Are your products ready? Consider Intelimer temperature trigger technology. In lipstick, for example, our Intelimer IPA 13-6 polymer facilitates pigment dispersion, making formulations look great. At the same time, it provides low tackiness, low greasiness, and transfer resistance as well as reduces the migration of oils on skin, making formulations more worry-free for users. Intelimer IPA 13-6 polymer also improves moisturization and is silky and light, making formulations feel wonderful to use. Want a colorful solution? Check it out for yourself and see what Air Products and Intelimer technology can offer your formulations. Visit the website below or call in the U.S. and Canada or Enhancing Competitive Positioning with Intelimer Technology Changing consumer dynamics have dampened growth within color cosmetics relative to other personal care categories, but the long-term value proposition and potential for this market remains intact. Air Products Intelimer offering can help formulators deliver solutions that make looking good easy for increasingly busy consumers. For samples or more information: Key Trends in Color Cosmetics Shift to low maintenance and easy-to-use products Inclusion of additional product benefits, such as antiaging and sun protection Continued innovation of color palettes How Intelimer 13-6 Polymer Can Help Provides low tackiness and greasiness, improves control of oils on skin and lips, improves transfer resistance, and improves ease of application and wash-off Is compatible with various ingredients and can provide specific benefits for some applications, like sun protection Facilitates pigment dispersion across wide variety of ingredients If you would like additional information or technical assistance in preparing specific formulations, write or call: Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2008 (30248) US

55 Lipstick with Intelimer 13-6 Polymer Formulating Guide No. C001 Description Lipstick with Intelimer 13-6 polymer is designed to provide non-greasy, non-tacky, and transfer resistance with long lasting color. Procedure 1. Pigment Preblend: Heat Caster Oil to C and add the rest of the ingredients in small increments. Mix until lump free. Allow the mixture to cool to room temperature. Typical Properties (not to be used as specifications) Appearance Lipstick ph N/A Stability Passed 4 month 50 C Viscosity (cps) Stick 2. Lipstick: Combine ingredients in the listed order in a main vessel and begin heating to C while stirring. Continue to stir until all ingredients are completely dispersed and uniform. Once uniform, pour batch into a proper mold at C. Ingredient / Trade Name Lipstick Formulation With Intelimer 13-6 INCI Designation %W/W Function Supplier Isopropyl Palmitate Isopropyl Palmitate 35.8 Emollient Stepan Lanolin oil Lanolin oil 2.5 Emollient Dermol 99 Isononyl Isononanoate 3.1 Emollient Alzo Eutanol G Octyldodecanol 3.2 Emollient Cognis Liponate 2-DH PEG-4 diheptanoate 6.4 Emollient Lipo Pigment preblend See other side 38.8 Color LiquaPar oil Isopropylparaben (and) Isobutylparaben (and) Butylparaben 0.2 Preservative ISP Intelimer IPA 13-6 Poly C10-30 alkyl acrylate 10.0 Thickener Air Products

56 Ingredient / Trade Name Pigment Preblend INCI Designation %W/W Function Supplier Caster Oil Ricinus Communis [castor] seed oil Black iron oxide (C ) D&C Red #27 (30% Dispersion) C D&C Red #7 (30% Dispersion) C Cosmetic Russet (50% Dispersion C ) Black iron oxide[and] ricinus communis [castor] seed oil D&C Red #27 Aluminum Lake [and] ricinus communis [castor] seed oil D&C Red #7 Calcium Lake [and] ricinus communis [castor] seed oil Iron Oxide [and] ricinus communis [castor] seed oil) Dispersing agent CasChem 0.44 Color Sun Chemical 1.5 Color Sun Chemical 1.0 Color Sun Chemical 0.25 Color Sun Chemical For Samples or More Information If you would like additional information or technical assistance in preparing specific formulations, write or call Air Products and Chemicals, Inc. Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2008 Pub. No GLB-Sep08 The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto.

57 Lipstick with Intelimer 13-6 Polymer Formulating Guide C002 Description Lipstick with Intelimer 13-6 polymer is designed to provide a non-greasy, non-tacky, and transfer resistance lipstick with long lasting color. Intelimer 13-6 is used as an oil phase thickener and/or structuring agent. Procedure 1. Combine all ingredients in the following order in a vessel while stirring and begin to heat. 2. Continue to stir and heat until all ingredients are completely dispersed and uniform. This should happen at a temperature of C. 3. Once mixture is uniform start to cool. 4. Continue to cool the formulation, at C pour batch into a proper mold. Typical Properties (not to be used as specifications) Appearance Lipstick ph n/a Stability Passed 4 month 50 C Viscosity (cps) Stick Ingredient / Trade Name INCI Designation %W/W Function Supplier Eutanol G Octyldodecanol 24.7 Emollient Cognis Isopropyl Palmitate Isopropyl Palmitate 15.0 Emollient Uvinul MC 80 Octinoxate 7.5 Uvinul M 40 Benzophenone Sunscreen Active Sunscreen Active Mineral Oil Mineral Oil USP 27.5 Emollient BASF BASF Aerosil TM 200 (Fumed) Silica 2.0 Slip Agent Degussa Castro Wax NF Hydrogenated Caster Oil 4.5 Structurant Caschem Intelimer IPA 13-6 Poly C10-30 Alkyl Acrylate 10.0 Oil Thickener Air Products 50% Titanium Dioxide 50% Caster Oil (COD 8008) LiquaPar Oil Titanium Dioxide [and] Ricinus Communis [Castor] Seed Oil Isopropylparaben (and) Isobutylparaben (and) Butylparaben 2.5 Gloss agent Sun Chemical 0.1 Preservative ISP

58 For Samples or More Information If you would like additional information or technical assistance in preparing specific formulations, write or call Air Products and Chemicals, Inc. Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2008 Pub. No GLB-Sep08 The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto.

59 Lip-gloss with Intelimer 13-6 Polymer Formulating Guide C003 Description Lip-gloss with Intelimer 13-6 polymer is designed to provide a non-greasy, non-tacky, and easy to apply lip-gloss. Intelimer 13-6 is used as an oil phase thickener and/or structuring agent. Procedure 1. Combine all the ingredients in the listed order, except the last two ingredients, in a vessel while stirring and begin to heat. 2. Continue to stir and heat until C, then the last two ingredients. 3. Continue stirring until mixture is uniform then start to cool. 4. Pour batch into proper mold at C. Typical Properties (not to be used as specifications) Appearance Lipstick ph n/a Stability Passed 4 month 50 C Viscosity (cps) Stick Ingredient / Trade Name INCI Designation %W/W Function Supplier Eutanol G Octyldodecanol 26.3 Emollient Cognis Isopropyl Palmitate Isopropyl Palmitate 15.0 Emollient Uvinul MC 80 Octinoxate 7.5 Uvinul M 40 Benzophenone Sunscreen Active Sunscreen Active Mineral Oil Mineral Oil USP 30.0 Emollient BASF BASF Castro Wax NF Hydrogenated Caster Oil 4.5 Structurant Caschem Intelimer IPA 13-6 Poly C10-30 Alkyl Acrylate 10.0 Thickener Air Products 50% Titanium Dioxide 50% Caster Oil (COD 8008) LiquaPar Oil Titanium Dioxide [and] Ricinus Communis [Castor] Seed Oil Isopropylparaben (and) Isobutylparaben (and) Butylparaben 1.6 Gloss Agent Sun Chemical 0.1 Preservative ISP

60 For Samples or More Information If you would like additional information or technical assistance in preparing specific formulations, write or call Air Products and Chemicals, Inc. Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2008 Pub. No GLB-Sep08 The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto.

61 Antiperspirant/ Deodorant

62 Antiperspirant/deodorant... when it makes a difference In spite of market penetration rates exceeding 90% in some geographies, the $10 billion global antiperspirant and deodorant market is expected to continue growing. Are your products positioned to meet these consumer dynamics? Consider Intelimer temperature trigger technology. Our Intelimer IPA 13-6 polymer improves controlled release of actives, which can not only make end products effective for longer periods of time, but can also enable a more environmentally friendly solution that utilizes a lower overall concentration of active chemicals. It also provides nonwhitening properties in products, can act as a thickening agent in anhydrous stick formulations, and has excellent sensory qualities. Feeling the heat? Check it out for yourself and see what Air Products and Intelimer technology can offer your formulations. Visit our website or call in the U.S. and Canada or Enhancing Your Competitive Positioning with Intelimer Technology Intelimer technology enables APDO products to provide more effective protection for longer periods of time. With a standardized active ingredient platform across most antiperspirant and deodorant formulations, product innovation and your competitiveness hinge on matching your product features to market trends. Air Products Intelimer polymers offering gives formulators versatile benefits that can meet the needs of today and position for the needs of tomorrow. Key Trends in Antiperspirant/Deodorant Renewed interest in aesthetic qualities of the product Innovation through increased breadth of fragrances and occasion-based positioning Continued concern about long-term impact of actives and increased penetration of natural alternatives Overall emphasis on ease of use How Intelimer IPA 13-6 Can Help Promotes nonwhitening properties, thereby ameliorating a common shortcoming in many formulations Utilized for delivery of actives as well as for fragrances and is compatible with most formulations currently in the marketplace Can be used for delivery of natural ingredients and is effective at maintaining product performance with lower actives Enables more effective protection for longer periods of time For samples or more information: If you would like additional information or technical assistance in preparing specific formulations, write or call: Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2008 (30249) US

63 Antiperspirant / Deodorant Emulsion with Intelimer 13-6 Polymer Formulating Guide No. A001 Description Antiperspirant/Deodorant Emulsion with Intelimer 13-6 polymer is designed to provide a stable emulsion with a silky feel, non-whitening, and controlled release of actives. Typical Properties (not to be used as specifications) Appearance Emulsion ph N/A Stability Passed 4 month 50 C Viscosity (cps) N/A Antiperspirant Aluminum % Release Study using Intelimer IPA 13-6 in Formulation A001 % Release of Aluminum 15 min 2 hrs 4 hrs 6hrs 24 hrs Description of Aluminum-analysis: Quantitative analysis for aluminum was carried out by inductively coupled plasma atomic emission spectroscopy (ICP-OES) using a Perkin-Elmer Optima 5000 dual view emission spectrometer with axial and radial viewing with background correction.

64 Ingredient / Trade Name INCI Designation %W/W Function Supplier Phase A Mineral Oil USP Mineral Oil 4.0 Emollient SF 1202 Cyclopentasiloxane 11.5 Emollient Momentive Dow Corning 5225C Arlacel P135 Cyclopentasiloxane (and) PEG/PPG-18/18 Dimethicone PEG-30 Dipoly Hydroxy Stearate Intelimer IPA 13-6 Poly C10-30 alkyl acrylate 5.0 Phase B 2.5 Emulsifier Dow Corning 2.0 Emulsifier Uniqema Control release of Actives/Rheology modifier Deionized Water Water (Aqua) 32.0 Diluent Air Products Keltrol CG-T Xanthan Gum 0.2 Stabilizer Keltrol Glycerin Pricerine Humectant Uniqema Magnesium Sulfate MgSO4 0.5 Electrolyte Locorn L Aluminum Chlorohydrate 40 (20% active) AP-Active Clariant Procedure 1. Combine Phase A ingredients in a vessel and heat while stirring to ºC. 2. Combine Phase B ingredients in a separate vessel and heat while stirring to ºC. 3. Slowly add Phase B to Phase A, homogenize for 3-6 minutes, continue stirring. 4. Cool to desired fill temperature and package. For Samples or More Information If you would like additional information or technical assistance in preparing specific formulations, write or call Air Products and Chemicals, Inc. Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2008 Pub. No GLB-Sep08 The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto.

65 Antiperspirant/Deodorant Stick with Intelimer 13-6 Polymer Formulating Guide No. A002 Description Antiperspirant/deodorant stick with Intelimer 13-6 polymer is designed to provide a silky feel, nonwhitening, and controlled release of actives. Typical Properties (not to be used as specifications) Appearance White Stick ph N/A Stability Passed 4 month 50 C Viscosity (cps) APDO Stick Antiperspirant Aluminum % Release Study with Intelimer 13-6 in Formulation A002 % Release of Aluminum 15 min 1 hr 2 hrs 3hrs 4 hrs 5 hrs 6hrs Description of Aluminum-analysis: Quantitative analysis for aluminum was carried out by inductively coupled plasma atomic emission spectroscopy (ICP-OES) using a Perkin-Elmer Optima 5000 dual view emission spectrometer with axial and radial viewing with background correction.

66 Ingredient / Trade Name INCI Designation %W/W Function Supplier Probutyl 14 PPG-14 Butyl Ether 28.5 Skin Conditioner Croda Dow Corning 345 Cyclohexasiloxane (and) Cyclopentasiloxane 5.1 Emollient Dow Corning Finsolve TN C12-15 Alkyl Benzoate 5.3 Solublizer Innospec Castro Wax NF Hydrogenated Cater Oil Structurant CasChem Intelimer IPA 13-1 Poly C10-30 alkyl acrylate 5.0 Control release of Actives/ Thickener Air Products Crodacol S-95 Stearyl Alcohol 28 Structurant Croda AAZG-7167 (80% active) LiquaPar Oil Aluminium Zirconium Tetra Chlorohydrex Gly Isopropylparaben (and) Isobutylparaben (and) Butylparaben 23.1 (18.48% active) Antiperspirant active Summit Research Lab 0.2 Preservative ISP Procedure 1. Combine all the ingredients in the order listed in the formulation in a vessel while stirring and begin to heat. 2. Continue to stir and heat until all the ingredients are completely dispersed and uniform. This should happen at a temperature of C. 3. Once mixture has become uniform, start to cool. 4. Continue to cool the formulation, at C pour batch into proper mold. For Samples or More Information If you would like additional information or technical assistance in preparing specific formulations, write or call Air Products and Chemicals, Inc. Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2008 Pub. No GLB-Sep08 The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto.

67 Antiperspirant Solid Stick with Intelimer 13-6 Polymer Formulating Guide A003 Description Antiperspirant solid stick with Intelimer 13-6 polymer is designed to provide nonwhitening, non-greasy, non-tacky, and control release of actives. Intelimer IPA 13-6 is used as an oil phase thickener and/or structuring agent. Procedure: 1. Combine all the ingredients in the following order in a vessel while stirring and begin to heat. 2. Continue to stir and heat until all the ingredients are completely dispersed and uniform. This should happen at a temperature of C. 3. Once mixture is uniform start to cool. 4. Continue to cool the formulation, at C pour batch into proper mold. Typical Properties (not to be used as specifications) Appearance stick ph n/a Stability Passed 4 month 50 C Viscosity (cps) stick For Samples or More Information If you would like additional information or technical assistance in preparing specific formulations, write or call Air Products. Ingredient / Trade Name INCI Designation %W/W Function Supplier Probutyl 14 PPG-14 Butyl ether 13.9 Skin Conditioner Croda Castro Wax NF Hydrogenated Caster oil 4 Structurant Caschem Lanette 18 Stearyl Alcohol 6.0 Structurant Cognis Finsolve TN C12-15 Alkyl Benzoate 5.3 Emollient Finetex SF 1202 Cyclopentasiloxane 39.5 Emollient GE Silicone Intelimer IPA 13-6 Poly C10-30 alkyl acrylate 5.0 Thickener/Cont rol release of Actives Air Products (Fumed) Silica Silica 3.0 Slip Aid Degussa AAZG-7167 (80% Active) LiquaPar oil Aluminium Zirconium Tetra Chlorohydrex Gly Isopropylparaben (and) Isobutylparaben (and) Butylparaben 23.1 (18.48% active) Antiperspirant active Summit Research Lab 0.2 Preservative ISP

68 For Samples or More Information If you would like additional information or technical assistance in preparing specific formulations, write or call Air Products. Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2007 Pub. No GLB The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto.

69 Other Applications

70 Applications Under Development Extending Capabilities to Shaving, Skin Care and Color Cosmetics At Air Products, we are constantly extending our existing products as well as developing new solutions to meet diverse personal care needs. Our continued study of Intelimer and Hybridur technologies presently suggests that they offer benefits for the following markets: Shaving (Intelimer 13-1 polymer) Skin Care (Hybridur 875 polymer) We welcome an opportunity to work with interested parties as we continue our validation process. We are also presently working on a host of other technologies that we plan to commercialize more broadly in the future. If you would like to see for yourself what Air Products can offer your formulations, visit the website below or call in the U.S. and Canada or Enhancing Competitive Positioning with Air Products Researchers at Air Products are continually working to uncover, adapt, enhance, and validate new technologies for the personal care industry. Our experience with industrial markets has provided us with the discipline and insight necessary to work proactively toward adding value through our chemical formulations. We have also learned the benefit of forging working relationships with our customers to develop and tailor solutions that meet their needs. We welcome an opportunity to work with you to solve your most challenging application and formulation requirements. For more information: If you would like additional information or technical assistance in preparing specific formulations, write or call: Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., 2008 (30250) US

71 Basic Shaving Cream with Intelimer 13-1 Polymer Formulating Guide No. R001 Description Basic Shaving Cream with Intelimer 13-1 polymer is designed to provide an easy to use, non-greasy, nontacky shaving cream. The unique benefit of Intelimer 13-1 polymer in this solution is its excellent sensory benefits and rheology modification. Procedure Typical Properties (not to be used as specifications) UAppearance White Emulsion UpH 5.5 Viscosity (cps) U (Spindle rpm) Combine all Phase A ingredients into a vessel. 2. In a separate vessel add all the Phase B ingredients. 3. Heat both vessels to C while stirring. 4. Slowly add Phase B to Phase A while continuing to stir. 5. Remove from heat and stir until emulsion reaches room temperature. 6. Adjust ph with Triethanolamine (TEA 99%). Ingredient/Trade Name INCI Designation %W/W Function Supplier Phase A Pristerene 4911 Stearic Stearic Acid 18.0 Uniqema Acid Stabilizer Mineral Oil Drakeol 7LT Mineral Oil 5.0 Emollient Penreco Tween 60 Polysorbate Emulsifier Uniqema Intelimer 13-1 Phase B Poly C10-30 Alkyl Acrylate 1.0 Rheology modification/control release of actives Deionized water Water Diluent Air Products Pricerine 9088 Glycerine 5.0 Humectant Uniqema Glydant DMDM Hydantoin 0.5 Preservative Lonza Triethanolamine TEA (99%) 0.04 Neutralizer Rita

72 For Samples or More Information If you would like additional information or technical assistance in preparing specific formulations, write or call Air Products and Chemicals, Inc. Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., GLB The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto.

73 Enhanced Shaving Cream with Intelimer 13-1 Polymer Formulating Guide No. R002 Description Enhanced Shaving Cream with Intelimer 13-1 polymer is designed to provide an easy to use, non-greasy, non-tacky shaving cream. The unique benefit of Intelimer 13-1 polymer in this solution is its excellent sensory properties as well as its enhancement of the formulation through inclusion of sun protection capability. Procedure 1. Combine all Phase A ingredients into a vessel. 2. In a separate vessel add all the Phase B ingredients. 3. Heat both vessels to C while stirring. 4. Slowly add Phase B to Phase A while continuing to stir. 5. Remove from heat and stir until emulsion reaches room temperature. 6. Adjust ph with Triethanolamine (TEA 99%). Typical Properties (not to be used as specifications) Appearance White Cream ph 6.0 Viscosity (cps) (Spindle rpm) Ingredient/Trade Name INCI Designation %W/W Function Supplier Phase A Pristerene 4911 Stearic Stearic Acid 10.0 Acid Stabilizer Uniqema Panalane H-300E Hydrogenated Polyisobutene 5.0 Emollient Lipo Jojoba Oil Simmondsia Chinensis (Jojoba) Oil 5.0 Jeen International Corp. Conditioner Arlacel 165 PEG Stearate 2.0 Emulsifier Uniqema Stepan GMS Pure Glyceryl stearate 2.0 Emulsifier Stepan Liponate GC Caprylic Caprylate triglyceride 2.0 Emollient Lipo T-Lite SF Titanium Dioxide 1.0 Sunscreen active BASF Intelimer 13-1 Poly C10-30 Alkyl Acrylate 1.0 Rheology modification/controlled Air Products release Phase B Deionized water Water Diluent Pricerine 9088 Glycerine 5.0 Humectant Uniqema Glydant DMDM Hydantoin 0.5 Preservative Lonza Triethanolamine TEA (99%) 0.04 Neutralizer Rita

74 For Samples or More Information If you would like additional information or technical assistance in preparing specific formulations, write or call Air Products and Chemicals, Inc. Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., GLB The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto.

75 Aloe Shaving Cream with Intelimer 13-1 Polymer Formulating Guide No. R003 Description Aloe Shaving Cream with Intelimer 13-1 polymer is designed to provide an easy to use, non-greasy, nontacky shaving cream with aloe. The unique benefit of Intelimer 13-1 polymer in this solution is its excellent sensory properties as well as its improved retention and release of soothing agent aloe vera. Typical Properties (not to be used as specifications) ph 5.5 Procedure 1. Combine all Phase A ingredients into a vessel. 2. In a separate vessel add all the Phase B ingredients. 3. Heat both vessels to C while stirring. 4. Slowly add Phase B to Phase A while continuing to stir. 5. Remove from heat and stir until emulsion reaches room temperature. 6. Add Phase C to emulsion. 7. Adjust ph with Triethanolamine (TEA 99%). Ingredient/Trade Name INCI Designation %W/W Function Supplier Phase A Stearic Acid Pristerene 4911 Stearic Acid 18 Stabilizer Uniqema Mineral Oil Drakeol 7LT Mineral Oil 5 Emollient Penerco Tween 60 Polysorbate 60 5 Emulsifier Uniqema Intelimer 13-1 Rheology Poly C10-30 Alkyl 1 modification/controlled Acrylate release Air Products Phase B Water DI water Diluent Pricerine 9088 Glycerine 5 Humectant Uniqema Glydant DMDM Hydantoin 0.5 Preservative Lonza D Panthenol Panthenol 0.5 Skin Protectant BASF Allantoin Allantoin 0.5 Skin Protectant DSM Triethanolamine TEA (99%) 0.05 Neutralizer Rita Phase C Aloe Vera 1 Skin soothing agent Bell Flavor & Fragrances Dow Corning 200/1000 cst Dimethicone 0.5 Feel enhancer Dow Corning

76 For Samples or More Information If you would like additional information or technical assistance in preparing specific formulations, write or call Air Products and Chemicals, Inc. Air Products and Chemicals, Inc Hamilton Boulevard Allentown, PA U.S.A. Telephone: (Outside the U.S. and Canada ) Fax: tell me more Air Products and Chemicals, Inc., GLB The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto.

77 Facial Exfoliate with Intelimer 13-1 Polymer Formulating Guide No. R004 Description Facial Exfoliate with Intelimer 13-1 polymer is designed to provide a smooth and silky but nonetheless effective exfoliate. The unique benefit of Intelimer 13-1 polymer in this solution is its excellent sensory benefits. Procedure 1. Combine all Phase A ingredients into a vessel. 2. In a separate vessel add all the Phase B ingredients. 3. Heat both vessels to C while stirring. 4. Slowly add Phase B to Phase A while continuing to stir. 5. Remove from heat and stir until emulsion reaches room temperature. 6. Add Cypress Green Jojoba Spheres to emulsion at room temperature with mild stirring. 7. Adjust ph with Triethanolamine (TEA 99%). Typical Properties (not to be used as specifications) Appearance White Cream ph 5.5 Viscosity (cps) (Spindle rpm) 57,700 65,000 Ingredient/Trade Name INCI Designation %W/W Function Supplier Phase A Deionized Water Water 73.5 Diluent Crodacol C-70 Cetyl Alcohol 4.3 Stabilizer Croda Amisoft MS-11 Acylgutamate 4 Surfactant Ajinomoto Velvetex BK-35 Cocamidopropyl betaine 4 Foam booster Cognis Pricerine 9088 Glycerine 2 Humectant Uniqema Phase B Pristerene 4911 Stearic Acid BRIJ 721 Intelimer 13-1 Stearic Acid 5 Stabilizer Uniqema Polyoxyethylene (21) Stearyl Ether Poly C10-30 Alkyl Acrylate 2.2 Emulsifier Uniqema 2.2 Rheology modification/controlled release Air Products Mineral Oil Drakeol 7LT Mineral Oil 2 Emollient Rite Aid Hydrogenated Jojoba Oil Cypress Green Jojoba Spheres. Lot #: SJCG / Exfoliation Desert Whale